File name: Pandora51s1_OldFieldNY_20230907_L2Fit_fout2c5d20211018p1-8.txt File generation date: 20230908T052958.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 51 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora51_OF_v5d20190801.txt Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt Level 1 file used: Pandora51s1_OldFieldNY_20230907_L1_smca1c5d20211018p1-8.txt Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044) Short location name: OldFieldNY Country of location: USA Location latitude [deg]: 40.9635 Location longitude [deg]: -73.1402 Location altitude [m]: 3 Local noon date: 20230907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO First and last pixel inside fitting window: 257 399 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2748 305.4155 305.5562 305.6968 305.8375 305.9781 306.1187 306.2593 306.3999 306.5405 306.6810 306.8216 306.9621 307.1027 307.2432 307.3837 307.5242 307.6647 307.8052 307.9457 308.0861 308.2266 308.3670 308.5074 308.6478 308.7882 308.9286 309.0690 309.2094 309.3497 309.4901 309.6304 309.7707 309.9110 310.0513 310.1916 310.3319 310.4722 310.6124 310.7527 310.8929 311.0331 311.1733 311.3135 311.4537 311.5939 311.7340 311.8742 312.0143 312.1545 312.2946 312.4347 312.5748 312.7149 312.8549 312.9950 313.1350 313.2751 313.4151 313.5551 313.6951 313.8351 313.9751 314.1151 314.2550 314.3950 314.5349 314.6748 314.8147 314.9546 315.0945 315.2344 315.3743 315.5141 315.6540 315.7938 315.9336 316.0734 316.2132 316.3530 316.4928 316.6326 316.7723 316.9120 317.0518 317.1915 317.3312 317.4709 317.6106 317.7503 317.8899 318.0296 318.1692 318.3088 318.4484 318.5880 318.7276 318.8672 319.0068 319.1463 319.2859 319.4254 319.5649 319.7044 319.8439 319.9834 320.1229 320.2624 320.4018 320.5413 320.6807 320.8201 320.9595 321.0989 321.2383 321.3777 321.5170 321.6564 321.7957 321.9351 322.0744 322.2137 322.3530 322.4922 322.6315 322.7708 322.9100 323.0492 323.1885 323.3277 323.4669 323.6061 323.7452 323.8844 324.0235 324.1627 324.3018 324.4409 324.5800 324.7191 324.8582 324.9973 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230907T114217.9Z 8650.487707 251 1 50.00 2 76.30 93.89 15.60 210.81 0.00 1 0.00 1 0 25 4.072e-01 1.826e-02 3.688e-01 1.649e-02 5.133156e-01 9.160562e-03 5.838524e-03 -6.000000e+00 2.498491e-01 229.93 -2.00 3.51 -2.00 320.93 0.00e+00 6.620186e-03 4.095376e-03 9.316089e-04 -6.000000e+00 1.212637e-02 288.55 -2.00 20.00 -2.00 320.22 0.00e+00 4.123 0.001 302.00 328.00 3 5.1732e+00 3.0756e-02 5.0520e-02 -6.0000e+00 6.2200e-01 1.8049e-02 3.9616e-02 3.1647e-02 -6.0000e+00 6.7602e-01 -6.2898e-02 3.4684e-02 1.4193e-02 -6.0000e+00 3.9741e-01 2.6301e-02 1.6795e-02 9.3097e-03 -6.0000e+00 1.6428e-01 2.7742e-05 -1.0698e-03 5.5196e-04 8.6498e-05 -6.0000e+00 1.2940e-02 2.9325e-03 8.1823e-05 12 8 8 10 0 0 99.54 22.01 0.83 0.00293 -0.00511 21 5 1 5 0 2380.320 26.73 20.00 22.01 28.95 18.5 1043.35 -87964 900000 -181310 -55751 900000 900000 900000 -57741 900000 -51127 38764 208837 202393 99475 26966 70760 23949 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-846 2365 -3590 204 -252 2378 -34 -2053 1055 548 1072 -2599 -25 -2066 -1408 1381 -4706 -1348 -2241 685 607 -1379 -1152 -1419 602 437 962 -461 1196 1374 458 1462 -462 -563 -1481 3184 4263 248 -1213 -2402 -1005 3138 3698 -738 2400 70 -219 2445 -2294 2153 -2105 305 -2166 -2550 -209 1228 -288 -1045 387 -1062 358 1646 -4086 -752 1264 -693 989 2613 -1214 -259 545 -1040 921 -1139 -387 1155 342 SS 20230907T115255.0Z 8650.495080 254 1 12.91 2 74.31 95.67 16.71 218.10 0.00 1 0.00 1 0 17 1.155e-01 7.356e-03 1.349e-01 5.560e-03 4.496547e-01 2.936390e-03 5.166143e-03 -6.000000e+00 6.903605e-02 229.93 -2.00 3.51 -2.00 319.94 0.00e+00 1.251647e-03 9.617183e-04 6.308124e-04 -6.000000e+00 3.127593e-03 288.55 -2.00 20.00 -2.00 319.15 0.00e+00 3.630 0.001 302.00 328.00 3 3.8241e+00 8.7457e-03 4.3312e-02 -6.0000e+00 1.7183e-01 -1.7127e-02 1.0546e-02 2.3781e-02 -6.0000e+00 1.8630e-01 -6.9488e-03 8.3394e-03 1.1671e-02 -6.0000e+00 1.1123e-01 -5.1354e-03 4.2565e-03 3.2972e-03 -6.0000e+00 4.6284e-02 1.8896e-04 -7.1014e-04 1.7732e-04 4.2441e-05 -6.0000e+00 3.5557e-03 1.3921e-03 -2.8973e-05 12 9 1 12 1 1 76.61 22.00 0.47 0.00139 -0.00394 9 9 1 5 0 1290.050 26.73 20.00 22.00 29.38 18.4 1045.85 -19641 -27424 -23585 104270 30174 -28425 -26220 28915 14551 3523 15059 -21645 9008 -17652 -4932 -9930 -4323 4888 -6836 2160 -8528 -3726 15048 -3481 -6431 3756 6038 2704 7615 1033 -1591 -6415 -8756 3051 -4451 -558 -1008 -369 293 -1487 -3022 -2843 -2602 326 4342 935 -1594 -1542 3154 1083 145 3063 1779 3246 158 2799 -3049 1433 53 593 2006 572 2229 -515 -1466 841 2177 2020 269 2438 -607 1074 -848 -567 -799 -51 -1206 220 -1080 -1624 -915 -1570 -2105 -649 -1205 62 -712 367 590 409 574 -220 352 1390 1343 121 1531 286 -194 -365 -590 -696 357 -362 -1493 -1425 27 103 -20 81 -157 -275 22 499 54 1033 1269 915 69 -363 -1378 -104 782 286 -96 402 993 637 344 -574 -602 -665 151 30 -31 -259 -621 164 12 -170 377 59 276 -319 -527 -442 565 297 -518 -517 371 237 68 275 -651 240 -678 -196 -467 -209 232 -386 116 -520 -222 789 -236 -477 260 404 181 485 76 -135 -643 -977 306 -473 -60 -123 -54 51 -301 -679 -673 -636 79 1018 229 -403 -394 792 295 44 897 569 1087 57 1014 -1187 529 20 221 781 248 1044 -263 -752 405 1019 984 148 1464 -404 721 -569 -358 -464 -27 -608 112 -618 -1071 -680 -1207 -1747 -565 -1131 61 -738 383 607 400 522 -189 289 1168 1243 128 1805 351 -248 -457 -690 -808 397 -421 -1751 -1764 35 141 -30 123 -252 -448 35 790 82 1486 1853 1409 106 -583 -2233 -162 1252 442 -142 571 1381 931 551 -943 -1055 -1219 286 56 -62 -542 -1336 355 26 -354 747 114 526 SS 20230907T120218.5Z 8650.501603 257 1 10.33 2 72.55 97.28 17.84 223.83 0.00 1 0.00 1 0 17 1.044e-01 7.894e-03 8.445e-02 5.464e-03 4.145099e-01 2.866644e-03 4.787990e-03 -6.000000e+00 6.241881e-02 229.93 -2.00 3.51 -2.00 319.51 0.00e+00 -6.288554e-04 8.136267e-04 6.877589e-04 -6.000000e+00 2.826696e-03 288.55 -2.00 20.00 -2.00 318.69 0.00e+00 3.286 0.001 302.00 328.00 3 4.0313e+00 8.2300e-03 3.9473e-02 -6.0000e+00 1.5536e-01 -2.3066e-02 9.7217e-03 2.2198e-02 -6.0000e+00 1.6841e-01 5.7340e-03 7.2122e-03 1.0522e-02 -6.0000e+00 1.0056e-01 -1.1336e-02 3.7070e-03 2.9432e-03 -6.0000e+00 4.1863e-02 2.2355e-04 -6.8082e-05 1.7496e-04 3.5401e-05 -6.0000e+00 3.2129e-03 2.8784e-04 8.0023e-05 12 9 1 12 9 1 98.44 22.00 0.26 0.00029 -0.00022 7 9 1 5 0 1290.430 26.73 20.00 22.00 29.67 18.4 1047.78 -113 6521 -1805 -6486 74675 -56309 25690 22710 44902 -6149 -23150 -8860 -33589 4437 5341 -5215 -8884 7210 -2448 -2508 -6422 -11785 13260 -3166 6246 -9437 -7178 -5232 1091 356 6340 -1648 -3650 -60 -1216 -948 3124 -2099 1279 1338 -1594 -3554 1257 -298 -518 -719 -1512 3781 -3620 4036 1721 596 1785 1009 1861 -690 1620 576 2107 1578 1012 2837 1056 987 -32 -817 -263 -296 1812 -283 891 8 898 -660 -799 -66 -935 -469 -303 -1540 -487 -288 -2395 -784 -1203 -290 831 73 -318 -482 358 -1464 -335 941 750 1627 1128 716 4 -756 -158 -910 -702 -676 -950 -1397 349 -714 24 509 177 174 677 568 -298 1016 536 -96 -362 -764 -165 256 868 483 827 -748 701 1517 -102 363 -440 -595 -377 -643 29 -575 251 -104 333 269 248 -236 -263 -2 133 -40 -143 760 -1954 461 477 834 -196 -897 -334 -1865 205 276 -333 -635 469 -185 -197 -522 -1039 993 -294 576 -1025 -751 -528 102 35 663 -203 -495 -8 -159 -130 467 -385 272 326 -426 -1020 354 -86 -151 -211 -447 1092 -1123 1225 581 220 685 414 790 -310 721 257 915 696 473 1423 575 567 -18 -452 -142 -165 1093 -191 636 6 646 -456 -519 -39 -535 -271 -188 -1081 -374 -244 -2169 -728 -1202 -299 884 80 -344 -497 347 -1374 -299 850 743 1722 1321 905 5 -978 -194 -1065 -796 -798 -1176 -1798 466 -1003 36 788 285 282 1062 856 -434 1442 776 -144 -567 -1223 -263 406 1352 723 1203 -1062 983 2160 -157 591 -752 -1042 -673 -1192 57 -1155 504 -213 674 535 481 -445 -502 SS 20230907T120856.1Z 8650.506205 261 1 13.47 2 71.31 98.42 18.71 227.49 0.00 1 0.00 1 0 25 4.882e-02 6.468e-03 3.029e-02 3.299e-03 3.871446e-01 1.724907e-03 4.481326e-03 -6.000000e+00 2.917836e-02 229.93 -2.00 3.51 -2.00 319.21 0.00e+00 1.289979e-03 4.445384e-04 2.697252e-04 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