File name: Pandora51s1_OldFieldNY_20231229_L2Fit_fout2c5d20211018p1-8.txt File generation date: 20240113T081511.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 51 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora51_OF_v5d20190801.txt Instrument calibration file used: Pandora51s1_CF_v5d20211018.txt Level 1 file used: Pandora51s1_OldFieldNY_20231229_L1_smca1c5d20211018p1-8.txt Full location name: Flax Pond NYSDEC (USEPA AQS ID 36-103-0044) Short location name: OldFieldNY Country of location: USA Location latitude [deg]: 40.9635 Location longitude [deg]: -73.1402 Location altitude [m]: 3 Local noon date: 20231229 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 - Full Lab Cal on 1.8 for HCHO First and last pixel inside fitting window: 257 399 Nominal wavelengths inside fitting window [nm]: 305.1342 305.2748 305.4155 305.5562 305.6968 305.8375 305.9781 306.1187 306.2593 306.3999 306.5405 306.6810 306.8216 306.9621 307.1027 307.2432 307.3837 307.5242 307.6647 307.8052 307.9457 308.0861 308.2266 308.3670 308.5074 308.6478 308.7882 308.9286 309.0690 309.2094 309.3497 309.4901 309.6304 309.7707 309.9110 310.0513 310.1916 310.3319 310.4722 310.6124 310.7527 310.8929 311.0331 311.1733 311.3135 311.4537 311.5939 311.7340 311.8742 312.0143 312.1545 312.2946 312.4347 312.5748 312.7149 312.8549 312.9950 313.1350 313.2751 313.4151 313.5551 313.6951 313.8351 313.9751 314.1151 314.2550 314.3950 314.5349 314.6748 314.8147 314.9546 315.0945 315.2344 315.3743 315.5141 315.6540 315.7938 315.9336 316.0734 316.2132 316.3530 316.4928 316.6326 316.7723 316.9120 317.0518 317.1915 317.3312 317.4709 317.6106 317.7503 317.8899 318.0296 318.1692 318.3088 318.4484 318.5880 318.7276 318.8672 319.0068 319.1463 319.2859 319.4254 319.5649 319.7044 319.8439 319.9834 320.1229 320.2624 320.4018 320.5413 320.6807 320.8201 320.9595 321.0989 321.2383 321.3777 321.5170 321.6564 321.7957 321.9351 322.0744 322.2137 322.3530 322.4922 322.6315 322.7708 322.9100 323.0492 323.1885 323.3277 323.4669 323.6061 323.7452 323.8844 324.0235 324.1627 324.3018 324.4409 324.5800 324.7191 324.8582 324.9973 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231229T181128.3Z 8763.757966 478 1 48.81 2 66.61 199.24 115.73 344.47 0.00 1 0.00 1 0 17 1.776e-01 1.363e-02 1.128e-01 6.963e-03 4.155453e-01 3.609977e-03 4.780292e-03 -6.000000e+00 1.037890e-01 223.22 -2.00 3.51 -2.00 319.73 0.00e+00 2.610304e-03 1.051775e-03 5.933826e-04 -6.000000e+00 4.657131e-03 276.31 -2.00 20.00 -2.00 319.14 0.00e+00 2.500 0.000 302.00 328.00 3 4.9345e+00 1.0225e-02 3.2885e-02 -6.0000e+00 2.5532e-01 1.3109e-02 1.2059e-02 2.2119e-02 -6.0000e+00 2.7859e-01 3.6293e-02 9.5495e-03 1.0593e-02 -6.0000e+00 1.6598e-01 -1.9418e-02 4.9514e-03 4.4206e-03 -6.0000e+00 6.9458e-02 1.8064e-04 7.7598e-04 2.2702e-04 4.6998e-05 -6.0000e+00 5.5237e-03 -4.0761e-03 3.1163e-04 12 8 8 10 0 0 99.99 22.27 0.54 -0.00408 0.00175 249 57 1 5 0 195.980 26.94 20.00 22.27 16.88 18.9 971.93 -60229 74518 -56284 900000 -58808 69814 -2176 19873 49950 -44172 72943 -27054 60387 -14695 31382 -4304 43 15964 -23722 27429 -19117 31632 1076 9139 2366 -6952 11017 -17959 29049 -11082 12827 -1426 752 17745 -7664 11295 -12580 12701 -4040 6345 1464 -4104 2424 -9742 7022 -4255 6259 1426 -68 6659 -4442 4598 -3995 6285 -2135 3718 846 -882 2832 -2667 4204 -2331 5513 -1535 2232 157 483 3668 -1583 2902 -2363 -284 297 -398 1658 -2418 2988 -2398 3804 -1361 -885 -1684 -2719 -609 -2512 791 -2108 835 -492 -436 799 -237 2733 586 3462 -394 1502 77 36 291 -990 948 -787 1214 -760 -899 -667 -1001 478 -1264 685 -797 570 -369 95 1211 -574 668 -1281 456 -1231 951 273 87 1685 -1071 2417 222 1503 -397 -269 -220 -339 1106 -693 -17 -233 688 -260 -184 -73 -743 111 -2131 855 -2131 900000 -2033 768 -50 423 859 -1863 1144 -1147 1408 -772 1298 -269 3 947 -2144 1588 -1739 1868 85 730 207 -688 928 -1899 2026 -1161 1187 -166 93 1921 -1015 1319 -1985 1895 -825 1338 344 -1075 615 -2839 1749 -1196 1587 382 -19 1820 -1468 1503 -1524 2289 -855 1477 349 -367 1119 -1125 1746 -1101 2637 -834 1160 80 244 1845 -897 1753 -1614 -194 198 -252 968 -1335 1472 -1263 2072 -890 -634 -1340 -2339 -544 -2439 787 -2253 882 -519 -436 732 -204 2238 502 3065 -408 1713 97 47 372 -1193 1033 -841 1316 -894 -1116 -870 -1390 702 -2037 1142 -1363 930 -571 137 1667 -813 979 -2023 733 -2010 1484 414 127 2362 -1479 3159 309 2236 -651 -455 -386 -618 2087 -1405 -35 -500 1484 -559 -382 -145 -1425 216 SS 20231229T183751.6Z 8763.776292 494 1 4.30 2 68.51 205.47 116.82 350.89 0.00 1 0.00 1 0 25 5.252e-02 7.068e-03 2.648e-02 2.913e-03 4.383868e-01 1.489397e-03 5.162249e-03 -6.000000e+00 3.062090e-02 223.22 -2.00 3.51 -2.00 318.76 0.00e+00 7.907713e-04 3.341892e-04 1.884067e-04 -6.000000e+00 1.351860e-03 276.31 -2.00 20.00 -2.00 318.16 0.00e+00 2.705 0.000 302.00 328.00 3 2.8241e+00 4.0329e-03 3.4889e-02 -6.0000e+00 7.5351e-02 3.2587e-02 4.6399e-03 2.2105e-02 -6.0000e+00 8.2258e-02 -5.6296e-03 3.3482e-03 1.1057e-02 -6.0000e+00 4.9011e-02 -4.9809e-03 1.7570e-03 3.2260e-03 -6.0000e+00 2.0443e-02 1.2089e-03 -6.8342e-04 8.9359e-05 4.0212e-05 -6.0000e+00 1.6129e-03 -8.7469e-04 -4.3842e-06 12 9 1 12 1 1 98.98 22.28 0.23 -0.00087 -0.00601 11 31 1 5 0 357.670 26.94 20.00 22.28 17.83 18.7 977.55 -5188 -17164 -9953 8030 -31917 19088 -18182 -2745 -24331 -7166 -12891 -12198 10984 -5907 4174 -6052 2536 -570 2705 3218 -5278 6420 -6901 4216 -4405 -436 -3915 -1758 1466 -5038 6115 -1651 495 -3313 