File name: Pandora131s1_Palau_20251005_L2Fit_fout2c11d20221208p1-8.txt File generation date: 20251005T150156.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Katrin Mueller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 131 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora131_OF_v3d20200610.txt Instrument calibration file used: Pandora131s1_CF_v11d20221208.txt Level 1 file used: Pandora131s1_Palau_20251005_L1_smca1c11d20221208p1-8.txt Full location name: Palau Atmospheric Observatory Short location name: Palau Country of location: Palau Location latitude [deg]: 7.3420 Location longitude [deg]: 134.4722 Location altitude [m]: 23 Local noon date: 20251005 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: 1st VP, year 2023 First and last pixel inside fitting window: 228 370 Nominal wavelengths inside fitting window [nm]: 305.0440 305.1849 305.3259 305.4668 305.6077 305.7486 305.8895 306.0303 306.1712 306.3121 306.4529 306.5937 306.7346 306.8754 307.0162 307.1569 307.2977 307.4385 307.5792 307.7200 307.8607 308.0014 308.1421 308.2828 308.4235 308.5642 308.7048 308.8455 308.9861 309.1268 309.2674 309.4080 309.5486 309.6892 309.8297 309.9703 310.1108 310.2514 310.3919 310.5324 310.6729 310.8134 310.9539 311.0944 311.2348 311.3753 311.5157 311.6561 311.7966 311.9370 312.0774 312.2177 312.3581 312.4985 312.6388 312.7791 312.9195 313.0598 313.2001 313.3404 313.4807 313.6209 313.7612 313.9014 314.0417 314.1819 314.3221 314.4623 314.6025 314.7426 314.8828 315.0230 315.1631 315.3032 315.4434 315.5835 315.7236 315.8636 316.0037 316.1438 316.2838 316.4239 316.5639 316.7039 316.8439 316.9839 317.1239 317.2639 317.4038 317.5438 317.6837 317.8236 317.9636 318.1035 318.2433 318.3832 318.5231 318.6629 318.8028 318.9426 319.0824 319.2223 319.3621 319.5018 319.6416 319.7814 319.9211 320.0609 320.2006 320.3403 320.4800 320.6197 320.7594 320.8991 321.0387 321.1784 321.3180 321.4577 321.5973 321.7369 321.8765 322.0160 322.1556 322.2952 322.4347 322.5743 322.7138 322.8533 322.9928 323.1323 323.2717 323.4112 323.5507 323.6901 323.8295 323.9689 324.1084 324.2477 324.3871 324.5265 324.6659 324.8052 324.9445 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251004T211409.4Z 9408.884831 150 1 48.85 2 84.80 95.44 125.37 265.32 0.00 1 0.00 1 0 25 6.370e-01 4.646e-02 4.993e-01 3.822e-02 8.197237e-01 2.232999e-02 8.736105e-03 -6.000000e+00 3.708278e-01 228.26 -2.00 3.05 -2.00 322.35 0.00e+00 -1.239762e-02 1.348844e-02 1.240584e-02 -6.000000e+00 1.982219e-02 294.40 -2.00 20.00 -2.00 321.81 0.00e+00 9.507 0.001 302.00 328.00 3 2.1655e-01 9.8634e-02 1.2366e-01 -6.0000e+00 9.2368e-01 1.1216e+00 1.2737e-01 1.0059e-01 -6.0000e+00 1.0132e+00 -1.4798e+00 8.2585e-02 3.4807e-02 -6.0000e+00 5.9988e-01 