File name: Pandora51s1_OldFieldNY_20231109_L2Fit_fwvt1c5d20211018p1-8.txt File generation date: 20231110T044330.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 51 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora51_OF_v5d20190801.txt Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt Level 1 file used: Pandora51s1_OldFieldNY_20231109_L1_smca1c5d20211018p1-8.txt Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044) Short location name: OldFieldNY Country of location: USA Location latitude [deg]: 40.9635 Location longitude [deg]: -73.1402 Location altitude [m]: 3 Local noon date: 20231109 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO First and last pixel inside fitting window: 1681 1831 Nominal wavelengths inside fitting window [nm]: 492.1009 492.2214 492.3419 492.4623 492.5828 492.7032 492.8236 492.9440 493.0643 493.1847 493.3050 493.4253 493.5456 493.6659 493.7862 493.9064 494.0266 494.1468 494.2670 494.3872 494.5074 494.6275 494.7476 494.8677 494.9878 495.1079 495.2280 495.3480 495.4680 495.5880 495.7080 495.8280 495.9479 496.0679 496.1878 496.3077 496.4276 496.5474 496.6673 496.7871 496.9069 497.0267 497.1465 497.2663 497.3860 497.5057 497.6254 497.7451 497.8648 497.9845 498.1041 498.2237 498.3433 498.4629 498.5825 498.7021 498.8216 498.9411 499.0606 499.1801 499.2996 499.4190 499.5385 499.6579 499.7773 499.8967 500.0160 500.1354 500.2547 500.3740 500.4933 500.6126 500.7318 500.8511 500.9703 501.0895 501.2087 501.3279 501.4470 501.5662 501.6853 501.8044 501.9235 502.0426 502.1616 502.2806 502.3997 502.5187 502.6376 502.7566 502.8755 502.9945 503.1134 503.2323 503.3512 503.4700 503.5889 503.7077 503.8265 503.9453 504.0641 504.1828 504.3016 504.4203 504.5390 504.6577 504.7763 504.8950 505.0136 505.1322 505.2508 505.3694 505.4880 505.6065 505.7250 505.8436 505.9620 506.0805 506.1990 506.3174 506.4358 506.5542 506.6726 506.7910 506.9094 507.0277 507.1460 507.2643 507.3826 507.5009 507.6191 507.7373 507.8555 507.9737 508.0919 508.2101 508.3282 508.4463 508.5645 508.6825 508.8006 508.9187 509.0367 509.1547 509.2727 509.3907 509.5087 509.6266 509.7445 509.8625 509.9804 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231109T191820.4Z 8713.804403 426 1 48.89 2 69.01 221.70 83.23 262.43 0.00 1 0.00 1 0 15 2.346e-03 2.337e-03 6.405e-04 6.386e-04 4.225861e+03 3.923001e+01 2.975278e+02 -6.000000e+00 1.270055e+02 281.19 -2.00 20.00 -2.00 505.26 0.00e+00 1.193436e-03 1.736317e-05 7.229138e-05 -6.000000e+00 6.493956e-05 281.19 -2.00 20.00 -2.00 500.45 0.00e+00 1.251276e-01 1.248166e-02 3.203614e-02 -6.000000e+00 4.566477e-02 223.73 -2.00 3.51 -2.00 502.03 0.00e+00 2.764 0.000 489.00 513.00 1 6.4509e+00 9.5670e-04 5.0851e-03 -6.0000e+00 3.4986e-03 -3.1745e-03 2.4558e-04 7.6929e-04 -6.0000e+00 9.0862e-04 2.0198e-03 4.4497e-04 5.9154e-05 4.5041e-05 -6.0000e+00 2.2465e-04 5.1669e-03 -4.8915e-05 10 0 0 10 0 0 99.98 22.09 1.22 0.00517 0.00825 191 43 1 4 0 255.920 26.73 20.00 22.09 18.59 18.6 974.52 -238 -153 -122 256 458 471 574 322 476 436 348 130 -208 -281 -239 23 99 -90 -94 -27 135 147 251 29 249 300 123 -93 -153 -158 -129 79 -88 -174 -161 124 43 -112 -82 -224 -158 -15 80 57 36 26 118 137 -180 -253 -538 -496 -279 -350 -230 -399 -192 5 166 154 195 126 96 32 64 111 132 -56 -163 -252 -71 -83 36 -213 -340 -387 -187 -45 -374 -237 -365 -139 -127 -113 -217 -145 -247 -202 -214 -42 52 61 -107 86 145 141 84 -177 -432 -453 -354 -168 -241 -493 -215 -343 -194 -2 -20 -129 66 50 21 265 327 579 506 311 362 195 256 320 398 161 124 141 131 362 308 244 25 67 -21 -18 120 -26 -63 -51 94 91 261 174 181 254 57 -29 -244 -166 -221 -235 -83 -227 -148 -122 266 486 481 595 337 494 446 351 137 -217 -289 -245 24 104 -92 -98 -28 142 155 264 30 264 318 130 -97 -155 -155 -125 77 -88 -180 -171 132 46 -117 -84 -230 -162 -16 84 60 38 28 125 144 -185 -255 -526 -473 -263 -334 -226 -405 -198 5 173 160 203 132 100 34 67 113 133 -56 -160 -245 -68 -80 35 -212 -341 -386 -183 -44 -356 -225 -348 -133 -122 -111 -215 -145 -247 -202 -213 -42 52 62 -105 84 148 141 82 -170 -404 -416 -323 -156 -230 -492 -209 -336 -189 -2 -18 -122 64 49 21 264 327 581 512 316 367 195 252 309 381 155 120 137 127 351 298 235 24 63 -20 -16 110 -24 -60 -50 93 91 261 175 183 258 58 -30 -244 -162 -211 -223 -79 SQ 20231109T192221.9Z 8713.807198 429 1 1.84 2 69.52 222.57 83.98 263.07 0.00 1 0.00 1 0 15 2.689e-03 2.690e-03 1.209e-03 1.208e-03 4.401804e+03 7.360220e+01 3.126675e+02 -6.000000e+00 1.455875e+02 281.19 -2.00 20.00 -2.00 505.29 0.00e+00 1.090113e-03 3.281330e-05 6.747291e-05 -6.000000e+00 7.444286e-05 281.19 -2.00 20.00 -2.00 500.54 0.00e+00 1.462235e-01 2.342417e-02 3.289564e-02 -6.000000e+00 5.235581e-02 223.73 -2.00 3.51 -2.00 502.13 0.00e+00 2.829 0.000 489.00 513.00 1 4.9513e+00 1.7933e-03 5.1640e-03 -6.0000e+00 4.0111e-03 -4.4292e-03 4.6155e-04 8.0161e-04 -6.0000e+00 1.0419e-03 8.9622e-03 4.9789e-04 1.1164e-04 4.5343e-05 -6.0000e+00 2.5757e-04 7.5552e-03 -7.4874e-05 12 1 1 12 1 1 -17.48 22.08 1.35 0.00756 0.01101 5 37 1 4 0 304.510 26.73 20.01 22.08 18.59 18.6 974.16 -64 -242 -79 354 301 501 502 609 273 575 31 204 -75 -331 -288 182 -20 -139 -112 233 147 353 273 -26 225 443 293 -168 -427 -258 -283 84 -126 -296 -92 68 154 -181 26 -327 -66 218 306 -110 121 40 73 -106 -321 -271 -419 -714 -320 -199 -321 -119 -144 -268 -80 215 286 184 193 82 109 369 28 101 -267 -90 -301 -113 -45 -244 -530 -103 -84 -261 -147 -408 -133 -474 -197 -305 -361 -160 -341 -98 -103 -100 -50 330 -92 204 -54 134 203 -210 -215 -623 -595 -223 -168 -499 -266 -206 -304 -72 23 -59 -27 -124 85 629 322 441 308 358 448 358 271 391 254 343 197 39 87 233 182 231 182 53 230 119 147 58 -12 56 324 -58 45 193 138 196 18 110 -212 -106 -240 -200 -382 -62 -235 -79 358 305 517 527 628 281 594 32 206 -77 -333 -289 184 -20 -143 -115 242 153 367 284 -27 236 465 305 -173 -439 -256 -285 83 -127 -304 -94 71 160 -188 26 -332 -67 223 316 -113 125 42 76 -107 -329 -270 -414 -707 -313 -197 -319 -119 -148 -272 -81 220 293 186 196 83 110 373 28 100 -266 -89 -294 -111 -45 -240 -527 -102 -83 -254 -142 -392 -128 -462 -193 -295 -354 -158 -338 -97 -102 -99 -50 325 -92 205 -54 133 197 -203 -203 -592 -564 -209 -162 -493 -264 -206 -302 -70 23 -57 -26 -124 84 626 323 444 312 365 454 358 267 387 249 337 195 38 86 231 180 228 179 52 224 114 141 56 -12 56 318 -58 45 195 137 195 18 110 -212 -104 -235 -194 -373 SQ 20231109T192608.3Z 8713.809818 432 1 4.22 2 70.00 223.38 84.68 263.67 0.00 1 0.00 1 0 15 2.593e-03 2.593e-03 1.120e-03 1.119e-03 4.408605e+03 6.828512e+01 3.109579e+02 -6.000000e+00 1.403898e+02 281.19 -2.00 20.00 -2.00 505.30 0.00e+00 1.032243e-03 3.040218e-05 6.496288e-05 -6.000000e+00 7.177710e-05 281.19 -2.00 20.00 -2.00 500.58 0.00e+00 1.253172e-01 2.167241e-02 3.338258e-02 -6.000000e+00 5.045282e-02 223.73 -2.00 3.51 -2.00 502.15 0.00e+00 2.893 0.000 489.00 513.00 1 5.6391e+00 1.6586e-03 5.2375e-03 -6.0000e+00 3.8657e-03 -1.1126e-02 4.2689e-04 8.1165e-04 -6.0000e+00 1.0035e-03 4.4755e-03 -4.1646e-04 1.0348e-04 4.4654e-05 -6.0000e+00 2.4821e-04 1.0231e-02 -4.9913e-05 12 1 1 12 1 1 93.71 22.08 1.31 0.01023 0.00734 6 18 1 4 0 601.090 26.73 19.99 22.08 18.54 18.6 974.02 -90 -304 -128 245 596 587 588 451 405 441 97 -157 -358 -198 -185 119 76 -89 -27 -79 107 535 31 180 219 275 21 -159 -65 -234 -45 121 -93 -285 -90 52 200 -183 27 -194 -159 0 135 -34 -65 220 -24 227 -186 -433 -457 -498 -253 -103 -297 -373 -141 -149 260 323 17 275 90 135 90 27 115 -164 -159 -271 -331 -382 47 -211 -221 -111 -94 -116 -229 -246 -495 -273 -137 -352 -192 -242 -36 -11 -283 -220 -37 132 45 26 253 137 184 -211 -351 -276 -538 -337 -317 -294 -341 -298 -146 2 -159 -172 -83 87 -48 332 427 354 575 501 511 441 291 119 501 134 150 65 9 256 262 356 100 -173 124 -252 162 161 41 111 26 127 75 283 249 324 108 -83 -225 -136 -252 -293 -272 -87 -294 -129 246 613 600 612 472 421 453 99 -157 -363 -198 -185 120 76 -91 -27 -82 110 551 32 186 228 286 22 -163 -66 -231 -45 122 -93 -290 -94 55 207 -188 27 -196 -161 0 139 -36 -67 226 -25 234 -189 -440 -450 -492 -247 -101 -294 -372 -144 -154 267 330 17 283 91 137 92 27 114 -162 -158 -267 -324 -376 47 -207 -218 -110 -94 -113 -221 -236 -478 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