File name: Pandora89s1_PaloDuroTX_20260614_L2Fit_fout2c2d20241101p1-8.txt File generation date: 20260615T065317.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Kevin Mishoe Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 89 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora89_OF_v3d20240314.txt Instrument calibration file used: Pandora89s1_CF_v2d20241101.txt Level 1 file used: Pandora89s1_PaloDuroTX_20260614_L1_smca1c2d20241101p1-8.txt Full location name: Palo Duro, TX Short location name: PaloDuroTX Country of location: United States Location latitude [deg]: 34.8806 Location longitude [deg]: -101.6647 Location altitude [m]: 1056 Local noon date: 20260614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based clearance session 1 First and last pixel inside fitting window: 194 335 Nominal wavelengths inside fitting window [nm]: 305.1224 305.2633 305.4042 305.5451 305.6860 305.8269 305.9677 306.1085 306.2494 306.3902 306.5310 306.6718 306.8126 306.9533 307.0941 307.2349 307.3756 307.5163 307.6570 307.7977 307.9384 308.0791 308.2198 308.3604 308.5011 308.6417 308.7823 308.9230 309.0636 309.2041 309.3447 309.4853 309.6258 309.7664 309.9069 310.0474 310.1879 310.3284 310.4689 310.6094 310.7499 310.8903 311.0307 311.1712 311.3116 311.4520 311.5924 311.7328 311.8731 312.0135 312.1538 312.2942 312.4345 312.5748 312.7151 312.8554 312.9957 313.1359 313.2762 313.4164 313.5566 313.6969 313.8371 313.9773 314.1174 314.2576 314.3978 314.5379 314.6781 314.8182 314.9583 315.0984 315.2385 315.3786 315.5186 315.6587 315.7987 315.9388 316.0788 316.2188 316.3588 316.4988 316.6387 316.7787 316.9186 317.0586 317.1985 317.3384 317.4783 317.6182 317.7581 317.8979 318.0378 318.1776 318.3175 318.4573 318.5971 318.7369 318.8767 319.0164 319.1562 319.2959 319.4357 319.5754 319.7151 319.8548 319.9945 320.1342 320.2738 320.4135 320.5531 320.6928 320.8324 320.9720 321.1116 321.2512 321.3907 321.5303 321.6698 321.8094 321.9489 322.0884 322.2279 322.3674 322.5068 322.6463 322.7857 322.9252 323.0646 323.2040 323.3434 323.4828 323.6222 323.7616 323.9009 324.0403 324.1796 324.3189 324.4582 324.5975 324.7368 324.8761 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260614T181012.4Z 9661.757088 289 1 53.79 2 14.10 142.87 7.72 159.11 0.00 1 0.00 1 0 17 8.927e-03 7.661e-03 1.322e-03 1.001e-03 1.429909e-01 5.190453e-04 1.610523e-03 -6.000000e+00 5.137871e-03 231.82 -2.00 3.36 -2.00 314.48 0.00e+00 2.785047e-04 4.028773e-05 1.486312e-05 -6.000000e+00 2.275146e-04 284.62 -2.00 20.00 -2.00 313.89 0.00e+00 1.031 0.000 302.00 328.00 3 5.1473e+00 1.3369e-03 1.1583e-02 -6.0000e+00 1.2882e-02 4.1940e-02 1.4804e-03 7.0074e-03 -6.0000e+00 1.3957e-02 -1.2698e-02 8.4652e-04 3.3840e-03 -6.0000e+00 8.2938e-03 2.2651e-03 3.6674e-04 9.4382e-04 -6.0000e+00 3.5171e-03 