5.8610e-01 3.9522e-02 6.0988e-03 -6.0000e+00 2.5951e-01 1.7936e-05 -4.5146e-04 1.0795e-03 1.5117e-04 -6.0000e+00 1.7232e-02 2.2066e-02 0.0000e+00 12 8 8 10 0 0 99.33 17.99 0.69 0.02207 0.01867 31 7 4 8 0 1569.480 20.00 17.99 31.97 26.21 26.11 31.7 996.08 -17284 900000 -74947 240575 -14611 900000 900000 -55523 -26988 16048 900000 23201 -103890 900000 -101312 900000 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-403 4400 -409 900000 2336 900000 -10302 6294 352 10457 -1126 2744 10772 4635 900000 6768 4930 3255 884 3803 3535 5214 5776 5579 5916 -3278 4304 3474 5684 1952 7978 1760 7918 785 3248 1018 -5220 -100 280 5886 -5925 5191 1594 -4669 -426 -1168 3774 5719 3339 -4808 4093 -2153 148 1623 821 -1615 -5972 -176 -4020 8395 -1745 -826 -3391 3251 -5363 -8077 -2359 -686 5505 -8103 6952 -4349 -3169 1906 -8487 -2431 -125 3867 -1182 -1339 -1868 -1403 5038 -178 12412 466 9183 393 1870 2719 1789 3302 -3012 1880 -3193 6500 -5595 4956 -1796 169 -428 -8007 SS 20251004T214435.8Z 9408.905969 156 1 51.70 2 77.29 96.55 132.56 266.01 0.00 1 0.00 1 0 25 5.547e-02 4.258e-03 3.380e-02 1.257e-03 4.632723e-01 6.290171e-04 4.668998e-03 -6.000000e+00 3.050230e-02 228.26 -2.00 3.05 -2.00 320.51 0.00e+00 -1.062670e-04 2.458937e-04 2.669089e-04 -6.000000e+00 1.417237e-03 294.40 -2.00 20.00 -2.00 319.68 0.00e+00 4.420 0.000 302.00 328.00 3 3.3918e-01 2.0164e-03 4.8314e-02 -6.0000e+00 7.5657e-02 1.0724e-02 2.5656e-03 2.1355e-02 -6.0000e+00 8.2166e-02 2.5215e-02 2.1839e-03 1.0367e-02 -6.0000e+00 4.9241e-02 -1.9142e-02 1.1074e-03 2.9591e-03 -6.0000e+00 2.1282e-02 2.9322e-03 -7.9185e-05 3.4231e-05 2.9532e-05 -6.0000e+00 1.3373e-03 1.9955e-02 0.0000e+00 11 1 0 11 8 0 99.91 17.98 0.13 0.01995 0.01936 634 138 2 8 0 77.730 20.00 17.98 35.31 26.21 26.11 32.0 1016.29 -13146 -21731 -26383 -9827 -24203 -2645 -24735 -4974 -20346 -11861 -7641 -17975 -9263 -11550 69 -9236 -3069 -6936 -1771 -5167 -5248 964 -4588 1886 -4076 1368 -2578 -2021 -1866 -840 2060 -719 2386 -2237 -2552 -6110 -1254 -530 -1046 573 -549 696 -1178 441 -1103 -81 -579 -312 68 -1141 717 359 1575 234 265 759 397 565 9 1037 -304 1357 1273 1965 521 -120 -628 -860 336 629 742 80 79 316 190 -164 -312 -897 -894 -252 -481 -346 -1456 -1541 -912 -308 264 68 845 802 909 591 -15 455 588 765 466 793 591 107 -551 -1186 -1030 -420 -390 -871 -761 -828 -317 -8 328 184 352 132 -271 -150 -289 -97 -58 -68 -62 -33 173 192 459 392 153 110 410 482 460 42 -438 -171 -195 -25 -58 130 141 121 88 -206 -353 -123 -254 -344 -104 -264 -23 -292 -57 -315 -182 -114 -320 -168 -265 2 -293 -100 -254 -66 -211 -222 38 -200 85 -215 73 -144 -107 -94 -43 117 -49 179 -187 -199 -482 -105 -49 -122 79 -85 113 -204 76 -195 -14 -104 -56 12 -220 149 83 391 63 75 224 122 172 3 301 -92 447 471 802 