File name: Pandora51s1_OldFieldNY_20231202_L2Fit_fout2c5d20211018p1-8.txt File generation date: 20231203T045008.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 51 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora51_OF_v5d20190801.txt Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt Level 1 file used: Pandora51s1_OldFieldNY_20231202_L1_smca1c5d20211018p1-8.txt Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044) Short location name: OldFieldNY Country of location: USA Location latitude [deg]: 40.9635 Location longitude [deg]: -73.1402 Location altitude [m]: 3 Local noon date: 20231202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO First and last pixel inside fitting window: 257 399 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2748 305.4155 305.5562 305.6968 305.8375 305.9781 306.1187 306.2593 306.3999 306.5405 306.6810 306.8216 306.9621 307.1027 307.2432 307.3837 307.5242 307.6647 307.8052 307.9457 308.0861 308.2266 308.3670 308.5074 308.6478 308.7882 308.9286 309.0690 309.2094 309.3497 309.4901 309.6304 309.7707 309.9110 310.0513 310.1916 310.3319 310.4722 310.6124 310.7527 310.8929 311.0331 311.1733 311.3135 311.4537 311.5939 311.7340 311.8742 312.0143 312.1545 312.2946 312.4347 312.5748 312.7149 312.8549 312.9950 313.1350 313.2751 313.4151 313.5551 313.6951 313.8351 313.9751 314.1151 314.2550 314.3950 314.5349 314.6748 314.8147 314.9546 315.0945 315.2344 315.3743 315.5141 315.6540 315.7938 315.9336 316.0734 316.2132 316.3530 316.4928 316.6326 316.7723 316.9120 317.0518 317.1915 317.3312 317.4709 317.6106 317.7503 317.8899 318.0296 318.1692 318.3088 318.4484 318.5880 318.7276 318.8672 319.0068 319.1463 319.2859 319.4254 319.5649 319.7044 319.8439 319.9834 320.1229 320.2624 320.4018 320.5413 320.6807 320.8201 320.9595 321.0989 321.2383 321.3777 321.5170 321.6564 321.7957 321.9351 322.0744 322.2137 322.3530 322.4922 322.6315 322.7708 322.9100 323.0492 323.1885 323.3277 323.4669 323.6061 323.7452 323.8844 324.0235 324.1627 324.3018 324.4409 324.5800 324.7191 324.8582 324.9973 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231202T172839.4Z 8736.728234 471 1 2.06 2 63.88 192.06 99.31 308.33 0.00 1 0.00 1 0 25 1.706e-02 8.796e-03 1.525e-02 5.289e-03 2.913497e-01 2.758139e-03 3.593182e-03 -6.000000e+00 1.011927e-02 222.98 -2.00 3.51 -2.00 317.02 0.00e+00 9.704961e-05 3.742180e-04 6.177349e-05 -6.000000e+00 4.461738e-04 278.60 -2.00 20.00 -2.00 316.40 0.00e+00 2.258 0.000 302.00 328.00 3 3.6607e+00 7.1631e-03 2.6900e-02 -6.0000e+00 2.4883e-02 3.3112e-02 8.0253e-03 1.4819e-02 -6.0000e+00 2.6992e-02 -1.2465e-02 4.8150e-03 7.4036e-03 -6.0000e+00 1.6100e-02 1.4458e-03 2.3748e-03 2.1383e-03 -6.0000e+00 