File name: Pandora89s1_PaloDuroTX_20250831_L2Fit_fwvt1c2d20241101p1-8.txt
File generation date: 20250901T065716.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Kevin Mishoe
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 89
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora89_OF_v3d20240314.txt
Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt
Level 1 file used: Pandora89s1_PaloDuroTX_20250831_L1_smca1c2d20241101p1-8.txt
Full location name: Palo Duro, TX
Short location name: PaloDuroTX
Country of location: United States
Location latitude [deg]: 34.8806
Location longitude [deg]: -101.6647
Location altitude [m]: 1056
Local noon date: 20250831
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based clearance session 1
First and last pixel inside fitting window: 1615 1765
Nominal wavelengths inside fitting window [nm]: 492.0559 492.1768 492.2976 492.4185 492.5393 492.6601 492.7809 492.9016 493.0224 493.1431 493.2638 493.3845 493.5052 493.6258 493.7465 493.8671 493.9877 494.1083 494.2289 494.3494 494.4700 494.5905 494.7110 494.8315 494.9520 495.0724 495.1929 495.3133 495.4337 495.5541 495.6745 495.7948 495.9152 496.0355 496.1558 496.2761 496.3963 496.5166 496.6368 496.7570 496.8773 496.9974 497.1176 497.2378 497.3579 497.4780 497.5981 497.7182 497.8383 497.9583 498.0783 498.1983 498.3183 498.4383 498.5583 498.6782 498.7982 498.9181 499.0380 499.1578 499.2777 499.3975 499.5174 499.6372 499.7570 499.8767 499.9965 500.1162 500.2360 500.3557 500.4754 500.5950 500.7147 500.8343 500.9539 501.0735 501.1931 501.3127 501.4323 501.5518 501.6713 501.7908 501.9103 502.0298 502.1492 502.2686 502.3880 502.5074 502.6268 502.7462 502.8655 502.9849 503.1042 503.2235 503.3427 503.4620 503.5812 503.7005 503.8197 503.9389 504.0580 504.1772 504.2963 504.4155 504.5346 504.6536 504.7727 504.8918 505.0108 505.1298 505.2488 505.3678 505.4868 505.6057 505.7247 505.8436 505.9625 506.0813 506.2002 506.3190 506.4379 506.5567 506.6755 506.7943 506.9130 507.0318 507.1505 507.2692 507.3879 507.5065 507.6252 507.7438 507.8625 507.9811 508.0996 508.2182 508.3368 508.4553 508.5738 508.6923 508.8108 508.9293 509.0477 509.1661 509.2845 509.4029 509.5213 509.6397 509.7580 509.8763 509.9947
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250831T125018.4Z 9374.534935 54 1 9.82 2 84.50 83.55 172.38 12.56 0.00 1 0.00 1 0 22 4.435e-03 4.397e-03 1.251e-04 1.250e-04 1.507664e+04 9.006858e+00 1.010730e+03 -6.000000e+00 2.499339e+02 286.70 -2.00 20.00 -2.00 505.34 0.00e+00 1.909721e-03 3.489187e-06 1.234033e-04 -6.000000e+00 1.254300e-04 286.70 -2.00 20.00 -2.00 500.67 0.00e+00 9.165745e-01 2.450517e-03 8.837183e-02 -6.000000e+00 8.759514e-02 229.60 -2.00 3.36 -2.00 502.23 0.00e+00 9.155 0.012 489.00 513.00 1 8.6712e-01 1.8793e-04 1.4238e-02 -6.0000e+00 6.7253e-03 -2.7465e-02 4.7324e-05 2.3274e-03 -6.0000e+00 1.7408e-03 2.3010e-01 3.3587e-03 1.1253e-05 1.0904e-04 -6.0000e+00 4.4482e-04 2.1061e-02 4.6144e-04 11 8 0 10 0 0 9.91 26.42 2.07 0.02106 0.04436 502 54 1 4 0 19.540 34.00 20.00 26.42 27.42 6.0 963.37 -747 -383 -30 418 845 983 945 891 757 597 222 -91 -219 -390 -447 -179 11 -14 -5 136 181 152 306 350 403 431 93 -329 -491 -640 -749 -378 24 -48 48 197 25 -219 -245 -147 -32 152 343 494 529 565 443 121 -310 -666 -936 -1064 -845 -487 -308 -105 40 108 