File name: Pandora166s1_PhiladelphiaPA_20220412_L2Fit_fout2c1d20210412p1-8.txt
File generation date: 20251125T100845.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c1p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 166
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora166_OF_v3d20210217.txt
Instrument calibration file used: Pandora166s1_CF_v1d20210412.txt
Level 1 file used: Pandora166s1_PhiladelphiaPA_20220412_L1_smca1c1d20210412p1-8.txt
Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE
Short location name: PhiladelphiaPA
Country of location: United States
Location latitude [deg]: 39.9919
Location longitude [deg]: -75.0811
Location altitude [m]: 6
Local noon date: 20220412
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0985 305.2393 305.3800 305.5207 305.6614 305.8021 305.9428 306.0835 306.2242 306.3648 306.5054 306.6461 306.7867 306.9273 307.0679 307.2085 307.3490 307.4896 307.6302 307.7707 307.9112 308.0517 308.1922 308.3327 308.4732 308.6137 308.7542 308.8946 309.0350 309.1755 309.3159 309.4563 309.5967 309.7371 309.8774 310.0178 310.1581 310.2985 310.4388 310.5791 310.7194 310.8597 311.0000 311.1403 311.2805 311.4208 311.5610 311.7012 311.8415 311.9817 312.1219 312.2620 312.4022 312.5424 312.6825 312.8227 312.9628 313.1029 313.2430 313.3831 313.5232 313.6632 313.8033 313.9433 314.0834 314.2234 314.3634 314.5034 314.6434 314.7834 314.9234 315.0633 315.2033 315.3432 315.4831 315.6230 315.7629 315.9028 316.0427 316.1826 316.3224 316.4623 316.6021 316.7419 316.8818 317.0216 317.1614 317.3011 317.4409 317.5807 317.7204 317.8601 317.9999 318.1396 318.2793 318.4190 318.5586 318.6983 318.8380 318.9776 319.1172 319.2569 319.3965 319.5361 319.6757 319.8152 319.9548 320.0944 320.2339 320.3734 320.5130 320.6525 320.7920 320.9315 321.0709 321.2104 321.3499 321.4893 321.6287 321.7682 321.9076 322.0470 322.1864 322.3257 322.4651 322.6045 322.7438 322.8831 323.0225 323.1618 323.3011 323.4403 323.5796 323.7189 323.8581 323.9974 324.1366 324.2758 324.4150 324.5542 324.6934 324.8326 324.9718
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20220412T132709.2Z 8137.560523 268 1 48.62 2 56.72 108.16 124.05 352.90 0.00 1 0.00 1 0 17 2.312e-02 8.540e-03 1.965e-02 5.156e-03 2.654491e-01 2.591257e-03 3.149907e-03 -6.000000e+00 1.327674e-02 228.46 -2.00 3.49 -2.00 317.93 0.00e+00 3.246535e-04 3.916984e-04 6.434001e-05 -6.000000e+00 5.338222e-04 280.66 -2.00 20.00 -2.00 317.58 0.00e+00 1.816 0.000 302.00 328.00 3 5.1658e+00 6.8945e-03 2.2777e-02 -6.0000e+00 3.3286e-02 5.8560e-02 7.7397e-03 1.3535e-02 -6.0000e+00 3.6280e-02 -4.4490e-03 4.8855e-03 6.7185e-03 -6.0000e+00 2.1318e-02 -2.4556e-03 2.4671e-03 1.9268e-03 -6.0000e+00 8.8387e-03 3.4550e-04 6.2114e-05 1.5362e-04 2.1747e-05 -6.0000e+00 6.3671e-04 -1.7700e-02 2.4928e-05 11 8 0 10 0 0 99.97 20.12 0.33 -0.01770 -0.01723 14 3 1 5 0 3472.320 26.51 20.00 20.12 16.62 12.0 1035.78 -4894 -3165 -6927 -3563 -12246 -756 541 4058 1716 -2711 -4349 -11011 6524 -3548 -1699 3581 5240 -4592 1884 1484 822 4578 2244 1001 -1097 -829 705 624 1718 -3287 520 3867 204 2708 -1096 -2443 -602 -2823 -2412 -254 -1344 -659 -1665 1648 1286 -3232 -363 -415 -965 1964 376 1927 -108 339 437 -130 472 519 374 972 2439 