File name: Pandora221s1_Palawan_20250921_L2Fit_fwvt1c3d20240201p1-8.txt File generation date: 20250921T160836.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 221 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora221_OF_v3d20220412.txt Instrument calibration file used: Pandora221s1_CF_v3d20240201.txt Level 1 file used: Pandora221s1_Palawan_20250921_L1_smca1c3d20240201p1-8.txt Full location name: Department of Environment and Natural Resources - Provincial Environmental Manag Short location name: Palawan Country of location: Philippines Location latitude [deg]: 9.7915 Location longitude [deg]: 118.7340 Location altitude [m]: 56 Local noon date: 20250921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0602 492.1816 492.3030 492.4243 492.5457 492.6671 492.7884 492.9097 493.0310 493.1523 493.2735 493.3948 493.5160 493.6372 493.7584 493.8796 494.0008 494.1219 494.2430 494.3641 494.4852 494.6063 494.7274 494.8484 494.9694 495.0905 495.2115 495.3324 495.4534 495.5743 495.6953 495.8162 495.9371 496.0579 496.1788 496.2996 496.4205 496.5413 496.6621 496.7828 496.9036 497.0243 497.1451 497.2658 497.3864 497.5071 497.6278 497.7484 497.8690 497.9896 498.1102 498.2308 498.3514 498.4719 498.5924 498.7129 498.8334 498.9539 499.0743 499.1948 499.3152 499.4356 499.5560 499.6763 499.7967 499.9170 500.0373 500.1576 500.2779 500.3982 500.5184 500.6387 500.7589 500.8791 500.9992 501.1194 501.2396 501.3597 501.4798 501.5999 501.7200 501.8400 501.9601 502.0801 502.2001 502.3201 502.4401 502.5600 502.6800 502.7999 502.9198 503.0397 503.1596 503.2794 503.3993 503.5191 503.6389 503.7587 503.8785 503.9982 504.1179 504.2377 504.3574 504.4771 504.5967 504.7164 504.8360 504.9556 505.0752 505.1948 505.3144 505.4339 505.5534 505.6730 505.7925 505.9119 506.0314 506.1508 506.2703 506.3897 506.5091 506.6285 506.7478 506.8672 506.9865 507.1058 507.2251 507.3444 507.4636 507.5829 507.7021 507.8213 507.9405 508.0596 508.1788 508.2979 508.4171 508.5362 508.6552 508.7743 508.8934 509.0124 509.1314 509.2504 509.3694 509.4883 509.6073 509.7262 509.8451 509.9640 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250920T223252.9Z 9394.939502 56 1 51.86 2 81.35 90.78 72.37 88.22 0.00 1 0.00 1 0 22 3.357e-03 3.332e-03 5.109e-04 5.096e-04 1.829597e+04 3.811484e+01 1.156642e+03 -6.000000e+00 1.906569e+02 294.51 -2.00 20.00 -2.00 505.31 0.00e+00 9.412316e-04 1.437967e-05 8.278170e-05 -6.000000e+00 9.618854e-05 294.51 -2.00 20.00 -2.00 500.44 0.00e+00 6.825493e-01 9.948392e-03 9.555827e-02 -6.000000e+00 6.517789e-02 227.85 -2.00 3.06 -2.00 502.03 0.00e+00 6.268 0.000 489.00 513.00 1 5.7853e+00 7.6459e-04 1.2220e-02 -6.0000e+00 5.0168e-03 6.0520e-03 1.9381e-04 2.4298e-03 -6.0000e+00 1.2997e-03 2.2643e-03 4.5903e-04 4.1842e-05 9.6450e-05 -6.0000e+00 3.1231e-04 6.5046e-03 5.4709e-05 10 0 0 10 0 0 83.53 23.60 1.20 0.00650 0.00969 35 6 1 4 0 1481.490 26.11 20.00 23.60 32.05 9.1 953.25 -839 -587 -187 2 301 528 617 612 404 323 152 -74 -414 -406 -506 -467 -211 24 116 131 72 93 172 261 244 502 543 -65 -297 -515 -482 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441 496 704 430 321 45 -133 -79 132 73 178 330 142 195 235 -2 -22 -216 -342 -397 -126 -33 -55 282 285 58 90 149 386 295 256 -13 -263 -422 -447 -459 SQ 20250920T225035.5Z 9394.951799 67 1 52.35 2 76.99 91.55 68.12 88.99 0.00 1 0.00 1 0 15 3.201e-03 3.187e-03 8.353e-04 8.330e-04 1.268215e+04 5.960239e+01 8.194187e+02 -6.000000e+00 1.817687e+02 294.51 -2.00 20.00 -2.00 505.28 0.00e+00 6.574784e-04 2.345315e-05 5.844694e-05 -6.000000e+00 9.172246e-05 294.51 -2.00 20.00 -2.00 500.37 