File name: Pandora51s1_OldFieldNY_20220928_L2Fit_fout2c5d20211018p1-8.txt File generation date: 20251205T032051.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 51 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora51_OF_v5d20190801.txt Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt Level 1 file used: Pandora51s1_OldFieldNY_20220928_L1_smca1c5d20211018p1-8.txt Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044) Short location name: OldFieldNY Country of location: USA Location latitude [deg]: 40.9635 Location longitude [deg]: -73.1402 Location altitude [m]: 3 Local noon date: 20220928 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO First and last pixel inside fitting window: 257 399 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2748 305.4155 305.5562 305.6968 305.8375 305.9781 306.1187 306.2593 306.3999 306.5405 306.6810 306.8216 306.9621 307.1027 307.2432 307.3837 307.5242 307.6647 307.8052 307.9457 308.0861 308.2266 308.3670 308.5074 308.6478 308.7882 308.9286 309.0690 309.2094 309.3497 309.4901 309.6304 309.7707 309.9110 310.0513 310.1916 310.3319 310.4722 310.6124 310.7527 310.8929 311.0331 311.1733 311.3135 311.4537 311.5939 311.7340 311.8742 312.0143 312.1545 312.2946 312.4347 312.5748 312.7149 312.8549 312.9950 313.1350 313.2751 313.4151 313.5551 313.6951 313.8351 313.9751 314.1151 314.2550 314.3950 314.5349 314.6748 314.8147 314.9546 315.0945 315.2344 315.3743 315.5141 315.6540 315.7938 315.9336 316.0734 316.2132 316.3530 316.4928 316.6326 316.7723 316.9120 317.0518 317.1915 317.3312 317.4709 317.6106 317.7503 317.8899 318.0296 318.1692 318.3088 318.4484 318.5880 318.7276 318.8672 319.0068 319.1463 319.2859 319.4254 319.5649 319.7044 319.8439 319.9834 320.1229 320.2624 320.4018 320.5413 320.6807 320.8201 320.9595 321.0989 321.2383 321.3777 321.5170 321.6564 321.7957 321.9351 322.0744 322.2137 322.3530 322.4922 322.6315 322.7708 322.9100 323.0492 323.1885 323.3277 323.4669 323.6061 323.7452 323.8844 324.0235 324.1627 324.3018 324.4409 324.5800 324.7191 324.8582 324.9973 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220928T122817.3Z 8306.519644 94 1 3.93 2 71.97 109.54 102.77 97.66 0.00 1 0.00 1 0 25 5.646e-02 7.369e-03 4.511e-02 4.519e-03 4.066631e-01 2.345367e-03 4.737000e-03 -6.000000e+00 3.350533e-02 227.83 -2.00 3.51 -2.00 319.06 0.00e+00 9.632059e-04 5.824922e-04 2.140113e-04 -6.000000e+00 1.515057e-03 286.36 -2.00 20.00 -2.00 318.27 0.00e+00 3.188 0.001 302.00 328.00 3 2.9908e+00 6.5187e-03 3.8148e-02 -6.0000e+00 8.3037e-02 -1.3298e-03 7.5759e-03 2.1075e-02 -6.0000e+00 9.0187e-02 -5.2307e-03 5.3847e-03 1.0312e-02 -6.0000e+00 5.3869e-02 -3.2899e-03 2.7898e-03 2.9903e-03 -6.0000e+00 