File name: Pandora89s1_PaloDuroTX_20251119_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20251120T063905.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20251119_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20251119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20251119T143536.9Z 9454.608066 70 1 53.35 2 78.20 124.30 75.24 132.24 0.00 1 0.00 1 0 17 2.834e-01 1.738e-02 1.463e-01 6.436e-03 4.904134e-01 3.332936e-03 5.417051e-03 -6.000000e+00 1.608609e-01 223.86 -2.00 3.36 -2.00 320.37 0.00e+00 3.939107e-03 1.217764e-03 5.833025e-04 -6.000000e+00 7.824539e-03 278.59 -2.00 20.00 -2.00 319.79 0.00e+00 4.739 0.002 302.00 328.00 3 4.3507e+00 1.0094e-02 4.8076e-02 -6.0000e+00 3.9780e-01 8.1939e-02 1.2370e-02 2.4510e-02 -6.0000e+00 4.3515e-01 -1.1095e-01 1.1103e-02 1.3224e-02 -6.0000e+00 2.5667e-01 4.6123e-02 5.6626e-03 6.3918e-03 -6.0000e+00 1.0990e-01 6.0356e-05 1.1695e-03 1.9008e-04 6.6430e-05 -6.0000e+00 7.7481e-03 7.6737e-02 0.0000e+00 12 9 8 11 8 0 98.39 25.52 0.52 0.07674 0.08553 17 2 1 5 0 3138.020 33.25 20.00 25.52 18.32 6.1 898.56 -9925 -152052 -129364 900000 900000 -115174 -89372 900000 75022 -18504 900000 900000 70150 29477 -38838 -45336 16329 900000 -30863 -15342 83127 -21179 25392 -27533 49949 65500 380 32647 29916 45671 -16560 23888 19942 441 10504 43606 -15368 -7147 12808 4502 12954 1868 -1242 20332 2713 30877 938 4834 -2271 15235 769 740 276 5343 10964 -5588 -1726 3508 -377 -1224 2691 2263 4683 193 1135 3363 -3734 5032 -5436 1195 3013 1108 -3222 675 -4688 -2628 2827 -4217 -2306 -1095 -1763 -1860 1321 -1430 2656 3877 1372 -4580 103 -1130 886 -2797 -3158 888 -186 -970 1367 -595 1280 -455 517 -759 -592 93 -967 -1847 -1099 1342 189 871 285 157 503 -1909 -495 -1566 -161 -1551 -10 278 1854 624 2091 145 778 230 -886 355 1926 670 -192 -259 -287 399 -335 379 131 164 1094 -693 -958 -1123 -107 -7191 -4644 900000 900000 -3347 -2241 900000 470 -274 900000 900000 719 554 -1682 -2299 484 900000 -1635 -708 1421 -1062 854 -1663 1452 1642 18 1166 1163 1746 -1360 1482 1350 34 731 2405 -1801 -936 1622 686 1924 324 -227 3033 491 4258 177 897 -474 2922 187 195 78 1507 3010 -1849 -545 1025 -114 -387 901 854 1902 84 465 1303 -1573 2126 -2927 660 1697 629 -1809 334 -2195 -1117 1134 -2004 -1258 -680 -1241 -1417 1027 -1226 2336 3540 1201 -4254 97 -991 706 -2185 -2508 748 -181 -987 1538 -732 1522 -514 523 -795 -637 98 -1087 -2206 -1387 1786 280 1394 474 257 778 -2818 -687 -2216 -236 -2462 -16 454 2891 956 3036 205 1050 299 -1213 533 3146 1193 -361 -505 -590 799 -708 812 287 360 2280 -1396 -2007 -2298 SS 20251119T150308.3Z 9454.627179 82 1 54.16 2 73.67 129.09 71.39 137.32 0.00 1 0.00 1 0 25 2.821e-02 7.269e-03 3.272e-03 6.133e-04 3.810018e-01 3.027125e-04 4.248311e-03 -6.000000e+00 1.577164e-02 223.86 -2.00 3.36 -2.00 318.19 0.00e+00 1.215661e-03 5.690369e-05 1.877584e-04 -6.000000e+00 7.007557e-04 278.58 -2.00 20.00 -2.00 317.55 0.00e+00 3.501 0.001 302.00 328.00 3 1.8359e+00 8.0837e-04 3.5734e-02 -6.0000e+00 3.8891e-02 -3.9038e-03 9.1975e-04 1.8322e-02 -6.0000e+00 4.2417e-02 -2.3123e-02 6.1283e-04 9.1415e-03 -6.0000e+00 2.5278e-02 1.0563e-02 3.2243e-04 2.9805e-03 -6.0000e+00 1.0858e-02 2.5322e-03 1.3924e-03 1.7072e-05 2.9483e-05 -6.0000e+00 7.5769e-04 