1.1065e-03 1.5428e-03 2.7788e-05 1.2106e-05 -6.0000e+00 2.4030e-04 8.3099e-02 0.0000e+00 11 8 0 10 0 0 99.97 26.34 0.43 0.08310 0.09469 44 5 1 5 0 1222.310 34.00 20.00 26.34 27.91 6.0 962.49 1097 -276 -1967 -1341 -850 -346 296 1097 -764 -872 -484 -245 166 922 696 622 1078 792 1237 311 1643 1295 672 672 1013 244 -384 -639 97 961 777 507 -1983 -2787 -2800 -2196 -1766 -785 -608 -627 -354 -895 -675 63 -536 -193 -946 -1155 -147 444 244 766 230 546 1202 450 -98 -117 60 756 1084 1768 1494 43 -50 -1069 -813 481 8 597 836 1143 1247 420 -285 -1336 -1312 -1344 -1174 -1113 -905 -1815 -546 -594 75 814 1225 1313 1059 500 -248 -407 -657 -537 -189 654 1082 522 230 -451 -981 -930 -497 -1077 -753 -877 -591 241 627 964 345 464 -138 -830 -685 -936 -285 71 57 134 389 418 302 340 -568 -71 209 -142 138 -203 -31 -105 120 271 287 683 673 518 176 -331 -743 -1038 467 -118 -779 -504 -303 -129 112 450 -328 -360 -200 -110 82 459 368 333 582 439 700 179 916 734 399 414 636 152 -221 -367 53 539 421 292 -1167 -1518 -1624 -1281 -1190 -578 -479 -528 -306 -794 -597 55 -464 -161 -759 -953 -119 371 202 655 205 495 1094 417 -91 -106 54 702 1005 1742 1538 43 -49 -955 -698 434 7 617 895 1214 1277 403 -262 -1192 -1099 -1168 -1059 -1111 -922 -1963 -609 -670 90 1021 1488 1593 1303 568 -272 -430 -668 -572 -206 729 1317 666 285 -527 -1131 -1029 -578 -1292 -947 -1087 -759 319 869 1305 467 625 -181 -996 -820 -1126 -336 90 73 177 507 564 387 412 -700 -82 242 -175 167 -256 -39 -135 160 362 401 974 985 763 254 -466 -1016 -1399 SS 20260614T181402.2Z 9661.759747 292 1 4.32 2 13.64 146.01 7.48 165.07 0.00 1 0.00 1 0 17 8.848e-03 7.685e-03 2.057e-03 1.672e-03 1.406864e-01 8.707910e-04 1.588125e-03 -6.000000e+00 5.092014e-03 231.82 -2.00 3.36 -2.00 314.03 0.00e+00 9.578764e-05 6.236116e-05 1.586448e-05 -6.000000e+00 2.254985e-04 284.62 -2.00 20.00 -2.00 313.48 0.00e+00 1.029 0.000 302.00 328.00 3 3.7010e+00 2.2323e-03 1.1490e-02 -6.0000e+00 1.2767e-02 2.7471e-02 2.4634e-03 6.8764e-03 -6.0000e+00 1.3833e-02 -1.0284e-02 1.4141e-03 3.3284e-03 -6.0000e+00 8.2200e-03 1.8823e-03 6.0830e-04 9.0802e-04 -6.0000e+00 3.4855e-03 4.7555e-03 1.5825e-03 4.6208e-05 1.2360e-05 -6.0000e+00 2.3816e-04 8.3542e-02 0.0000e+00 12 9 1 12 1 1 99.57 26.35 0.56 0.08354 0.09543 8 12 1 5 0 479.320 34.00 20.00 26.35 28.07 6.1 963.84 1229 397 -1385 -2001 -1005 -456 382 659 -513 -735 -356 -900 557 943 -56 772 496 1048 1456 393 1312 702 1271 866 987 21 -352 -881 565 451 986 705 -1729 -2667 -2552 -2558 -1462 -937 -673 -652 -485 -707 -768 64 -464 -553 -698 -1326 -250 197 384 1016 970 522 936 273 -3 244 -59 374 1049 1737 1690 -34 -31 -1358 -767 239 97 658 1298 1413 1139 658 -137 -944 -1482 -942 -1243 -1158 -1136 -1610 -892 -587 257 595 1047 1341 744 527 -290 -468 -632 -323 -204 738 1036 379 15 -299 -923 -1100 -592 -1176 -770 -564 -326 185 533 885 578 207 -127 -799 -630 -564 -375 176 122 174 372 133 197 498 -160 -127 80 -229 -17 -316 -93 -405 164 289 561 747 727 401 119 -285 -792 -862 608 196 -635 -861 -409 -195 168 318 -257 -355 -171 -472 300 527 -33 463 302 649 921 240 823 426 799 567 662 14 -228 -525 340 263 599 454 -1138 -1628 -1530 -1682 -1047 -718 -563 -559 -427 -637 -691 56 -408 -469 -592 -1086 -200 164 336 880 874 480 867 258 -3 224 -54 354 1012 1710 1733 -34 -29 -1237 -700 220 97 680 1381 1496 1167 656 -128 -834 -1295 -810 -1143 -1129 -1159 -1737 -959 -676 303 711 1282 1635 873 612 -319 -484 -628 -336 -222 841 1244 460 18 -344 -1024 -1223 -665 -1396 -956 -703 -421 238 720 1191 774 272 -159 -947 -727 -653 -455 221 158 224 491 172 250 597 -189 -149 93 -273 -20 -396 -118 -519 209 390 764 1041 1005 559 162 -391 -1061 -1136 SS 20260614T181829.4Z 9661.762841 295 1 53.30 2 13.16 149.90 7.31 172.39 0.00 1 0.00 1 0 25 1.519e-02 1.064e-02 5.392e-03 3.453e-03 1.490444e-01 1.775547e-03 1.673203e-03 -6.000000e+00 8.744914e-03 231.82 -2.00 3.36 -2.00 315.39 0.00e+00 7.600938e-04 1.627037e-04 2.183572e-05 -6.000000e+00 3.871321e-04 284.62 -2.00 20.00 -2.00 314.71 0.00e+00 1.027 0.000 302.00 328.00 3 6.9411e+00 4.6052e-03 1.1767e-02 -6.0000e+00 2.1926e-02 6.6041e-02 5.1159e-03 7.3604e-03 -6.0000e+00 2.3754e-02 -1.2035e-02 2.9216e-03 3.5315e-03 -6.0000e+00 1.4115e-02 3.4756e-04 1.2983e-03 1.0878e-03 -6.0000e+00 5.9874e-03 1.8012e-04 1.7732e-03 9.7266e-05 1.1632e-05 -6.0000e+00 4.0891e-04 8.1148e-02 0.0000e+00 12 9 8 11 40 0 99.90 26.35 0.58 0.08115 0.09447 25 3 1 5 0 2131.700 34.00 20.00 26.35 28.29 6.1 966.32 3465 -3716 -3520 504 3009 -5396 -3397 1344 -515 -3038 -535 3043 402 875 397 28 3117 -1317 208 -1157 3790 678 1887 -414 1918 1707 -172 -1296 201 4126 -1089 1028 -959 -2692 -3913 891 -2760 -831 36 -570 -529 -910 -1069 431 -346 1470 -830 -797 -630 -48 -719 -11 161 681 2487 -610 -1047 -617 162 1332 856 1420 3038 786 -293 -1374 -1811 780 -150 531 1418 1609 1238 382 -575 -2260 -1462 -3176 -1246 -1503 -872 -1945 45 -924 355 1303 1477 1078 428 341 -707 -2009 -1258 -426 -399 114 1233 496 319 -55 -682 -1548 -528 -375 -837 -1082 -519 600 912 1198 408 939 791 -1905 -1180 -1087 -275 -56 -42 114 1077 79 1583 354 -816 -176 -488 -184 308 -488 -384 -261 314 650 158 383 1057 216 441 -19 -1425 -1041 1115 -1163 -1101 132 735 -1506 -1029 425 -170 -990 -170 1019 154 369 179 13 1404 -635 101 -575 1760 329 939 -218 1010 884 -84 -587 87 1767 -515 504 -479 -1256 -1815 432 -1608 -564 25 -430 -411 -725 -852 336 -269 1083 -598 -606 -473 -38 -540 -9 130 555 2011 -514 -877 -505 132 1105 764 1348 2959 757 -257 -1222 -1559 696 -138 528 1450 1634 1216 352 -524 -1879 -1132 -2597 -1114 -1493 -852 -2023 48 -1066 434 1657 1929 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