2.2476e-02 6.9168e-04 -2.5695e-04 1.4216e-04 3.6781e-05 -6.0000e+00 1.7368e-03 -7.6775e-04 6.5875e-05 12 9 1 12 1 1 99.96 22.20 0.32 -0.00077 -0.00270 8 27 1 5 0 416.810 26.83 19.99 22.20 18.68 14.3 961.27 -19550 -3100 12264 -15600 28174 -6102 3313 -33168 368 -21382 -4592 -8238 -7276 3534 -8007 4637 -12310 12244 3370 3521 2344 -7536 8883 -4345 -1958 -6264 5567 684 -6007 4402 -5918 7129 -4705 -3726 -7529 1206 -565 201 2255 -4529 276 -1151 228 932 -1696 166 -2487 196 -2552 1064 1702 2038 2060 1720 2729 1434 872 670 258 1563 1708 2067 1941 1289 -889 -202 392 582 -156 -212 687 -555 884 -939 -432 -755 81 -778 -349 -279 -1389 -295 -2023 -454 -580 -345 -611 112 637 -837 151 -675 103 1035 166 637 812 917 -224 -454 -471 -75 -114 -425 -736 -1399 -468 -194 32 227 261 729 211 149 -249 466 427 -3 -344 -1020 -349 188 898 -196 429 1009 1027 1369 211 11 -559 18 -220 -182 -195 -671 534 -104 449 -53 -104 -105 -527 -650 -95 324 -512 595 -176 96 -1549 13 -1022 -195 -408 -423 209 -618 351 -1191 989 313 339 232 -841 887 -530 -247 -809 660 82 -760 532 -844 1041 -797 -630 -1293 198 -107 45 563 -1386 88 -390 79 323 -584 59 -903 70 -952 403 665 859 931 826 1349 709 439 335 128 774 891 1174 1159 817 -571 -123 241 368 -105 -154 530 -445 685 -701 -306 -487 51 -499 -236 -207 -1178 -263 -1900 -446 -590 -372 -690 127 715 -906 155 -651 98 999 171 707 980 1174 -301 -595 -595 -87 -133 -501 -930 -1818 -636 -271 46 344 418 1172 330 227 -368 660 612 -5 -538 -1619 -552 289 1369 -290 619 1434 1432 1922 315 18 -937 30 -386 -328 -361 -1271 1025 -203 867 -102 -192 -192 -963 SS 20220928T123255.5Z 8306.522865 97 1 49.26 2 71.15 110.40 101.95 98.39 0.00 1 0.00 1 0 25 2.337e-02 5.428e-03 4.278e-03 3.803e-04 3.922146e-01 1.971222e-04 4.550072e-03 -6.000000e+00 1.386399e-02 227.83 -2.00 3.51 -2.00 319.47 0.00e+00 1.064520e-03 5.497267e-05 1.587556e-04 -6.000000e+00 6.270791e-04 286.36 -2.00 20.00 -2.00 318.68 0.00e+00 3.057 0.000 302.00 328.00 3 3.5469e-01 5.5905e-04 3.6659e-02 -6.0000e+00 3.4359e-02 1.1453e-03 6.5808e-04 2.0369e-02 -6.0000e+00 3.7323e-02 -1.1768e-03 4.8421e-04 9.9435e-03 -6.0000e+00 2.2293e-02 -8.3757e-03 2.4960e-04 2.9129e-03 -6.0000e+00 9.2977e-03 1.1129e-02 -5.9219e-04 1.2303e-05 3.6509e-05 -6.0000e+00 7.1898e-04 3.3218e-04 -1.3550e-05 10 0 0 10 0 0 90.80 22.21 0.23 0.00033 -0.00412 1679 381 1 5 0 28.920 26.83 20.00 22.21 18.88 14.4 963.44 -5525 -5872 -7574 -8680 -9234 -8210 -7897 -4659 -6731 -6814 -7725 -5609 -2503 -1939 -1575 -1803 -209 -663 168 -749 -1028 -576 -552 -1006 -2086 -2173 -3455 -2401 -1444 190 747 555 -95 -3018 -2713 -1631 -1145 -759 -697 -1194 -1596 -1184 -1167 -660 -438 -412 -598 -319 242 1006 1232 869 1236 1164 906 952 343 90 520 1009 1468 1922 1685 