File name: Pandora89s1_PaloDuroTX_20260126_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20260127T070221.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20260126_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20260126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260126T152258.9Z 9522.640959 100 1 4.57 2 74.10 127.07 115.99 38.14 0.00 1 0.00 1 0 17 8.515e-02 8.447e-03 4.739e-02 3.946e-03 4.983584e-01 1.961285e-03 5.478366e-03 -6.000000e+00 4.759212e-02 224.15 -2.00 3.36 -2.00 319.13 0.00e+00 1.417391e-03 4.846847e-04 4.288634e-04 -6.000000e+00 2.079095e-03 274.38 -2.00 20.00 -2.00 318.58 0.00e+00 3.590 0.001 302.00 328.00 3 2.6634e+00 5.3915e-03 3.9636e-02 -6.0000e+00 1.1760e-01 1.6221e-02 6.2659e-03 2.3961e-02 -6.0000e+00 1.2838e-01 -4.6779e-02 4.9660e-03 1.2323e-02 -6.0000e+00 7.6306e-02 2.2151e-02 2.6549e-03 4.2656e-03 -6.0000e+00 3.2597e-02 8.6885e-04 1.2306e-03 1.0737e-04 4.1789e-05 -6.0000e+00 2.2867e-03 8.5888e-02 0.0000e+00 12 9 1 12 1 1 97.76 25.16 0.35 0.08589 0.09514 7 10 1 5 0 570.300 33.25 20.03 25.16 -2.40 5.9 738.61 -20224 -32427 -44579 -21328 -12656 -36906 -29633 -24489 -24143 -16252 -33596 -16556 2601 -5430 -5303 -4455 -4079 -5645 -6110 -7431 -1122 -6560 -509 -9710 2231 -4534 -5262 4074 -480 -1503 1700 -1324 3051 -4589 -768 -71 -5072 -2930 -568 -32 -1017 1678 2155 1494 993 4481 -474 448 -153 1281 2425 1222 247 696 3446 280 604 -2 -466 1545 1173 2017 2097 -1435 -136 -805 445 1087 -183 509 1057 549 734 -10 -1052 -1804 -2468 -1295 -1699 -846 -1922 -2464 -1102 -408 -245 779 1651 985 911 729 242 -721 -1247 -795 -59 751 1185 144 37 -803 -377 -1457 -1145 -1357 -353 -1121 -453 269 921 1093 949 201 -157 -1189 -362 -573 -63 -61 504 528 788 555 606 367 -581 -36 702 -181 263 -174 -286 -410 338 -131 -44 716 523 229 -57 -321 -570 -919 -459 -873 -1286 -443 -239 -966 -821 -726 -762 -488 -1331 -675 108 -297 -335 -305 -301 -452 -515 -646 -92 -593 -47 -1054 226 -494 -551 376 -49 -179 225 -204 470 -720 -116 -12 -965 -667 -149 -9 -316 528 686 482 327 1432 -161 155 -51 465 959 529 116 341 1697 134 311 -1 -233 789 610 1165 1330 -891 -85 -492 274 680 -133 401 800 411 556 -7 -715 -1147 -1582 -844 -1299 -688 -1776 -2314 -1075 -424 -256 843 1814 1084 958 754 233 -665 -1178 -828 -65 889 1493 195 49 -999 -446 -1717 -1314 -1691 -458 -1460 -623 378 1346 1727 1547 323 -240 -1788 -516 -827 -96 -93 799 832 1200 862 902 523 -842 -51 1009 -277 421 -286 -492 -731 604 -240 -85 1389 1034 453 -108 -602 -1020 -1612 SS 20260126T152816.6Z 9522.644637 104 1 8.06 2 73.24 128.02 115.33 39.24 0.00 1 0.00 1 0 17 9.234e-02 8.875e-03 5.478e-02 4.323e-03 4.765545e-01 2.147989e-03 5.213311e-03 -6.000000e+00 5.162416e-02 224.15 -2.00 3.36 -2.00 319.23 0.00e+00 8.571511e-04 5.491560e-04 2.379852e-04 -6.000000e+00 2.254813e-03 274.38 -2.00 20.00 -2.00 318.69 0.00e+00 3.417 0.001 302.00 328.00 3 3.4448e+00 5.9055e-03 3.7798e-02 -6.0000e+00 1.2756e-01 2.1642e-02 6.8807e-03 2.2972e-02 -6.0000e+00 1.3924e-01 -3.8946e-02 5.5316e-03 1.1655e-02 -6.0000e+00 8.2762e-02 1.7991e-02 2.9530e-03 3.9020e-03 -6.0000e+00 3.5366e-02 4.7019e-04 1.6207e-03 1.1858e-04 3.7729e-05 -6.0000e+00 2.4799e-03 8.3873e-02 0.0000e+00 12 9 1 12 1 1 99.67 25.17 0.62 0.08387 0.09605 6 5 1 5 0 1150.050 33.25 