File name: Pandora51s1_OldFieldNY_20220914_L2Fit_fout2c5d20211018p1-8.txt File generation date: 20251205T031158.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 51 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora51_OF_v5d20190801.txt Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt Level 1 file used: Pandora51s1_OldFieldNY_20220914_L1_smca1c5d20211018p1-8.txt Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044) Short location name: OldFieldNY Country of location: USA Location latitude [deg]: 40.9635 Location longitude [deg]: -73.1402 Location altitude [m]: 3 Local noon date: 20220914 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO First and last pixel inside fitting window: 257 399 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2748 305.4155 305.5562 305.6968 305.8375 305.9781 306.1187 306.2593 306.3999 306.5405 306.6810 306.8216 306.9621 307.1027 307.2432 307.3837 307.5242 307.6647 307.8052 307.9457 308.0861 308.2266 308.3670 308.5074 308.6478 308.7882 308.9286 309.0690 309.2094 309.3497 309.4901 309.6304 309.7707 309.9110 310.0513 310.1916 310.3319 310.4722 310.6124 310.7527 310.8929 311.0331 311.1733 311.3135 311.4537 311.5939 311.7340 311.8742 312.0143 312.1545 312.2946 312.4347 312.5748 312.7149 312.8549 312.9950 313.1350 313.2751 313.4151 313.5551 313.6951 313.8351 313.9751 314.1151 314.2550 314.3950 314.5349 314.6748 314.8147 314.9546 315.0945 315.2344 315.3743 315.5141 315.6540 315.7938 315.9336 316.0734 316.2132 316.3530 316.4928 316.6326 316.7723 316.9120 317.0518 317.1915 317.3312 317.4709 317.6106 317.7503 317.8899 318.0296 318.1692 318.3088 318.4484 318.5880 318.7276 318.8672 319.0068 319.1463 319.2859 319.4254 319.5649 319.7044 319.8439 319.9834 320.1229 320.2624 320.4018 320.5413 320.6807 320.8201 320.9595 321.0989 321.2383 321.3777 321.5170 321.6564 321.7957 321.9351 322.0744 322.2137 322.3530 322.4922 322.6315 322.7708 322.9100 323.0492 323.1885 323.3277 323.4669 323.6061 323.7452 323.8844 324.0235 324.1627 324.3018 324.4409 324.5800 324.7191 324.8582 324.9973 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220914T114445.6Z 8292.489417 251 1 49.64 2 77.17 96.86 55.01 259.29 0.00 1 0.00 1 0 25 4.702e-01 1.644e-02 3.664e-01 1.472e-02 5.629290e-01 8.162822e-03 6.281656e-03 -6.000000e+00 2.828049e-01 229.35 -2.00 3.51 -2.00 321.09 0.00e+00 4.248378e-03 3.901499e-03 1.202006e-03 -6.000000e+00 1.348658e-02 288.01 -2.00 20.00 -2.00 320.42 0.00e+00 4.381 0.001 302.00 328.00 3 4.7579e+00 2.8087e-02 5.3964e-02 -6.0000e+00 7.0258e-01 3.7293e-02 3.6806e-02 3.3643e-02 -6.0000e+00 7.6289e-01 -3.4504e-02 3.2975e-02 1.4997e-02 -6.0000e+00 4.5547e-01 9.2093e-03 1.5784e-02 7.6889e-03 -6.0000e+00 1.9144e-01 