0.00e+00 4.556678e-01 1.629785e-02 6.912573e-02 -6.000000e+00 6.217745e-02 227.85 -2.00 3.06 -2.00 501.97 0.00e+00 4.325 0.000 489.00 513.00 1 6.9900e+00 1.2530e-03 8.6145e-03 -6.0000e+00 4.7854e-03 1.8306e-02 3.1956e-04 1.7309e-03 -6.0000e+00 1.2405e-03 9.2016e-04 9.4530e-04 7.1227e-05 7.1146e-05 -6.0000e+00 2.9786e-04 1.7302e-02 -4.5738e-05 12 1 1 12 1 1 94.90 23.60 1.09 0.01730 0.02386 13 2 1 4 0 3738.630 26.11 20.00 23.60 32.71 9.1 958.00 -823 -560 -226 -101 237 443 566 376 471 54 228 36 -356 -366 -545 -454 -174 63 49 223 114 109 311 386 338 470 462 74 -408 -392 -281 -567 20 65 56 95 224 -27 -139 -175 -12 -13 -51 344 492 454 592 203 23 -233 -531 -718 -611 -521 -164 -154 -31 75 325 241 311 323 320 252 75 8 44 7 -248 -389 -283 -222 48 -30 129 -375 -155 58 -446 -329 -321 -407 -327 -251 -166 -181 -4 -167 223 92 441 286 444 470 408 212 103 -469 -713 -663 -167 -325 -36 -83 -38 -117 -271 -299 -154 -107 -317 150 132 156 315 605 664 298 493 184 -211 -48 125 52 292 255 57 453 263 78 95 -203 -338 -405 -203 77 -210 145 268 -3 279 246 184 147 141 -252 -167 -463 -287 -477 -817 -553 -230 -104 246 467 595 399 498 56 239 38 -364 -377 -560 -460 -178 65 52 237 121 117 332 414 357 495 484 78 -419 -397 -282 -574 21 68 59 101 234 -29 -145 -182 -13 -13 -53 359 518 478 616 209 23 -239 -528 -714 -603 -511 -165 -157 -32 76 337 249 323 330 328 257 78 8 44 7 -246 -382 -276 -219 48 -30 127 -375 -152 56 -434 -319 -306 -392 -316 -246 -162 -177 -4 -166 219 91 428 283 439 457 393 202 95 -432 -645 -607 -150 -303 -35 -80 -38 -116 -266 -290 -149 -104 -314 149 130 153 310 598 665 301 492 180 -208 -46 120 50 283 248 55 438 254 75 90 -193 -320 -383 -193 73 -205 140 263 -3 273 242 182 146 139 -246 -162 -442 -277 -455 SQ 20250920T225531.7Z 9394.955228 70 1 51.97 2 75.78 91.77 66.94 89.21 0.00 1 0.00 1 0 22 2.899e-03 2.879e-03 3.369e-04 3.360e-04 1.211872e+04 2.383241e+01 7.838216e+02 -6.000000e+00 1.646258e+02 294.51 -2.00 20.00 -2.00 505.28 0.00e+00 5.973552e-04 9.472742e-06 5.593953e-05 -6.000000e+00 8.305807e-05 294.51 -2.00 20.00 -2.00 500.40 0.00e+00 3.908935e-01 6.562047e-03 6.686625e-02 -6.000000e+00 5.628403e-02 227.85 -2.00 3.06 -2.00 502.00 0.00e+00 3.980 0.000 489.00 513.00 1 5.3171e+00 5.0462e-04 8.1241e-03 -6.0000e+00 4.3321e-03 1.5839e-02 1.2867e-04 1.6667e-03 -6.0000e+00 1.1224e-03 5.1812e-03 3.5635e-04 2.8828e-05 6.9234e-05 -6.0000e+00 2.6968e-04 1.2406e-02 1.3313e-05 10 0 0 10 0 0 91.40 23.60 1.13 0.01241 0.01488 99 16 1 4 0 524.870 26.11 20.00 23.60 32.89 9.1 959.28 -743 -543 -255 -19 308 410 510 450 337 229 232 -71 -275 -286 -446 -301 -107 51 65 123 97 52 150 226 171 418 459 8 -195 -415 -451 -343 17 145 129 228 166 -107 -207 -178 -111 45 135 314 424 411 400 260 13 -304 -519 -664 -588 -363 -179 -45 52 92 172 152 240 257 371 309 130 111 83 -83 -348 -364 -320 -224 -19 -11 -21 -85 -62 -290 -378 -388 -449 -378 -287 -126 -178 -91 -30 -111 -123 74 286 350 368 447 381 261 58 -337 -533 -739 -483 -338 -10 -29 30 30 -213 -217 -264 -141 -119 83 148 257 397 575 514 351 319 140 -54 52 139 28 181 202 192 241 307 -2 35 -94 -314 -255 -145 -47 -40 134 178 86 132 157 256 258 156 -101 -207 -412 -448 -467 -729 -540 -258 -19 318 431 537 478 357 239 243 -74 -280 -292 -456 -309 -110 53 69 130 102 55 158 238 182 441 482 8 -200 -420 -451 -345 17 152 137 242 174 -111 -216 -185 -116 47 140 329 448 434 418 268 14 -310 -515 -657 -577 -361 -180 -46 53 94 175 155 245 263 381 316 132 113 83 -83 -345 -356 -312 -220 -18 -10 -21 -85 -60 -284 -366 -374 -436 -363 -278 -124 -174 -89 -30 -110 -121 73 280 347 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