222 -48 -240 -330 142 309 401 45 44 169 94 -72 -126 -387 -392 -129 -286 -231 -1064 -1182 -748 -270 244 65 796 727 761 456 -11 330 473 701 486 934 755 135 -649 -1255 -1012 -428 -437 -1032 -945 -1085 -445 -12 551 319 595 211 -403 -210 -410 -145 -94 -115 -106 -54 276 295 674 551 204 152 631 823 843 80 -865 -356 -405 -54 -129 296 321 267 184 -439 -737 SS 20251004T215515.8Z 9408.913377 159 1 38.38 2 74.66 96.97 135.08 266.24 0.00 1 0.00 1 0 25 2.791e-02 4.739e-03 1.268e-02 9.421e-04 3.956951e-01 4.651556e-04 4.042497e-03 -6.000000e+00 1.534467e-02 228.26 -2.00 3.05 -2.00 319.58 0.00e+00 7.777110e-05 1.340027e-04 2.176611e-04 -6.000000e+00 7.130108e-04 294.40 -2.00 20.00 -2.00 318.66 0.00e+00 3.709 0.000 302.00 328.00 3 7.5257e-01 1.3522e-03 4.0691e-02 -6.0000e+00 3.8061e-02 3.4939e-02 1.6194e-03 1.8160e-02 -6.0000e+00 4.1336e-02 6.6085e-03 1.2248e-03 8.7684e-03 -6.0000e+00 2.4772e-02 -1.0490e-02 6.4652e-04 2.4764e-03 -6.0000e+00 1.0705e-02 4.0652e-03 -1.4831e-04 2.5363e-05 2.3848e-05 -6.0000e+00 6.7287e-04 2.0679e-02 0.0000e+00 12 1 1 12 1 1 99.84 17.98 0.19 0.02068 0.01956 313 92 2 8 0 117.350 20.00 17.98 36.95 26.21 26.11 32.2 1024.96 -11136 -4260 -4464 -11148 -7157 -14534 7674 -9385 2499 -12245 -1025 -4413 -3513 1761 -2299 2587 -3794 587 -3446 1925 -1711 -2747 22 -2986 1360 -2479 -4614 -2271 -869 -1176 53 1199 377 633 -4056 -525 -3584 85 -597 -330 -73 -804 59 -1504 -229 -1100 -93 -884 -934 -272 209 1022 438 946 -129 975 621 928 622 174 1138 828 1667 1582 1084 -93 -458 -541 381 977 154 359 -197 427 -26 -53 -387 -951 -54 -476 -121 -869 -1354 -1594 -888 -483 16 282 516 955 643 896 148 633 596 567 618 549 567 -215 -284 -1085 -892 -465 -638 -873 -971 -720 -456 13 102 146 170 85 -172 -120 166 -140 6 -173 -36 -23 57 239 510 706 230 679 409 613 376 110 -235 -146 79 -175 -22 -77 75 -27 75 -340 -394 -238 -96 -106 -267 -146 -307 154 -241 65 -396 -30 -139 -130 75 -121 148 -247 39 -254 141 -134 -215 2 -264 125 -251 -478 -217 -77 -105 5 134 48 84 -523 -63 -493 14 -119 -78 -19 -222 17 -440 -66 -325 -27 -258 -274 -81 68 361 168 385 -55 427 260 417 272 75 504 403 828 862 604 -48 -243 -285 202 601 105 254 -139 286 -16 -32 -211 -506 -31 -320 -86 -694 -1167 -1440 -856 -499 18 316 574 1017 635 806 124 524 542 583 717 666 741 -279 -340 -1265 -970 -527 -797 -1069 -1246 -968 -654 21 172 252 285 134 -248 -163 227 -202 9 -286 -61 -38 89 360 731 1039 320 966 601 989 649 197 -431 -264 153 -356 -46 -162 158 -56 147 -634 -768 SS 20251004T220439.3Z 9408.919900 161 1 52.28 2 72.35 97.36 137.30 266.45 0.00 1 0.00 1 0 25 1.588e-02 4.736e-03 4.204e-03 4.724e-04 3.497630e-01 2.314050e-04 3.590283e-03 -6.000000e+00 8.732545e-03 228.26 -2.00 3.05 -2.00 319.26 0.00e+00 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