File name: Pandora89s1_PaloDuroTX_20251027_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20251028T063814.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20251027_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20251027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251027T154352.5Z 9431.655469 125 1 48.56 2 62.07 132.86 123.58 102.86 0.00 1 0.00 1 0 17 1.070e-02 7.405e-03 1.326e-03 5.932e-04 2.464312e-01 2.947706e-04 2.790452e-03 -6.000000e+00 6.018323e-03 225.31 -2.00 3.36 -2.00 316.55 0.00e+00 4.926794e-04 3.579514e-05 4.797704e-05 -6.000000e+00 2.687176e-04 281.16 -2.00 20.00 -2.00 315.87 0.00e+00 2.125 0.000 302.00 328.00 3 2.9227e+00 7.6484e-04 2.2138e-02 -6.0000e+00 1.4876e-02 1.1948e-02 8.5984e-04 1.1848e-02 -6.0000e+00 1.6199e-02 -7.8340e-03 5.0404e-04 5.8262e-03 -6.0000e+00 9.6580e-03 2.3166e-03 2.4134e-04 1.7023e-03 -6.0000e+00 4.1457e-03 3.3070e-03 1.3442e-03 1.6636e-05 1.8734e-05 -6.0000e+00 2.8756e-04 7.5014e-02 0.0000e+00 12 9 1 12 9 1 100.00 25.54 0.43 0.07501 0.08511 741 89 1 5 0 65.430 33.50 20.00 25.54 21.83 6.0 922.10 -220 -685 -1999 -2510 -3782 -1936 -1108 -424 -1117 -2376 -1593 -1383 -107 1112 564 1344 1341 1197 1925 891 1151 1634 1493 1105 1046 444 -80 -652 785 635 1243 1083 -1369 -2995 -3092 -2648 -1890 -862 -458 -602 -250 -515 -634 184 -257 -88 -568 -1124 -402 333 355 698 627 711 994 450 3 -170 -253 788 1047 1788 1748 78 -217 -1203 -1214 159 75 527 918 930 1032 145 -375 -1229 -1796 -1339 -1432 -919 -1179 -1767 -1023 -487 189 632 1158 1397 1089 736 -168 -706 -589 -528 -252 604 1073 513 6 -387 -996 -1011 -459 -1145 -815 -819 -555 341 703 1131 596 428 -124 -741 -582 -779 -252 119 134 114 589 506 302 388 -461 -163 252 91 15 -163 -139 -274 112 76 222 717 647 392 58 -221 -771 -928 -36 -116 -351 -392 -573 -305 -194 -82 -227 -482 -329 -290 -25 296 165 407 420 390 643 305 389 562 543 388 381 162 -30 -227 266 229 479 415 -549 -1134 -1255 -1075 -889 -445 -274 -392 -157 -334 -414 118 -166 -56 -378 -735 -262 228 241 499 472 550 781 362 2 -134 -198 632 842 1550 1610 72 -184 -958 -1012 130 70 501 904 912 972 136 -318 -1017 -1422 -1110 -1252 -897 -1193 -1913 -1082 -550 227 754 1416 1706 1279 846 -177 -728 -589 -560 -278 734 1358 689 8 -479 -1206 -1160 -547 -1414 -1057 -1111 -746 476 992 1672 892 615 -175 -1014 -749 -1005 -339 162 195 169 858 720 412 529 -604 -214 332 122 20 -232 -202 -406 163 118 362 1135 1048 641 92 -357 -1209 -1426 SS 20251027T154859.8Z 9431.659026 128 1 0.86 2 61.31 133.98 122.60 103.42 0.00 1 0.00 1 0 17 1.154e-02 8.661e-03 7.250e-03 4.157e-03 2.404631e-01 2.082913e-03 2.704972e-03 -6.000000e+00 6.491940e-03 225.31 -2.00 3.36 -2.00 315.82 0.00e+00 6.397740e-05 2.130171e-04 5.857736e-05 -6.000000e+00 2.899230e-04 281.16 -2.00 20.00 -2.00 315.17 0.00e+00 2.073 0.000 302.00 328.00 3 2.5884e+00 5.3509e-03 2.1545e-02 -6.0000e+00 1.6047e-02 1.1165e-02 5.9939e-03 1.1419e-02 -6.0000e+00 1.7475e-02 -9.4705e-03 3.4558e-03 5.6193e-03 -6.0000e+00 1.0419e-02 4.2980e-03 1.5922e-03 1.5887e-03 -6.0000e+00 4.4713e-03 4.8881e-03 1.1848e-03 1.1554e-04 1.8233e-05 -6.0000e+00 3.1026e-04 7.6198e-02 0.0000e+00 12 9 1 12 1 1 999.00 25.54 0.29 0.07620 0.08510 2 20 1 5 0 285.850 33.50 20.00 25.54 22.11 6.0 925.52 -1024 -1361 -2603 -1507 -2431 308 -176 -1229 -2140 -1843 -1215 -324 1079 1158 408 489 1977 445 1879 2128 355 2703 1850 1739 523 -1059 -183 513 864 -536 118 1888 -1377 -3631 -3390 -1837 -1728 -912 775 -1313 -343 -1056 -551 354 501 -651 -362 -1329 -1092 345 471 915 803 1562 1677 777 -236 -475 205 1286 1560 2139 1657 -361 -124 -1633 -312 -151 1 1055 1413 636 -76 -217 -185 -1042 -2596 -1872 -1947 -1230 -1125 -1267 -1229 -919 268 678 1329 1252 1234 316 -532 186 -1146 -1462 -872 1165 1306 247 336 -266 -1142 -788 -30 -570 -622 -636 -154 191 144 902 924 589 321 -760 -888 -590 -199 -177 493 191 872 690 138 629 -273 -763 -130 -265 87 -293 -583 -286 268 132 109 939 501 370 220 -405 -620 -879 -258 -350 -628 -345 -538 70 -42 -328 -604 -510 -341 -94 350 398 154 191 787 175 752 862 145 1100 803 794 250 -482 -82 211 372 -232 54 924 -668 -1780 -1627 -895 -928 -553 510 -915 -247 -785 -410 259 366 -470 -253 -916 -754 248 345 704 650 1236 1350 642 -196 -386 165 1057 1318 1949 1546 -339 -111 -1434 -263 -131 1 1030 1431 646 -75 -206 -164 -880 -2211 -1590 -1789 -1209 -1170 -1351 -1322 -1021 316 810 1626 1535 1451 357 -594 195 -1183 -1548 -977 1371 1643 321 425 -328 -1349 -911 -34 -699 -778 -832 -203 264 205 1303 1343 822 442 -999 -1137 -754 -257 -238 682 270 1209 964 185 822 -355 -976 -167 -340 120 -409 -811 -403 391 198 167 1464 781 581 346 -618 -940 -1309 SS 20251027T155254.5Z 9431.661742 131 1 53.75 2 60.74 134.85 121.85 103.84 0.00 1 0.00 1 0 17 1.953e-02 8.740e-03 7.785e-03 2.774e-03 2.400905e-01 1.379284e-03 2.733759e-03 -6.000000e+00 1.102714e-02 225.31 -2.00 3.36 -2.00 317.16 0.00e+00 8.598980e-04 1.940621e-04 6.349893e-05 -6.000000e+00 4.925174e-04 281.16 -2.00 20.00 -2.00 316.44 0.00e+00 2.037 0.000 302.00 328.00 3 5.7278e+00 3.6226e-03 2.1377e-02 -6.0000e+00 2.7299e-02 5.5943e-02 4.0939e-03 1.1685e-02 -6.0000e+00 2.9767e-02 -1.0473e-02 2.4605e-03 5.7421e-03 -6.0000e+00 1.7730e-02 8.6776e-04 1.2075e-03 1.8245e-03 -6.0000e+00 7.5771e-03 2.1242e-04 1.4174e-03 7.9052e-05 1.8455e-05 -6.0000e+00 5.2476e-04 7.4369e-02 0.0000e+00 11 8 0 10 0 0 99.99 25.54 0.49 0.07437 0.08502 19 2 1 5 0 2828.760 33.25 20.00 25.54 22.26 5.9 925.06 4865 -9758 -7810 -971 1836 -5349 -4229 7019 -1491 -3864 891 1171 701 2881 1041 -610 1796 900000 -2181 224 4314 644 1501 337 4322 -1348 -502 -1680 1748 3843 -1772 2617 -1504 -1989 -4344 612 -3558 -771 -389 -32 827 -630 -1327 185 -277 1225 121 518 -1375 918 -842 264 -1067 808 2088 51 -765 -494 -159 935 1137 1138 2593 1074 348 -299 -1100 -212 -880 -193 736 1062 536 1263 -1386 -1281 -1171 -1333 -2310 -1188 -1148 -2294 -31 -544 256 1571 1238 683 921 346 2 -1498 -1232 -826 -307 653 1783 221 632 -445 -746 -729 -492 -920 -776 -935 -427 718 708 1012 341 89 2 -1008 -593 -1140 -607 -482 149 225 500 131 726 378 -378 -341 216 -54 589 330 76 -342 529 260 121 592 636 322 359 -369 -1101 -945 633 -1492 -1087 -112 196 -648 -566 928 -224 -583 131 193 133 606 244 -151 447 900000 -605 61 1121 177 430 102 1303 -427 -147 -463 459 1047 -549 838 -511 -631 -1382 203 -1432 -362 -211 -19 501 -397 -849 116 -174 741 72 299 -812 559 -558 182 -718 548 1421 36 -540 -340 -118 653 852 925 2205 915 273 -219 -862 -161 -763 -181 712 1019 497 1078 -1087 -988 -857 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