6.9252e-03 1.0029e-03 -7.4214e-04 1.6589e-04 2.8672e-05 -6.0000e+00 5.2530e-04 2.3301e-03 -5.9048e-05 12 9 1 12 1 1 999.00 22.29 0.19 0.00233 -0.00325 2 17 1 5 0 674.040 26.94 19.99 22.29 16.11 18.6 961.61 -771 335 -6954 -3327 1284 -4307 -1971 -5061 4153 457 44 1797 -727 908 -2956 560 -3705 1557 -1551 1331 2769 -1793 3212 -3867 2736 -3007 1654 -3128 1250 5772 1007 613 -3800 -1550 -2392 1557 -1531 1067 3215 -1272 126 -3001 -907 -1603 -1183 170 -1356 1364 598 1236 725 1794 1916 1217 717 619 535 407 1116 658 696 2445 1484 1091 -661 -224 124 912 482 -1028 236 89 1392 -182 -609 -1041 -212 182 -306 -1464 -1943 -1800 -2262 -1003 -528 -1451 69 -532 -180 407 565 -64 2245 440 417 1304 802 69 -986 -97 -897 -311 970 -241 -694 -712 -1033 -478 159 514 -401 554 -22 468 413 452 690 358 188 -671 -553 -199 -10 -149 501 1022 1331 1632 505 -151 -533 192 436 341 -46 -548 -475 29 364 -581 -102 -787 900000 -92 42 -916 -399 137 -492 -239 -689 570 66 7 282 -130 184 -684 132 -957 398 -424 364 751 -504 915 -1223 847 -984 513 -961 362 1639 316 209 -1400 -554 -834 541 -604 466 1589 -704 73 -1825 -552 -986 -724 103 -824 808 357 743 459 1177 1307 861 525 456 397 304 817 490 534 1959 1251 942 -565 -184 99 732 411 -943 225 86 1322 -169 -537 -874 -167 145 -256 -1327 -1888 -1853 -2419 -1107 -604 -1732 84 -660 -219 480 639 -69 2293 455 451 1509 984 90 -1307 -127 -1132 -373 1137 -296 -879 -938 -1400 -662 226 759 -613 837 -33 667 562 605 923 499 269 -989 -821 -293 -14 -210 686 1361 1745 2169 699 -219 -794 288 667 534 -74 -912 -802 49 614 -970 -168 -1270 900000 SS 20231202T173242.1Z 8736.731043 474 1 42.23 2 64.05 193.09 99.89 309.04 0.00 1 0.00 1 0 25 1.105e-02 5.935e-03 1.900e-03 4.202e-04 2.904640e-01 2.136557e-04 3.473829e-03 -6.000000e+00 6.434589e-03 222.98 -2.00 3.51 -2.00 318.19 0.00e+00 5.094163e-04 3.950567e-05 8.474721e-05 -6.000000e+00 2.870240e-04 278.60 -2.00 20.00 -2.00 317.50 0.00e+00 2.271 0.000 302.00 328.00 3 1.4303e+00 5.6997e-04 2.6917e-02 -6.0000e+00 1.5813e-02 1.2439e-02 6.4877e-04 1.4696e-02 -6.0000e+00 1.7260e-02 -6.0188e-03 4.1369e-04 7.2937e-03 -6.0000e+00 1.0300e-02 -3.6579e-03 2.0901e-04 2.1198e-03 -6.0000e+00 4.3061e-03 9.3879e-03 -5.0882e-05 1.3561e-05 2.7092e-05 -6.0000e+00 3.3929e-04 2.1493e-03 5.2991e-05 12 1 1 12 1 1 100.00 22.29 0.21 0.00215 0.00177 1050 278 1 5 0 39.830 26.94 19.99 22.29 16.23 18.9 963.96 -2155 -3342 -4392 -4085 -3645 -514 -1801 -980 -2370 -3225 -1987 -1034 -25 -1423 -296 -962 7 503 245 443 -299 930 696 303 -447 -787 -1359 -1163 448 868 1546 815 -226 -2591 -1702 -294 -445 -16 -816 -964 -1371 -663 -773 -543 -337 -582 -465 -274 278 1006 1034 811 985 958 778 850 360 285 796 1222 1615 1677 1253 149 -553 -116 802 1220 1222 