234 342 359 305 306 175 27 -111 -351 -560 -694 -657 -598 -448 -199 -135 -227 -266 -231 -365 -335 -278 -286 -186 14 39 -196 -258 -200 -186 -119 28 249 359 314 356 398 163 -168 -517 -985 -1103 -869 -533 -247 -250 -302 -314 -374 -297 -169 -240 -196 90 327 515 843 1018 776 448 238 83 107 316 537 537 504 562 464 442 417 147 -93 -139 -357 -387 -116 -21 -41 253 391 305 384 433 443 384 261 -64 -348 -589 -706 -506 900000 -715 -369 -29 416 848 995 958 904 769 599 223 -90 -216 -385 -443 -178 11 -14 -5 139 185 156 315 359 414 442 96 -335 -489 -633 -743 -377 25 -49 50 203 26 -223 -249 -149 -32 156 354 511 549 584 454 123 -313 -662 -927 -1042 -831 -485 -311 -108 41 111 239 350 370 313 314 179 28 -113 -351 -560 -686 -650 -593 -444 -199 -135 -226 -264 -226 -356 -325 -270 -279 -181 13 39 -194 -256 -197 -184 -118 28 247 356 313 350 382 154 -157 -480 -904 -1011 -803 -501 -239 -245 -301 -313 -370 -294 -167 -239 -196 90 327 516 847 1025 786 457 241 83 107 312 528 532 502 557 461 438 413 145 -92 -137 -349 -380 -114 -21 -41 256 398 312 394 447 458 397 269 -65 -352 -593 -708 -512 900000
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SQ 20250831T125038.1Z 9374.535163 54 3 9.82 2 84.44 83.60 172.37 13.07 0.00 1 0.00 1 0 22 4.396e-03 4.358e-03 1.234e-04 1.233e-04 1.491197e+04 8.875589e+00 1.000499e+03 -6.000000e+00 2.477583e+02 286.70 -2.00 20.00 -2.00 505.35 0.00e+00 1.885776e-03 3.442372e-06 1.221194e-04 -6.000000e+00 1.243363e-04 286.70 -2.00 20.00 -2.00 500.67 0.00e+00 9.119849e-01 2.416972e-03 8.767297e-02 -6.000000e+00 8.682371e-02 229.60 -2.00 3.36 -2.00 502.23 0.00e+00 9.070 0.011 489.00 513.00 1 8.5115e-01 1.8537e-04 1.4106e-02 -6.0000e+00 6.6662e-03 -2.7229e-02 4.6682e-05 2.3079e-03 -6.0000e+00 1.7253e-03 2.3655e-01 3.2549e-03 1.1112e-05 1.0760e-04 -6.0000e+00 4.4091e-04 1.8643e-02 4.8231e-04 11 8 0 10 0 0 10.74 26.42 2.06 0.01864 0.04122 502 54 1 4 0 19.540 34.00 20.00 26.42 27.51 6.0 964.11 -746 -395 -30 408 842 999 942 887 760 592 226 -126 -184 -362 -404 -180 51 8 20 124 170 140 294 339 386 412 71 -311 -490 -662 -765 -374 21 -56 51 196 24 -194 -234 -161 -49 138 362 504 525 548 413 120 -292 -666 -906 -1063 -835 -507 -321 -116 39 132 209 328 363 319 308 168 14 -108 -333 -579 -701 -640 -585 -457 -188 -118 -249 -272 -222 -350 -336 -294 -273 -188 11 61 -213 -270 -205 -184 -118 77 268 363 290 350 408 153 -146 -515 -967 -1118 -856 -527 -283 -259 -298 -294 -367 -292 -177 -237 -190 82 290 498 824 997 769 446 240 77 93 330 528 506 498 572 478 453 379 151 -75 -109 -343 -350 -91 -48 -20 258 363 303 362 445 452 375 233 -56 -361 -600 -697 -463 900000 -713 -381 -29 405 844 1010 955 900 772 594 227 -125 -182 -356 -400 -178 51 9 20 126 174 144 302 348 397 422 73 -316 -489 -654 -759 -373 21 -58 52 202 24 -198 -239 -163 -50 141 373 521 545 567 423 123 -295 -668 -896 -1041 -820 -504 -323 -118 40 135 214 336 374 327 316 172 14 -110 -334 -579 -693 -632 -579 -452 -188 -118 -248 -270 -217 -341 -326 -285 -266 -183 11 60 -210 -267 -202 -182 -116 76 266 360 289 344 391 145 -136 -477 -886 -1025 -790 -495 -273 -255 -296 -293 -363 -290 -174 -236 -190 83 290 499 828 1004 786 455 245 77 93 326 520 501 496 566 474 449 375 149 -74 -107 -335 -344 -90 -48 -20 261 370 310 371 459 467 388 240 -58 -365 -604 -699 -467 900000
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