2688 1479 878 -718 -63 -487 273 1328 951 636 1340 -161 -124 7 -464 -1259 -1436 -113 -948 -2304 -1503 -2250 -820 -657 -558 -588 264 944 863 872 362 815 1066 -397 -510 1068 1503 389 -415 -729 -1176 -1468 -242 -1912 -1377 -767 -1015 804 268 808 -176 369 9 -278 66 -131 780 84 274 -557 41 607 646 897 -135 828 1498 344 185 -826 317 -22 -270 18 -303 628 268 335 -612 -507 -483 -263 -450 -310 -713 -331 -1111 -60 45 366 175 -300 -486 -1363 766 -525 -280 613 920 -923 370 302 171 913 471 224 -264 -206 171 142 365 -728 118 918 54 712 -281 -629 -167 -931 -942 -112 -648 -328 -862 832 650 -1702 -182 -204 -468 938 192 1037 -63 206 272 -83 303 331 235 607 1553 1831 1100 693 -569 -47 -335 183 944 760 552 1198 -145 -107 6 -343 -855 -939 -77 -724 -1979 -1402 -2239 -842 -717 -648 -715 327 1162 1025 967 371 771 982 -390 -550 1249 1917 526 -557 -925 -1391 -1664 -280 -2414 -1817 -1048 -1448 1180 419 1309 -290 587 13 -388 87 -173 1062 122 421 -879 63 916 941 1245 -181 1054 1908 470 269 -1264 493 -35 -443 32 -546 1148 500 628 -1132 -908 -838 -448
SS 20220412T133239.3Z 8137.564344 271 1 24.46 2 55.72 109.27 124.18 354.42 0.00 1 0.00 1 0 17 1.776e-02 7.420e-03 1.116e-02 3.612e-03 2.624116e-01 1.819329e-03 3.136076e-03 -6.000000e+00 1.019900e-02 228.46 -2.00 3.49 -2.00 317.35 0.00e+00 3.473954e-04 2.399983e-04 5.483858e-05 -6.000000e+00 4.100823e-04 280.66 -2.00 20.00 -2.00 317.02 0.00e+00 1.770 0.000 302.00 328.00 3 4.4584e+00 4.8005e-03 2.2323e-02 -6.0000e+00 2.5570e-02 5.8069e-02 5.3747e-03 1.3390e-02 -6.0000e+00 2.7871e-02 -1.3444e-02 3.2725e-03 6.6302e-03 -6.0000e+00 1.6377e-02 6.9012e-05 1.6114e-03 1.8864e-03 -6.0000e+00 6.7894e-03 7.3980e-04 -2.6468e-04 1.0572e-04 2.1640e-05 -6.0000e+00 4.8919e-04 -1.7718e-02 -5.3527e-06 12 9 1 12 1 1 99.93 20.13 0.14 -0.01772 -0.01971 7 3 1 5 0 3033.930 26.51 20.00 20.13 17.03 11.9 1039.01 -3083 6430 -651 -5194 -6607 -2757 -6668 2679 -3036 -8679 -495 -3619 -3627 -2638 3822 548 1095 971 1631 -634 506 1634 -595 1517 2025 1619 -1631 -1887 2236 1776 1325 334 2160 -1994 -554 -1484 -1430 138 -819 -1375 51 -1355 1069 -1014 -1264 -58 -1128 -458 -1284 -146 648 289 1105 1106 361 1289 218 -238 307 175 1373 1826 2377 1821 -517 277 -504 -214 674 334 227 956 680 604 139 61 -136 -667 22 -1240 -1357 -1463 -2579 -1822 -917 -96 -191 401 519 -225 342 -550 317 734 457 67 272 1165 34 70 -149 -691 -878 -162 -683 -1937 -837 -789 101 579 586 90 320 -278 -328 623 700 -184 -47 126 -233 273 533 415 1033 248 123 1569 445 209 71 -375 19 201 -11 -559 140 189 274 -593 -304 -531 -200 -354 730 -80 -621 -720 -281 -751 309 -407 -1277 -67 -523 -586 -481 741 119 247 227 394 -161 129 410 -156 411 573 474 -488 -533 574 454 360 99 672 -656 -169 -453 -475 52 -367 -704 28 -775 614 -596 -743 -34 -649 -257 -712 -81 374 178 709 741 249 897 155 -169 214 122 975 1374 1904 1536 -441 220 -379 -158 524 287 209 906 644 555 121 49 -100 -476 16 -1021 -1228 -1432 -2678 -1953 -1030 -113 -234 501 647 -273 391 -589 316 713 465 73 326 1492 46 93 -189 -827 -1012 -190 -858 -2561 -1136 -1106 146 874 916 143 492 -409 -453 817 916 -250 -68 188 -355 411 786 595 1418 330 158 2004 602 297 105 -568 29 316 -18 -955 242 332 483 -1034 -516 -880 -326
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