318 -238 -86 -308 6 -356 -66 360 508 411 -685 -1098 -1635 -1725 -1052 -819 -682 -452 -154 -214 11 309 594 1094 1307 889 575 492 -71 -721 -741 -358 291 637 75 -995 -953 -619 -234 84 114 -244 -332 -21 146 674 982 875 457 -147 -603 -555 -111 123 315 415 525 1288 1296 406 -90 -237 -95 278 155 -122 -275 35 -3 -405 -252 -210 -99 -29 -159 -250 -346 -296 -246 -34 -131 -78 -208 -294 -183 -103 -3 -176 -41 -145 1 82 42 77 -53 164 128 59 -92 -165 -280 -239 87 173 331 190 -53 -621 -414 -73 -118 -5 -302 -404 -620 -311 -371 -261 -162 -278 -218 -127 128 474 519 435 558 568 476 504 216 178 489 758 1048 1117 901 112 -407 -80 552 850 883 257 -207 -77 -270 5 -272 -48 242 340 298 -537 -963 -1574 -1683 -1081 -898 -792 -548 -190 -260 12 327 605 1047 1260 926 635 604 -91 -955 -951 -448 337 722 90 -1281 -1233 -839 -333 127 175 -390 -528 -32 215 920 1347 1163 641 -220 -951 -883 -173 185 454 568 718 1705 1769 570 -136 -375 -154 444 259 -215 -508 63 -6 -743 -469 -376 -172 -50 SS 20231202T173809.2Z 8736.734829 477 1 49.67 2 64.29 194.46 100.67 310.00 0.00 1 0.00 1 0 25 1.227e-02 6.202e-03 1.174e-03 2.721e-04 2.928041e-01 1.416070e-04 3.598637e-03 -6.000000e+00 7.277312e-03 222.98 -2.00 3.51 -2.00 318.02 0.00e+00 4.941206e-04 2.467259e-05 8.057286e-05 -6.000000e+00 3.208537e-04 278.60 -2.00 20.00 -2.00 317.38 0.00e+00 2.291 0.000 302.00 328.00 3 8.1839e-01 3.7494e-04 2.7263e-02 -6.0000e+00 1.7895e-02 1.0979e-02 4.2321e-04 1.5013e-02 -6.0000e+00 1.9412e-02 -1.0346e-02 2.6980e-04 7.5060e-03 -6.0000e+00 1.1579e-02 -1.2459e-03 1.3792e-04 2.2127e-03 -6.0000e+00 4.9802e-03 1.6809e-02 -4.9634e-04 8.7077e-06 2.9353e-05 -6.0000e+00 3.7776e-04 2.9892e-03 -3.0888e-05 11 1 0 11 8 0 98.68 22.29 0.22 0.00299 -0.00074 1492 339 1 5 0 32.730 26.94 20.00 22.29 16.81 19.0 969.82 -3109 -3835 -4775 -5002 -3604 -2134 -1216 -1260 -2974 -4001 -2558 -1408 -547 -532 -576 -648 -80 406 250 447 199 821 971 -2 -274 -1256 -1450 -1045 132 1208 1445 900 -585 -2473 -1839 -538 -121 21 -412 -1083 -1099 -701 -797 -475 -364 -353 -562 -119 302 1222 1131 924 1088 1004 904 834 482 328 802 1131 1553 1704 1111 116 -702 -73 728 1257 1319 270 -200 -242 -255 -249 -387 -121 345 586 356 -612 -1199 -1643 -1739 -1064 -809 -685 -465 -210 -225 -49 308 575 1146 1343 898 684 457 -53 -792 -731 -397 233 734 60 -903 -1052 -591 -318 20 30 -283 -318 -37 266 770 1037 918 447 -108 -695 -505 -49 184 347 473 552 1338 1347 421 -47 -267 -46 276 146 -172 -298 18 -84 -371 -285 -216 -106 900000 -240 -315 -390 -378 -251 -148 -91 -105 -271 -380 -245 -145 -64 -72 -87 -106 -14 72 46 85 38 159 195 0 -61 -290 -327 -222 27 249 321 218 -152 -649 -465 -139 -35 7 -153 -457 -499 -330 -384 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