273 -2573 -50 1672 -3669 -285 -3015 850 -892 739 68 -1057 304 -1721 897 637 1272 645 537 2093 474 2089 -159 182 -36 1018 1781 1839 2209 518 65 180 808 1101 1164 587 -455 353 -431 568 -656 218 247 -461 348 -1281 -493 -2215 -2422 -1384 -544 -382 -636 286 -307 540 377 435 1199 896 847 238 1072 231 -682 -723 -930 -216 501 -4 -1630 -756 -840 -528 80 200 409 -76 62 276 761 385 574 236 62 -315 -601 12 27 425 464 327 985 1040 588 -184 89 -308 233 102 -450 -44 -166 123 -290 4 -68 -208 -311 -155 -628 -342 223 -1216 474 -679 -99 -1193 -313 -630 -671 572 -424 317 -554 230 -57 276 339 -614 678 -856 516 -605 -59 -544 -237 190 -721 903 -287 91 -624 50 -502 -11 399 -1076 -93 -1072 306 -337 278 26 -410 116 -678 353 259 558 302 270 1072 257 1145 -88 102 -20 559 999 1103 1446 357 45 119 529 727 828 458 -377 291 -358 449 -490 149 164 -313 253 -1039 -431 -2092 -2409 -1419 -580 -423 -722 327 -348 596 395 431 1154 890 889 272 1303 301 -915 -958 -1189 -262 590 -5 -2055 -979 -1130 -740 116 304 648 -121 96 417 1108 543 819 347 96 -495 -944 19 40 626 662 455 1360 1473 867 -287 146 -512 395 179 -817 -81 -311 233 -545 8 -122 -364 -541 SS 20231229T184720.7Z 8763.782878 497 1 50.17 2 69.31 207.65 117.08 353.23 0.00 1 0.00 1 0 25 3.838e-02 5.139e-03 4.906e-03 3.221e-04 4.527133e-01 1.669229e-04 5.273655e-03 -6.000000e+00 2.237445e-02 223.22 -2.00 3.51 -2.00 319.68 0.00e+00 1.279549e-03 4.866759e-05 2.277915e-04 -6.000000e+00 9.878493e-04 276.31 -2.00 20.00 -2.00 319.09 0.00e+00 2.802 0.000 302.00 328.00 3 2.8454e-01 4.7097e-04 3.6209e-02 -6.0000e+00 5.5058e-02 1.6309e-02 5.5729e-04 2.3116e-02 -6.0000e+00 6.0108e-02 -6.9816e-03 4.5304e-04 1.1601e-02 -6.0000e+00 3.5813e-02 -6.2607e-03 2.3535e-04 3.5866e-03 -6.0000e+00 1.4937e-02 1.3862e-02 -6.2890e-04 1.0138e-05 4.5108e-05 -6.0000e+00 1.1787e-03 -9.1050e-04 -3.2143e-05 10 0 0 10 0 0 16.19 22.28 0.23 -0.00091 -0.00564 2045 464 1 5 0 23.860 26.94 19.99 22.28 17.87 19.0 979.92 -10981 -12366 -13196 -12133 -16614 -9971 -14224 -9982 -13711 -11553 -12097 -8246 -4233 -4490 -1549 -3370 -257 -1232 -350 -954 -2545 -702 -1384 -1260 -2560 -2575 -3519 -3848 -2195 -1076 801 -80 -513 -3249 -2876 -2469 -1969 -987 -1192 -1347 -1664 -732 -910 -434 -207 -281 -219 -346 345 1012 1265 902 1261 1191 934 954 140 90 244 811 1312 1879 1833 816 -37 105 763 1014 1407 654 180 159 -37 -14 -349 -173 -136 41 105 -660 -947 -1523 -1759 -1194 -801 -619 -367 111 86 259 465 586 895 1044 678 530 626 279 -422 -532 -426 -15 431 -93 -1096 -1175 -745 -336 49 155 -38 -114 97 187 474 738 705 304 -187 -689 -530 35 208 296 319 311 1036 1174 415 -33 -260 -178 153 26 -233 -315 39 76 -213 -136 -83 3 51 -193 -241 -262 -225 -306 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