File name: Pandora221s1_Palawan_20251113_L2Fit_fout2c3d20240201p1-8.txt File generation date: 20251113T155744.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 221 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora221_OF_v3d20220412.txt Instrument calibration file used: Pandora221s1_CF_v3d20240201.txt Level 1 file used: Pandora221s1_Palawan_20251113_L1_smca1c3d20240201p1-8.txt Full location name: Department of Environment and Natural Resources - Provincial Environmental Manag Short location name: Palawan Country of location: Philippines Location latitude [deg]: 9.7915 Location longitude [deg]: 118.7340 Location altitude [m]: 56 Local noon date: 20251113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0163 305.1575 305.2987 305.4399 305.5811 305.7222 305.8634 306.0045 306.1456 306.2868 306.4279 306.5690 306.7101 306.8511 306.9922 307.1333 307.2743 307.4153 307.5564 307.6974 307.8384 307.9793 308.1203 308.2613 308.4022 308.5432 308.6841 308.8250 308.9659 309.1068 309.2477 309.3886 309.5295 309.6703 309.8112 309.9520 310.0928 310.2336 310.3744 310.5152 310.6560 310.7968 310.9375 311.0782 311.2190 311.3597 311.5004 311.6411 311.7818 311.9225 312.0631 312.2038 312.3444 312.4851 312.6257 312.7663 312.9069 313.0475 313.1880 313.3286 313.4692 313.6097 313.7502 313.8907 314.0312 314.1717 314.3122 314.4527 314.5932 314.7336 314.8740 315.0145 315.1549 315.2953 315.4357 315.5761 315.7164 315.8568 315.9972 316.1375 316.2778 316.4181 316.5584 316.6987 316.8390 316.9793 317.1195 317.2598 317.4000 317.5402 317.6805 317.8207 317.9608 318.1010 318.2412 318.3813 318.5215 318.6616 318.8017 318.9419 319.0820 319.2220 319.3621 319.5022 319.6422 319.7823 319.9223 320.0623 320.2023 320.3423 320.4823 320.6223 320.7623 320.9022 321.0422 321.1821 321.3220 321.4619 321.6018 321.7417 321.8815 322.0214 322.1613 322.3011 322.4409 322.5807 322.7205 322.8603 323.0001 323.1399 323.2796 323.4194 323.5591 323.6988 323.8385 323.9782 324.1179 324.2576 324.3973 324.5369 324.6766 324.8162 324.9558 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251112T223628.4Z 9447.941995 229 1 51.54 2 82.01 109.88 3.81 29.21 0.00 1 0.00 1 0 25 4.189e-01 1.376e-02 1.938e-01 4.154e-03 6.408545e-01 2.137113e-03 6.803282e-03 -6.000000e+00 2.329086e-01 226.95 -2.00 3.06 -2.00 321.07 0.00e+00 3.986748e-03 1.038972e-03 3.582157e-03 -6.000000e+00 1.086422e-02 294.40 -2.00 20.00 -2.00 320.35 0.00e+00 6.713 0.000 302.00 328.00 3 1.4489e+00 7.5186e-03 7.3549e-02 -6.0000e+00 5.7554e-01 2.2201e-01 1.0084e-02 3.5925e-02 -6.0000e+00 6.2540e-01 -2.9621e-01 9.0820e-03 1.7004e-02 -6.0000e+00 3.7541e-01 1.1107e-01 4.4079e-03 4.3682e-03 -6.0000e+00 1.6143e-01 9.5701e-05 -6.7492e-04 1.0855e-04 7.5993e-05 -6.0000e+00 