File name: Pandora85s1_NewOrleansLA-XULA_20260226_L2Fit_fwvt1c6d20250326p1-8.txt File generation date: 20260227T062607.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v6d20250326.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20260226_L1_smca1c6d20250326p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20260226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 3 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0885 492.2093 492.3300 492.4507 492.5713 492.6920 492.8126 492.9333 493.0539 493.1745 493.2950 493.4156 493.5361 493.6567 493.7772 493.8977 494.0181 494.1386 494.2590 494.3795 494.4999 494.6203 494.7406 494.8610 494.9813 495.1016 495.2219 495.3422 495.4625 495.5827 495.7030 495.8232 495.9434 496.0636 496.1837 496.3039 496.4240 496.5441 496.6642 496.7843 496.9044 497.0244 497.1444 497.2645 497.3844 497.5044 497.6244 497.7443 497.8643 497.9842 498.1041 498.2239 498.3438 498.4636 498.5834 498.7032 498.8230 498.9428 499.0626 499.1823 499.3020 499.4217 499.5414 499.6611 499.7807 499.9003 500.0200 500.1396 500.2591 500.3787 500.4983 500.6178 500.7373 500.8568 500.9763 501.0957 501.2152 501.3346 501.4540 501.5734 501.6928 501.8121 501.9315 502.0508 502.1701 502.2894 502.4086 502.5279 502.6471 502.7663 502.8855 503.0047 503.1239 503.2430 503.3622 503.4813 503.6004 503.7194 503.8385 503.9575 504.0766 504.1956 504.3146 504.4335 504.5525 504.6714 504.7904 504.9093 505.0282 505.1470 505.2659 505.3847 505.5035 505.6223 505.7411 505.8599 505.9786 506.0973 506.2161 506.3347 506.4534 506.5721 506.6907 506.8094 506.9280 507.0465 507.1651 507.2837 507.4022 507.5207 507.6392 507.7577 507.8762 507.9946 508.1131 508.2315 508.3499 508.4682 508.5866 508.7050 508.8233 508.9416 509.0599 509.1782 509.2964 509.4146 509.5329 509.6511 509.7693 509.8874 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260226T144729.6Z 9553.616315 202 1 0.77 2 62.64 119.46 121.75 12.22 0.00 1 0.00 1 0 15 4.761e-03 4.747e-03 2.824e-03 2.819e-03 3.269997e+03 1.736024e+02 2.298953e+02 -6.000000e+00 2.663485e+02 285.13 -2.00 20.00 -2.00 505.24 0.00e+00 5.523491e-04 7.791917e-05 3.390358e-05 -6.000000e+00 1.343067e-04 285.13 -2.00 20.00 -2.00 500.37 0.00e+00 1.588049e-01 5.581912e-02 2.322427e-02 -6.000000e+00 9.442074e-02 225.97 -2.00 3.24 -2.00 501.97 0.00e+00 2.165 0.000 489.00 513.00 1 4.5491e+00 4.2788e-03 3.7616e-03 -6.0000e+00 7.2359e-03 1.0586e-02 1.1130e-03 5.6970e-04 -6.0000e+00 1.8931e-03 1.4858e-02 7.7317e-04 2.7663e-04 2.9035e-05 -6.0000e+00 4.8409e-04 -1.1059e-02 9.1243e-06 12 9 9 12 1 1 999.00 24.95 2.10 -0.01106 -0.00570 1 16 1 4 0 382.150 33.00 20.01 24.95 26.05 4.4 1003.68 -1060 -314 -388 139 369 915 747 298 298 326 -93 -105 -494 -650 -468 -323 -38 -116 -66 149 -184 -282 -297 920 546 985 360 60 5 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-168 -695 -220 -223 635 723 634 1348 828 150 663 481 -5 95 -370 -250 524 406 792 233 364 382 -191 -516 -622 -804 10 -76 -321 -397 -79 227 65 63 427 107 848 163 -343 104 -817 -627 SQ 20260226T145151.2Z 9553.619342 205 1 4.78 2 61.82 120.25 121.56 13.27 0.00 1 0.00 1 0 15 3.863e-03 3.852e-03 7.644e-04 7.628e-04 3.143469e+03 4.699038e+01 2.256435e+02 -6.000000e+00 2.161347e+02 285.13 -2.00 20.00 -2.00 505.24 0.00e+00 5.447072e-04 2.108811e-05 3.279475e-05 -6.000000e+00 1.089843e-04 285.13 -2.00 20.00 -2.00 500.35 0.00e+00 1.810222e-01 1.512880e-02 2.154076e-02 -6.000000e+00 7.661457e-02 225.97 -2.00 3.24 -2.00 501.95 0.00e+00 