853 -150 94 828 1008 1430 543 48 32 -97 -31 -313 -188 16 282 250 -556 -974 -1402 -1705 -1105 -711 -626 -332 25 147 173 451 702 967 1232 784 573 584 169 -588 -692 -399 -8 356 -65 -1071 -1247 -664 -387 -28 186 -95 -160 53 211 536 785 756 301 -109 -708 -573 -62 255 220 351 408 1044 1353 373 -63 -206 -86 160 53 -160 -379 19 69 -295 -240 -82 7 -11 -137 -158 -208 -226 -229 -206 -216 -139 -224 -238 -285 -227 -116 -106 -100 -127 -16 -53 14 -65 -91 -52 -52 -102 -226 -242 -383 -253 -149 20 89 73 -14 -446 -391 -242 -192 -138 -151 -297 -433 -336 -341 -194 -130 -123 -178 -95 73 315 417 319 484 482 390 421 154 40 229 448 684 973 932 500 -88 52 445 557 866 370 35 24 -71 -22 -201 -110 9 156 152 -389 -772 -1228 -1479 -1013 -695 -649 -358 27 159 178 428 617 878 1142 736 604 691 220 -799 -915 -491 -9 392 -75 -1328 -1636 -914 -563 -41 288 -155 -264 84 316 748 1139 1112 434 -167 -1137 -922 -96 387 320 523 583 1454 1957 547 -99 -347 -151 291 101 -303 -749 37 142 -601 -473 -155 14 -21 SS 20220928T124337.4Z 8306.530295 100 1 49.70 2 69.27 112.42 100.05 100.06 0.00 1 0.00 1 0 25 1.702e-02 5.590e-03 2.646e-03 3.128e-04 3.609087e-01 1.617005e-04 4.217552e-03 -6.000000e+00 1.009907e-02 227.83 -2.00 3.51 -2.00 319.12 0.00e+00 5.807999e-04 4.023142e-05 1.361315e-04 -6.000000e+00 4.567512e-04 286.36 -2.00 20.00 -2.00 318.32 0.00e+00 2.797 0.000 302.00 328.00 3 3.3093e-01 4.4994e-04 3.3595e-02 -6.0000e+00 2.5029e-02 -1.5398e-03 5.2319e-04 1.8696e-02 -6.0000e+00 2.7187e-02 -2.1289e-03 3.6402e-04 9.1162e-03 -6.0000e+00 1.6239e-02 -6.6542e-03 1.8735e-04 2.5514e-03 -6.0000e+00 6.7733e-03 1.5290e-02 -4.9660e-04 1.0133e-05 3.2627e-05 -6.0000e+00 5.2368e-04 -1.9804e-04 -6.0403e-06 10 0 0 10 0 0 15.00 22.21 0.23 -0.00020 -0.00393 1953 443 1 5 0 24.830 26.83 20.00 22.21 20.20 14.5 972.80 -3774 -4555 -4973 -7318 -6282 -3767 -4489 -3347 -4479 -5397 -5364 -3479 -2535 -2012 -748 -1559 -605 -674 -499 -327 -804 126 568 -557 -1222 -1797 -2464 -2106 -833 363 995 529 -359 -3056 -2598 -1190 -916 -507 -802 -1005 -1474 -848 -1012 -579 -330 -494 -553 -379 20 880 1197 835 1140 1080 878 923 412 209 560 1082 1450 1939 1656 747 -230 35 896 1040 1523 583 42 81 -134 64 -403 -112 167 264 344 -532 -997 -1472 -1766 -1156 -766 -617 -420 -51 -3 64 350 674 947 1245 756 559 583 253 -617 -723 -349 -23 341 30 -990 -1207 -678 -388 -25 74 -102 -199 61 192 526 775 787 303 -145 -634 -609 -3 264 292 410 482 1079 1360 453 7 -201 -46 136 42 -155 -349 5 89 -318 -283 -107 -53 -57 -130 -170 -186 -261 -209 -125 -164 -135 -200 -254 -263 -185 -156 -144 -61 -141 -58 -68 -53 -36 -90 14 67 -71 -164 -249 -337 -274 -105 47 142 83 -61 -535 -441 -208 -180 -118 -204 -292 -466 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