File name: Pandora221s1_Palawan_20260610_L2Fit_fwvt1c3d20240201p1-8.txt File generation date: 20260610T161549.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 221 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora221_OF_v3d20220412.txt Instrument calibration file used: Pandora221s1_CF_v3d20240201.txt Level 1 file used: Pandora221s1_Palawan_20260610_L1_smca1c3d20240201p1-8.txt Full location name: Department of Environment and Natural Resources - Provincial Environmental Manag Short location name: Palawan Country of location: Philippines Location latitude [deg]: 9.7915 Location longitude [deg]: 118.7340 Location altitude [m]: 56 Local noon date: 20260610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0602 492.1816 492.3030 492.4243 492.5457 492.6671 492.7884 492.9097 493.0310 493.1523 493.2735 493.3948 493.5160 493.6372 493.7584 493.8796 494.0008 494.1219 494.2430 494.3641 494.4852 494.6063 494.7274 494.8484 494.9694 495.0905 495.2115 495.3324 495.4534 495.5743 495.6953 495.8162 495.9371 496.0579 496.1788 496.2996 496.4205 496.5413 496.6621 496.7828 496.9036 497.0243 497.1451 497.2658 497.3864 497.5071 497.6278 497.7484 497.8690 497.9896 498.1102 498.2308 498.3514 498.4719 498.5924 498.7129 498.8334 498.9539 499.0743 499.1948 499.3152 499.4356 499.5560 499.6763 499.7967 499.9170 500.0373 500.1576 500.2779 500.3982 500.5184 500.6387 500.7589 500.8791 500.9992 501.1194 501.2396 501.3597 501.4798 501.5999 501.7200 501.8400 501.9601 502.0801 502.2001 502.3201 502.4401 502.5600 502.6800 502.7999 502.9198 503.0397 503.1596 503.2794 503.3993 503.5191 503.6389 503.7587 503.8785 503.9982 504.1179 504.2377 504.3574 504.4771 504.5967 504.7164 504.8360 504.9556 505.0752 505.1948 505.3144 505.4339 505.5534 505.6730 505.7925 505.9119 506.0314 506.1508 506.2703 506.3897 506.5091 506.6285 506.7478 506.8672 506.9865 507.1058 507.2251 507.3444 507.4636 507.5829 507.7021 507.8213 507.9405 508.0596 508.1788 508.2979 508.4171 508.5362 508.6552 508.7743 508.8934 509.0124 509.1314 509.2504 509.3694 509.4883 509.6073 509.7262 509.8451 509.9640 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260609T220229.9Z 9656.918402 191 1 19.26 2 86.64 67.24 18.78 101.60 0.00 1 0.00 1 0 22 5.560e-03 5.472e-03 1.994e-04 1.989e-04 3.239881e+04 1.617149e+01 1.984508e+03 -6.000000e+00 3.161795e+02 294.86 -2.00 20.00 -2.00 505.39 0.00e+00 1.689987e-03 5.641171e-06 1.366934e-04 -6.000000e+00 1.594754e-04 294.86 -2.00 20.00 -2.00 500.63 0.00e+00 1.359477e+00 3.857089e-03 1.557500e-01 -6.000000e+00 1.080119e-01 227.97 -2.00 3.06 -2.00 502.19 0.00e+00 12.664 0.002 489.00 513.00 1 1.9140e+00 2.9605e-04 2.2603e-02 -6.0000e+00 8.3140e-03 -2.6619e-02 7.4092e-05 4.1324e-03 -6.0000e+00 2.1551e-03 4.0586e-02 1.1762e-03 1.4536e-05 1.5170e-04 -6.0000e+00 5.1743e-04 7.7967e-03 7.6205e-06 12 9 9 12 1 1 74.30 23.37 2.02 0.00780 0.01596 223 95 1 4 0 85.980 25.90 20.00 23.37 31.57 12.0 951.64 -1352 -957 -319 167 571 836 978 931 707 468 219 -128 -541 -694 -750 -610 -256 75 225 282 189 118 239 364 447 659 695 111 -497 -883 -914 -763 -182 296 444 347 157 -166 -358 -308 -256 53 311 589 678 678 564 367 -45 -557 -991 -1230 -1134 -691 -164 143 341 360 396 431 528 624 640 531 224 104 -70 -208 -580 -730 -713 -439 -213 -42 -101 -281 -470 -628 -653 -568 -403 -337 -311 -191 -68 -108 -294 -291 -40 232 660 995 1038 904 704 485 251 -267 -946 -1336 -1229 -1003 -501 -117 214 218 -157 -273 -304 -289 -284 -156 -26 114 487 973 1108 724 348 -96 -417 -311 193 443 645 730 503 370 251 -215 -382 -431 -560 -630 -258 -185 -55 264 335 289 290 302 443 593 533 179 -263 -682 -818 -696 -1279 -906 -307 163 564 843 990 952 723 473 219 -127 -538 -683 -738 -605 -254 75 231 288 195 121 246 378 460 678 712 114 -507 -876 -913 -757 -184 302 458 360 163 -172 -367 -314 -263 54 320 613 712 713 590 380 -47 -562 -989 -1223 -1121 -691 -166 147 353 375 411 446 548 643 662 549 230 106 -71 -211 -582 -724 -705 -437 -214 -42 -101 -283 -464 -617 -632 -553 -393 -326 -303 -186 -68 -108 -293 -285 -39 226 647 980 1016 868 662 438 223 -233 -819 -1157 -1083 -898 -464 -112 211 217 -157 -270 -300 -289 -284 -156 -26 113 486 968 1119 739 356 -98 -420 -309 189 435 638 718 499 367 249 -214 -373 -421 -548 -613 -254 -185 -55 268 342 297 303 314 462 615 556 185 -271 -696 -833 -715 SQ 20260609T221154.4Z 9656.924935 194 1 11.64 2 84.50 67.57 16.54 103.40 0.00 1 0.00 1 0 22 4.373e-03 4.318e-03 1.269e-04 1.266e-04 2.445239e+04 9.831153e+00 1.525271e+03 -6.000000e+00 2.486743e+02 294.86 -2.00 20.00 -2.00 505.35 0.00e+00 1.176313e-03 3.585224e-06 1.029067e-04 -6.000000e+00 1.254253e-04 294.86 -2.00 20.00 -2.00 500.56 0.00e+00 9.985027e-01 2.459472e-03 1.222141e-01 -6.000000e+00 8.495738e-02 227.97 -2.00 3.06 -2.00 502.13 0.00e+00 9.115 0.001 489.00 513.00 1 1.0638e+00 1.8897e-04 1.6803e-02 -6.0000e+00 6.5393e-03 -1.6694e-02 4.7564e-05 3.1822e-03 -6.0000e+00 1.6953e-03 1.6409e-01 1.0600e-03 9.8730e-06 1.2462e-04 -6.0000e+00 4.0695e-04 8.7829e-03 -4.2178e-06 11 8 0 10 0 0 -9.98 23.38 1.48 0.00878 0.01614 517 81 1 4 0 22.510 26.00 20.00 23.38 31.90 11.9 953.19 -1055 -746 -240 117 484 654 779 744 569 377 213 -42 -378 -520 -577 -457 -151 100 183 187 118 62 192 284 360 553 591 89 -322 -696 -736 -612 -98 206 299 306 114 -142 -321 -252 -204 32 234 459 555 552 478 307 6 -416 -780 -993 -933 -580 -194 23 258 236 276 275 381 463 500 412 194 75 -15 -192 -466 -575 -515 -349 -116 19 -38 -166 -320 -482 -564 -554 -483 -410 -342 -163 -92 -165 -195 -196 -51 133 484 733 735 748 583 378 162 -301 -821 -1084 -922 -712 -276 -82 124 87 -188 -277 -262 -232 -252 -72 109 173 477 803 862 586 342 21 -221 -86 175 282 383 434 279 315 315 -72 -175 -231 -402 -473 -136 -131 -15 257 303 199 240 254 371 447 391 48 -273 -604 -681 -572 -1013 -717 -235 117 488 663 793 765 584 383 216 -43 -381 -518 -574 -459 -151 101 188 194 123 64 200 293 374 574 611 93 -330 -702 -736 -616 -99 214 310 319 119 -147 -330 -256 -208 33 244 477 582 579 499 316 6 -423 -781 -975 -923 -573 -195 23 264 244 284 282 392 479 519 427 199 76 -15 -192 -466 -569 -507 -347 -117 19 -38 -165 -315 -473 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11 8 0 10 0 0 -1.98 23.38 1.48 0.01072 0.01863 517 81 1 4 0 22.510 26.00 20.00 23.38 31.90 11.9 953.55 -1073 -753 -244 123 483 664 784 723 567 361 224 -57 -376 -511 -592 -484 -166 78 185 180 149 106 209 284 337 551 574 87 -350 -674 -738 -634 -107 234 324 286 123 -148 -288 -279 -217 24 255 443 538 542 474 314 3 -408 -796 -997 -916 -571 -193 49 256 236 277 286 387 467 490 424 210 94 -19 -187 -496 -560 -516 -330 -109 -18 -43 -189 -275 -479 -576 -524 -468 -437 -356 -197 -120 -148 -176 -200 -70 132 480 757 755 747 593 375 170 -316 -803 -1060 -939 -698 -268 -70 152 79 -189 -297 -255 -244 -239 -50 61 177 436 792 866 598 358 62 -221 -114 187 268 384 439 276 315 306 -89 -163 -213 -410 -467 -174 -124 -14 245 304 210 229 263 391 460 353 52 -281 -587 -689 -555 -1018 -726 -239 123 487 674 800 746 584 367 228 -58 -374 -510 -590 -487 -166 79 190 187 155 110 216 294 351 573 594 90 -354 -672 -739 -632 -109 240 337 298 128 -153 -296 -285 -222 25 262 461 565 569 495 324 3 -415 -798 -981 -907 -565 -194 50 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