3.0653e-05 -4.0011e-04 4.8001e-04 7.5520e-05 -6.0000e+00 1.4650e-02 -2.1455e-03 6.8524e-05 12 9 8 11 8 0 99.84 22.22 0.44 -0.00215 -0.00515 15 3 1 5 0 3308.530 26.83 19.99 22.22 22.43 14.3 986.25 900000 -22015 900000 -110105 900000 -81988 -58745 -116567 -101917 -102775 -141751 224959 900000 -106517 -89051 900000 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849 -39 165 -3693 3332 -2644 1483 1264 977 -1064 -2417 660 271 1936 -3170 -776 -37 -1165 125 -2477 1068 -1760 109 1203 2388 -475 1782 1666 -1191 -177 -987 -322 1215 21 -2648 -211 145 -1006 770 -1313 44 -1754 121 -511 116 -358 -447 2345 -1802 644 120 -590 987 -1788 2086 -1531 670 -152 1023 -795 -162 -229 -1172 3077 262 739 2141 13 4590 -1860 -798 -1211 -1147 259 -780 2513 -657 714 -2776 SS 20220914T115456.3Z 8292.496485 254 1 48.04 2 75.27 98.59 56.84 261.16 0.00 1 0.00 1 0 25 3.911e-01 1.842e-02 3.161e-01 1.734e-02 4.966785e-01 9.813985e-03 5.897114e-03 -6.000000e+00 2.415431e-01 229.35 -2.00 3.51 -2.00 320.63 0.00e+00 1.090982e-02 3.946448e-03 1.241175e-03 -6.000000e+00 1.197679e-02 288.01 -2.00 20.00 -2.00 319.96 0.00e+00 3.851 0.001 302.00 328.00 3 5.3691e+00 3.1053e-02 4.8829e-02 -6.0000e+00 6.0376e-01 8.8878e-02 3.8736e-02 3.4376e-02 -6.0000e+00 6.5299e-01 -7.3463e-02 3.3136e-02 1.5991e-02 -6.0000e+00 3.8398e-01 2.0845e-02 1.6622e-02 1.4396e-02 -6.0000e+00 1.6447e-01 2.8162e-05 -1.2929e-03 5.7066e-04 1.3095e-04 -6.0000e+00 1.2485e-02 4.1127e-04 -9.3861e-05 12 8 8 10 0 0 99.96 22.22 0.38 0.00041 -0.00930 19 4 1 5 0 2527.560 26.83 20.00 22.22 22.65 14.2 987.44 291430 82762 900000 900000 -101906 900000 48653 900000 900000 74241 900000 -82578 -55814 -41091 7968 105819 -28740 85660 12674 58969 -38619 -59641 -27395 51933 47958 150421 81032 -6479 7545 10011 74265 10609 -3662 9127 -35650 -19207 -29917 -944 -19961 22770 -3017 -9998 -3904 -8282 24187 16722 1531 26461 4198 2256 -8202 20157 2822 14323 16739 -4756 3092 8828 -684 -714 4168 -4238 4111 -5756 2287 693 4663 -3550 5567 430 -5008 3584 799 -1240 1993 -4546 -1468 -3165 1308 -6770 -1851 -458 -1058 -608 1544 358 1765 524 621 776 1321 -1636 517 -855 -465 358 2300 2038 255 -379 -1255 -1595 -1900 -2186 386 -109 -1214 -1017 -707 -866 1414 177 -592 2446 -847 -425 -461 -722 1125 -1484 460 -1060 -1365 1466 996 1313 1922 672 530 1611 776 92 530 -240 -1780 -1327 167 2233 -382 -211 -83 -787 900000 4921 1397 900000 900000 -2355 900000 822 900000 900000 1254 900000 -2459 -1612 -1296 193 1787 -1219 1446 434 1355 -2190 -4079 -1423 1364 1350 2540 1720 -302 319 463 2229 638 -272 620 -3612 -1711 -3240 -92 -2705 2345 -427 -1614 -622 -1426 3098 2369 258 3653 733 428 -1843 3802 664 3173 3735 -1340 809 2158 -183 -195 1163 -1429 1418 -2349 865 258 1646 -1413 2234 202 -2670 1791 400 -596 848 -1884 -578 -1281 569 -3696 -1096 -296 -739 -449 1192 296 1504 461 538 640 1008 -1202 360 -627 -377 329 2356 2319 308 -450 -1400 -1642 -1881 -2241 411 -123 -1470 -1315 -990 -1325 2254 291 -956 3638 -1229 -596 -658 -1087 1759 -2455 743 -1693 -2115 2118 1383 1792 2575 960 812 2669 1389 175 1042 -502 -4000 -3093 392 5212 -906 -481 -181 -1652 900000 SS 20220914T120404.8Z 8292.502834 257 1 29.89 2 73.56 100.17 58.49 262.79 0.00 1 0.00 1 0 17 3.145e-01 8.278e-03 1.864e-01 6.822e-03 4.635906e-01 3.625039e-03 5.300031e-03 -6.000000e+00 1.876868e-01 229.35 -2.00 3.51 -2.00 320.25 0.00e+00 8.386816e-04 1.303432e-03 4.323449e-04 -6.000000e+00 8.497907e-03 288.01 -2.00 20.00 -2.00 319.49 0.00e+00 3.476 0.001 302.00 328.00 3 4.5693e+00 1.1059e-02 4.2430e-02 -6.0000e+00 4.6657e-01 9.6731e-03 1.3606e-02 2.4398e-02 -6.0000e+00 5.0602e-01 -7.7541e-03 1.1179e-02 1.2012e-02 -6.0000e+00 3.0218e-01 -4.5068e-03 5.6275e-03 3.4399e-03 -6.0000e+00 1.2591e-01 9.9655e-05 -2.8972e-04 2.2064e-04 4.5271e-05 -6.0000e+00 9.6785e-03 -1.4498e-03 6.1342e-05 12 9 1 12 1 1 99.94 22.21 0.31 -0.00145 -0.00363 16 6 1 5 0 1747.690 26.83 20.00 22.21 22.74 14.2 988.18 -16001 254178 222016 -24571 -25485 -44110 -30727 48685 -52118 4234 -16354 68069 -16889 24766 -17258 10099 -1225 -217 19720 -5318 36306 15829 19323 5749 -7620 14329 -22701 7683 -17309 25359 -4692 3629 4810 -11260 -2364 -9810 5650 -3062 -5340 -2893 41 716 701 6266 -10341 -179 -2111 -3432 3056 3113 6979 -1704 1295 1262 -2597 359 2858 877 -2860 3235 142 1534 4075 2475 -672 675 596 -194 3238 -2035 38 1491 320 1587 1389 577 -475 -2075 32 -1512 -2990 -665 -2002 -966 624 -1388 432 -48 35 -408 -677 -707 440 1012 291 301 1022 509 -9 -336 -900 381 848 -22 -830 -1242 -1114 1042 663 872 -601 611 483 32 213 -318 -13 454 -310 -351 -594 -305 -221 654 69 596 289 588 -168 135 -290 -492 -180 27 131 -368 -118 289 827 -274 -122 -326 69 -207 1691 1477 -364 -374 -780 -526 451 -1339 70 -342 741 -474 570 -673 347 -50 -9 765 -269 1268 677 871 311 -501 783 -1733 430 -1242 1312 -361 290 402 -1122 -211 -989 555 -392 -818 -498 8 137 139 1195 -2353 -37 -449 -750 645 698 1643 -477 379 394 -879 122 958 297 -993 1068 51 597 1701 1116 -312 297 259 -88 1574 -1137 22 887 188 894 717 274 -216 -981 17 -905 -2011 -484 -1586 -806 549 -1321 411 -47 34 -383 -593 -579 352 833 259 303 1124 620 -11 -418 -1051 416 888 -24 -978 -1513 -1434 1397 942 1341 -996 1016 782 49 315 -459 -19 693 -492 -577 -975 -487 -351 984 99 825 395 840 -264 224 -517 -919 -340 54 276 -795 -262 643 1814 -600 -254 -657 137 SS 20220914T121409.0Z 8292.509827 264 1 48.87 2 71.70 101.94 60.31 264.55 0.00 1 0.00 1 0 17 7.228e-02 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