2.107 0.000 489.00 513.00 1 4.3980e+00 1.1597e-03 3.6203e-03 -6.0000e+00 5.8715e-03 1.4102e-02 3.0163e-04 5.3976e-04 -6.0000e+00 1.5360e-03 1.7402e-02 1.1757e-04 7.4912e-05 2.8206e-05 -6.0000e+00 3.9282e-04 -9.6385e-03 5.8984e-06 12 9 1 12 1 1 95.06 24.97 2.11 -0.00964 -0.00882 16 21 1 4 0 281.150 33.00 20.01 24.97 26.29 4.4 1004.67 -1118 -833 -353 50 396 625 675 504 417 331 199 -44 -334 -348 -605 -546 -192 -73 45 146 269 268 219 400 341 556 498 -76 -242 -411 -721 -546 -125 123 144 338 469 23 -380 -151 -56 -96 173 323 393 522 494 268 215 -262 -514 -860 -839 -654 -365 -166 127 254 514 233 296 325 402 297 248 89 64 -193 -462 -388 -323 -278 -180 51 9 12 -149 -273 -449 -533 -387 -341 -219 -87 2 -100 30 -104 -229 -22 161 451 357 473 545 451 173 -131 -371 -790 -873 -495 -208 9 -168 53 -173 -413 -344 -339 -344 11 74 395 674 806 713 448 481 314 43 49 233 -19 138 180 371 160 357 153 -149 5 -233 -531 -382 -392 -391 -189 198 239 249 300 318 246 243 148 -170 -297 -542 -656 -1103 -832 -357 51 412 653 716 533 439 350 207 -46 -343 -353 -614 -557 -198 -77 48 155 283 282 231 421 360 586 522 -80 -251 -420 -730 -554 -127 127 151 356 490 24 -395 -156 -57 -99 178 337 413 548 515 277 221 -266 -514 -844 -825 -640 -365 -167 129 258 522 236 300 331 411 303 251 90 64 -193 -457 -377 -316 -273 -176 50 9 12 -146 -266 -433 -512 -373 -331 -211 -84 2 -98 30 -102 -225 -22 160 445 357 474 539 445 167 -126 -351 -748 -825 -467 -199 9 -167 52 -171 -404 -337 -329 -338 11 74 395 668 802 713 450 479 313 43 48 227 -19 135 175 359 155 344 147 -143 5 -222 -503 -360 -368 -375 -182 193 233 244 295 315 242 238 146 -166 -286 -520 -626 SQ 20260226T145530.6Z 9553.621882 208 1 2.57 2 61.14 120.92 121.38 14.15 0.00 1 0.00 1 0 15 4.810e-03 4.797e-03 3.013e-03 3.007e-03 3.165002e+03 1.851507e+02 2.250144e+02 -6.000000e+00 2.691037e+02 285.13 -2.00 20.00 -2.00 505.23 0.00e+00 5.251130e-04 8.310346e-05 3.052908e-05 -6.000000e+00 1.356956e-04 285.13 -2.00 20.00 -2.00 500.34 0.00e+00 1.972687e-01 5.964218e-02 2.197421e-02 -6.000000e+00 9.539632e-02 225.97 -2.00 3.24 -2.00 501.95 0.00e+00 2.062 0.000 489.00 513.00 1 5.8834e+00 4.5715e-03 3.5721e-03 -6.0000e+00 7.3107e-03 1.2345e-02 1.1898e-03 5.4536e-04 -6.0000e+00 1.9126e-03 3.9616e-03 4.4253e-04 2.9556e-04 2.7686e-05 -6.0000e+00 4.8910e-04 -9.1096e-03 -1.8287e-06 12 9 9 12 1 1 999.00 24.98 2.10 -0.00911 -0.00604 1 5 1 4 0 1283.750 33.00 20.01 24.98 26.51 4.4 1005.83 -1436 -492 -834 87 815 854 132 550 455 210 -205 183 -1062 -446 -689 -267 -152 481 285 192 482 606 -192 217 70 823 933 -179 -176 -55 -655 -852 -48 302 472 355 149 -67 -138 -322 -521 -74 169 492 -84 323 349 241 169 22 -551 -898 -898 -697 -194 -99 331 39 795 481 71 606 -65 -172 189 581 -13 125 -639 -511 -574 -599 339 425 -50 749 241 -482 -16 -459 -351 -480 -176 -119 -232 -396 -283 -247 16 -262 639 25 -497 770 764 568 163 374 -931 -1243 -929 188 -4 -380 -95 459 368 -121 -618 -471 -648 -385 -163 597 287 750 573 633 293 242 213 587 61 264 514 78 350 106 487 64 -322 -216 -100 -509 -146 171 -598 -107 -182 208 -26 45 568 570 64 384 -400 -607 -796 -387 -1420 -490 -848 90 841 899 140 586 483 221 -213 189 -1094 -457 -707 -274 -157 495 301 202 508 639 -204 230 75 871 980 -187 -181 -55 -659 -864 -49 314 497 371 155 -70 -142 -330 -535 -76 176 515 -87 337 361 250 172 22 -550 -890 -882 -689 -193 -100 336 40 810 490 73 620 -66 -175 193 582 -13 124 -629 -502 -561 -589 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