1.0570e-02 1.8004e-02 -4.6857e-05 12 8 8 10 0 0 47.53 23.41 0.40 0.01800 0.01293 53 8 1 5 0 972.420 26.00 20.00 23.41 31.08 9.7 948.29 -45598 -143741 -205578 -109445 -102407 -129801 -109464 -151145 78100 68350 -113884 -147534 -98833 -96976 82304 -42624 -6350 -63136 -18249 -57219 -62590 -32356 42820 -4435 -48457 -47342 -21554 -6618 -33913 -11791 -44391 -16539 6116 -5809 -31006 -1832 -7307 -13342 5862 12957 7017 -2896 1463 11727 3979 -11129 3597 6665 15036 5414 6650 6169 7026 7212 13507 11796 7932 5607 6058 4485 -312 3441 4433 6879 4097 3308 3816 -6530 2545 6488 7032 3288 2911 3127 4073 -1462 -3790 -3796 -3503 -2230 -821 -987 -3678 -1497 -890 -1706 -289 184 880 803 674 -1869 -1194 -1798 -1884 -1586 5 1054 -747 -229 -764 -2128 -2775 -904 -2187 -790 -857 -1142 -105 681 809 1470 536 515 -194 -8 -1116 -331 132 160 686 478 1249 761 764 177 -301 -111 773 954 625 192 -508 -360 -294 -359 399 276 202 -330 11 -784 -477 -202 -2012 -5829 -1169 -905 -1434 -1048 -2449 316 277 -1594 -3151 -1638 -2036 400 -881 -103 -1995 -399 -1947 -2307 -865 555 -101 -1826 -1860 -672 -172 -1113 -330 -2068 -697 240 -282 -1834 -78 -361 -822 366 913 594 -290 148 1102 408 -1361 388 718 1559 656 889 932 1150 1288 2407 2217 1603 1156 1202 887 -67 783 1142 1973 1279 1004 1136 -2217 868 2489 2977 1510 1329 1344 1582 -535 -1323 -1341 -1391 -1052 -407 -563 -2371 -995 -633 -1313 -230 151 719 631 492 -1311 -799 -1250 -1485 -1455 5 1159 -914 -277 -867 -2203 -2626 -859 -2307 -865 -995 -1435 -144 962 1270 2422 888 823 -295 -12 -1668 -518 219 258 1172 786 1982 1171 1130 255 -420 -164 1297 1669 1203 394 -1030 -776 -684 -823 924 656 479 -747 25 -1695 -1001 SS 20251112T225120.2Z 9447.952317 234 1 51.72 2 78.57 110.74 3.69 332.31 0.00 1 0.00 1 0 17 1.666e-01 7.862e-03 2.523e-02 1.499e-03 4.985383e-01 7.482737e-04 5.103208e-03 -6.000000e+00 9.262656e-02 226.95 -2.00 3.06 -2.00 319.85 0.00e+00 1.954197e-03 2.435141e-04 1.043738e-03 -6.000000e+00 4.320306e-03 294.40 -2.00 20.00 -2.00 318.98 0.00e+00 4.876 0.000 302.00 328.00 3 1.6142e+00 2.2205e-03 5.2880e-02 -6.0000e+00 2.2889e-01 2.5526e-02 2.7175e-03 2.3099e-02 -6.0000e+00 2.4871e-01 -5.1549e-02 2.1917e-03 1.1428e-02 -6.0000e+00 1.4929e-01 1.5401e-02 1.1430e-03 3.3377e-03 -6.0000e+00 6.4207e-02 5.3220e-04 -3.5763e-04 3.9854e-05 3.6461e-05 -6.0000e+00 4.2031e-03 1.7451e-02 -3.7937e-05 11 8 0 10 0 0 50.68 23.40 0.28 0.01745 0.01476 126 20 1 5 0 410.450 26.00 20.00 23.40 31.99 9.7 953.96 -58484 -59675 -57994 -45091 -39661 -63065 -65597 -57873 -47203 -20428 -60985 -45307 -38867 -27298 -5784 -14070 -9790 -17371 -3361 -11703 -6530 -4924 337 -7178 -5992 -8858 -3609 -7300 -5720 -1962 -8507 794 -1542 -581 -11231 -4048 -4496 -1856 454 556 1125 792 1810 -14 832 -793 1064 72 644 -411 3535 2206 973 2111 2438 2542 1479 1714 826 447 870 1642 3002 2902 1965 993 356 -2474 1039 1132 1760 1024 471 466 447 -780 -1723 -2720 -1989 -1075 -1646 -513 -2495 -1710 -978 -436 214 451 922 584 701 171 -524 -794 -171 -456 283 845 61 -240 -328 -1388 -1655 -175 -1393 -836 -702 -881 -250 523 637 691 601 333 -96 -172 0 -250 266 127 134 351 578 304 771 335 -115 794 491 209 300 -83 -478 -312 -66 -218 55 468 56 -91 -4 -614 -462 -958 -1160 -1204 -811 -603 -1162 -1333 -1235 -1035 -376 -1721 -1166 -1142 -890 -187 -588 -434 -904 -164 -657 -361 -266 18 -448 -398 -642 -256 -517 -379 -129 -691 68 -155 -63 -1281 -415 -513 -242 71 106 218 164 391 -3 187 -185 247 17 156 -104 951 669 323 753 916 987 601 695 329 176 352 724 1348 1459 1037 500 174 -1257 554 704 1111 682 314 296 283 -447 -918 -1445 -1152 -728 -1196 -418 -2098 -1499 -917 -437 210 455 931 610 676 153 -447 -685 -163 -464 326 1038 82 -317 -405 -1676 -1843 -198 -1645 -1032 -912 -1225 -351 806 1011 1139 973 514 -147 -249 0 -387 416 210 220 558 895 480 1157 486 -161 1145 752 354 520 -152 -863 -594 -129 -446 114 994 119 -187 -8 -1199 -880 SS 20251112T225710.3Z 9447.956369 237 1 52.02 2 77.23 111.09 4.50 316.24 0.00 1 0.00 1 0 17 1.025e-01 7.267e-03 1.564e-02 1.237e-03 4.576600e-01 6.117928e-04 4.670052e-03 -6.000000e+00 5.699211e-02 226.95 -2.00 3.06 -2.00 319.38 0.00e+00 1.405992e-03 1.714873e-04 6.355019e-04 -6.000000e+00 2.658331e-03 294.40 -2.00 20.00 -2.00 318.47 0.00e+00 4.400 0.000 302.00 328.00 3 1.7691e+00 1.7513e-03 4.7807e-02 -6.0000e+00 1.4083e-01 1.1829e-02 2.0825e-03 2.0869e-02 -6.0000e+00 1.5303e-01 -3.6319e-02 1.5716e-03 1.0198e-02 -6.0000e+00 9.1859e-02 1.1235e-02 8.3275e-04 2.9388e-03 -6.0000e+00 3.9505e-02 7.4470e-04 -3.4616e-04 3.3126e-05 2.9940e-05 -6.0000e+00 2.5863e-03 1.7618e-02 -4.4590e-05 11 8 0 10 0 0 84.33 23.40 0.34 0.01762 0.01502 139 22 1 5 0 374.210 26.00 19.99 23.40 32.31 9.7 956.28 -22805 -41459 -33504 -26441 -27644 -42163 -42767 -39058 -27847 -17928 -30490 -29043 -24226 -19046 -2021 -6422 -6141 -6340 -2046 -3851 -4139 -7150 304 -2150 -3276 -4962 -1733 -4717 -4760 -814 -6701 171 -297 1247 -6559 -4094 -2986 -1605 1125 1182 810 113 1429 587 1395 369 1505 -194 597 846 1899 1571 1588 1684 1418 1669 1510 826 13 103 380 1542 1693 3202 1172 146 -162 -2052 567 782 1200 738 38 549 191 -760 -1562 -2799 -1657 -1246 -1435 -606 -2249 -1436 -693 -339 113 663 1106 774 726 282 -366 -448 -227 -280 310 839 173 -240 -423 -1335 -1581 -178 -934 -930 -839 -758 -283 394 774 691 435 301 -162 97 -125 -191 238 70 -57 450 674 314 820 157 -125 760 345 246 129 -65 -538 -87 -158 -115 127 452 90 -170 97 -694 -483 -432 -1100 -885 -638 -600 -1012 -1109 -1107 -806 -515 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