7.6662e-02 0.0000e+00 11 8 0 10 0 0 99.99 25.51 0.37 0.07666 0.08712 381 41 1 5 0 142.120 33.25 20.00 25.51 21.28 6.0 920.35 -5115 -7416 -10826 -9600 -13599 -11458 -10139 -5328 -5513 -8186 -8248 -5821 -1229 -708 241 1290 1298 2968 2898 943 1534 1479 2285 1318 1009 690 -1090 -1549 768 886 1433 1810 -754 -3016 -2942 -2369 -1672 -146 -83 -343 -365 -78 -141 460 166 647 -301 -1036 -333 660 168 895 683 698 1031 179 -255 -316 -499 853 1278 1986 1923 45 185 -936 -712 418 86 616 995 792 859 -57 -567 -1483 -2090 -1649 -1564 -1215 -1176 -1807 -1092 -545 299 658 1354 1534 1131 776 -3 -545 -686 -656 -433 534 922 317 -91 -656 -1148 -1008 -574 -1275 -953 -795 -373 390 850 999 605 492 -133 -717 -494 -510 -85 75 137 116 627 689 360 430 -456 -153 414 43 152 -156 -178 -267 88 94 60 662 606 320 24 -297 -755 -893 -294 -453 -645 -508 -729 -647 -638 -358 -394 -605 -652 -528 -127 -86 33 170 182 432 440 149 240 239 394 244 196 135 -205 -278 138 176 318 444 -197 -758 -732 -648 -490 -51 -32 -144 -162 -36 -65 214 78 301 -141 -490 -161 342 88 500 408 405 613 109 -156 -189 -297 520 844 1351 1420 34 131 -680 -515 305 68 528 883 699 723 -48 -425 -1097 -1520 -1211 -1322 -1096 -1119 -1759 -1110 -591 328 755 1590 1798 1277 855 -3 -551 -691 -680 -479 628 1156 425 -121 -853 -1366 -1181 -695 -1611 -1206 -1055 -521 552 1246 1504 935 769 -196 -1027 -700 -696 -122 109 211 180 949 1014 532 604 -646 -207 571 63 230 -252 -285 -442 146 167 107 1203 1127 576 43 -514 -1307 -1514 SS 20251119T150855.3Z 9454.631195 86 1 18.51 2 72.76 130.14 70.63 138.44 0.00 1 0.00 1 0 17 3.316e-02 7.017e-03 1.476e-02 2.497e-03 3.637513e-01 1.228161e-03 4.058383e-03 -6.000000e+00 1.854333e-02 223.86 -2.00 3.36 -2.00 318.39 0.00e+00 1.413406e-03 2.431144e-04 1.712365e-04 -6.000000e+00 8.239198e-04 278.58 -2.00 20.00 -2.00 317.74 0.00e+00 3.326 0.001 302.00 328.00 3 3.5225e+00 3.3013e-03 3.4017e-02 -6.0000e+00 4.5726e-02 7.4266e-03 3.7726e-03 1.7548e-02 -6.0000e+00 4.9871e-02 -2.3575e-02 2.5590e-03 8.7610e-03 -6.0000e+00 2.9721e-02 1.1319e-02 1.3515e-03 2.9512e-03 -6.0000e+00 1.2766e-02 5.5137e-04 1.2201e-03 7.0129e-05 2.8157e-05 -6.0000e+00 8.9086e-04 7.6775e-02 0.0000e+00 12 9 1 12 1 1 99.90 25.50 0.46 0.07678 0.08594 17 6 1 5 0 1027.960 33.25 20.00 25.50 21.95 6.0 924.85 -3219 -12932 -18453 -10590 -8462 -21792 -9448 -5539 453 -3859 -5640 409 3013 830 -1296 -233 317 1639 -1214 -1972 1244 -544 3542 -2786 1604 2235 -722 49 -98 3595 282 -455 838 -1531 -1738 -2066 -1457 -282 -729 180 -187 -527 -489 183 -364 1762 14 -1559 -41 705 -548 1390 1032 1675 1250 -301 -29 499 -1007 191 1689 1676 2183 -445 479 -232 -443 127 6 388 649 647 439 244 -520 -1260 -1715 -1480 -1545 -1444 -878 -1606 -841 -652 359 559 999 685 1123 489 -51 -620 -873 -530 -405 118 1382 675 -75 -658 -864 -991 -540 -945 -655 -713 -459 464 512 1020 599 567 -274 -971 -545 -801 -180 -112 -50 431 936 623 471 461 -463 -179 272 -31 55 -44 -198 -115 150 75 109 605 542 391 22 -326 -675 -941 -165 -756 -1074 -510 -387 -1220 -527 -332 27 -241 -382 30 260 86 -155 -30 42 227 -181 -301 183 -84 560 -498 286 397 -125 8 -16 636 58 -103 195 -342 -385 -506 -379 -88 -268 72 -79 -232 -218 81 -164 771 6 -700 -18 314 -268 713 565 947 728 -182 -18 290 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