20.00 25.17 -2.33 6.0 740.69 -9351 -62786 -59156 1627 3076 -32087 -8755 -28676 -8240 -7177 -23172 13150 215 -5240 5632 -11265 -3172 19276 -4932 9325 925 -11722 1489 -4328 2668 -3108 4068 -515 3625 6725 1515 3613 3871 -8671 -4154 3913 -3079 -1343 2650 403 378 670 -2580 -425 257 2098 -357 2799 -1128 4472 -598 879 981 227 2256 -1216 -152 444 -1702 1661 70 1959 1878 220 230 -830 -2422 134 -1219 798 247 1210 1360 755 -1026 -1888 -1059 -1245 -1387 -1318 -1354 -2277 -955 -465 1313 452 1285 1222 1256 1285 -662 -329 -789 -155 197 656 1304 28 -116 -284 -603 -1311 -568 -1068 -1154 -1388 -727 739 1008 764 479 144 -293 -995 -856 -451 -59 -456 376 425 1005 415 754 79 -638 160 567 -98 40 113 -504 -163 -212 128 158 710 861 362 259 -216 -1107 -1026 -201 -2408 -2070 28 52 -839 -207 -931 -233 -206 -859 410 9 -289 320 -826 -231 1194 -407 680 73 -1107 134 -441 267 -330 382 -49 347 711 193 507 563 -1349 -618 599 -601 -286 641 110 109 201 -811 -131 80 642 -113 875 -385 1580 -244 381 457 102 1026 -586 -72 203 -787 772 36 1112 1168 141 139 -491 -1479 88 -855 599 193 922 979 542 -671 -1154 -640 -833 -998 -1087 -1164 -2125 -926 -482 1330 483 1398 1324 1298 1313 -638 -299 -732 -157 212 798 1662 39 -155 -355 -730 -1491 -665 -1361 -1450 -1839 -1016 1033 1541 1194 772 226 -463 -1472 -1206 -640 -88 -723 584 695 1584 638 1106 119 -922 221 810 -146 66 187 -880 -292 -380 244 299 1363 1679 706 509 -406 -1991 -1805 SS 20260126T153256.5Z 9522.647876 107 1 53.25 2 72.49 128.87 114.73 40.19 0.00 1 0.00 1 0 25 1.018e-01 9.022e-03 3.816e-02 2.622e-03 4.568327e-01 1.309900e-03 4.957802e-03 -6.000000e+00 5.713273e-02 224.15 -2.00 3.36 -2.00 319.40 0.00e+00 1.608766e-03 3.514716e-04 2.314869e-04 -6.000000e+00 2.497240e-03 274.38 -2.00 20.00 -2.00 318.86 0.00e+00 3.279 0.000 302.00 328.00 3 4.3789e+00 3.6416e-03 3.6243e-02 -6.0000e+00 1.4138e-01 3.7510e-02 4.2748e-03 2.2079e-02 -6.0000e+00 1.5452e-01 -2.7905e-02 3.5066e-03 1.1354e-02 -6.0000e+00 9.1768e-02 1.0827e-02 1.8641e-03 4.3093e-03 -6.0000e+00 3.9051e-02 2.0822e-04 1.6322e-03 7.3842e-05 3.9879e-05 -6.0000e+00 2.7340e-03 8.2791e-02 0.0000e+00 11 9 0 11 8 0 99.95 25.17 0.45 0.08279 0.09506 23 2 1 5 0 2314.730 33.00 20.00 25.17 -2.28 6.0 741.16 14978 -55218 -65855 3899 2414 -50706 -18500 25601 8851 -28811 19226 -2137 13482 4424 -2528 -12117 -9157 900000 -6128 -2054 13351 -4511 241 -4905 9830 5433 -5961 2428 4487 9813 -6065 3104 2447 -7124 -2681 7745 -8577 -3278 83 1693 -538 735 -1857 1862 -634 6183 227 159 -1175 2666 -142 -612 -609 1557 3562 371 -792 -1181 -896 1589 710 1755 2961 -78 176 -903 -2190 1771 -1002 161 1116 1156 294 -124 -1634 -3315 85 -1548 -1705 -1512 -746 -2254 -160 -687 1026 1453 1197 606 963 503 252 -1178 -1439 -224 -312 38 1306 467 449 -709 -752 -1023 -637 -616 -1001 -1027 -731 836 1023 731 86 203 6 -1346 -527 -1327 -72 -431 280 100 696 684 1333 85 -159 101 -330 -19 180 -6 -21 -319 -43 211 169 670 849 231 159 -268 -969 -1040 223 -1732 -2173 64 39 -1529 -459 458 199 -965 437 -73 479 207 -145 -833 -658 900000 -475 -155 863 -364 20 -458 829 480 -562 203 385 908 -749 393 323 -976 -351 1015 -1569 -693 20 442 -152 213 -561 545 -193 1757 69 49 -384 917 -50 -233 -248 648 1496 164 -352 -512 -385 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