File name: Pandora166s1_PhiladelphiaPA_20220825_L2Fit_fout2c1d20210412p1-8.txt
File generation date: 20251125T104841.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c1p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 166
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora166_OF_v3d20210217.txt
Instrument calibration file used: Pandora166s1_CF_v1d20210412.txt
Level 1 file used: Pandora166s1_PhiladelphiaPA_20220825_L1_smca1c1d20210412p1-8.txt
Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE
Short location name: PhiladelphiaPA
Country of location: United States
Location latitude [deg]: 39.9919
Location longitude [deg]: -75.0811
Location altitude [m]: 6
Local noon date: 20220825
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0985 305.2393 305.3800 305.5207 305.6614 305.8021 305.9428 306.0835 306.2242 306.3648 306.5054 306.6461 306.7867 306.9273 307.0679 307.2085 307.3490 307.4896 307.6302 307.7707 307.9112 308.0517 308.1922 308.3327 308.4732 308.6137 308.7542 308.8946 309.0350 309.1755 309.3159 309.4563 309.5967 309.7371 309.8774 310.0178 310.1581 310.2985 310.4388 310.5791 310.7194 310.8597 311.0000 311.1403 311.2805 311.4208 311.5610 311.7012 311.8415 311.9817 312.1219 312.2620 312.4022 312.5424 312.6825 312.8227 312.9628 313.1029 313.2430 313.3831 313.5232 313.6632 313.8033 313.9433 314.0834 314.2234 314.3634 314.5034 314.6434 314.7834 314.9234 315.0633 315.2033 315.3432 315.4831 315.6230 315.7629 315.9028 316.0427 316.1826 316.3224 316.4623 316.6021 316.7419 316.8818 317.0216 317.1614 317.3011 317.4409 317.5807 317.7204 317.8601 317.9999 318.1396 318.2793 318.4190 318.5586 318.6983 318.8380 318.9776 319.1172 319.2569 319.3965 319.5361 319.6757 319.8152 319.9548 320.0944 320.2339 320.3734 320.5130 320.6525 320.7920 320.9315 321.0709 321.2104 321.3499 321.4893 321.6287 321.7682 321.9076 322.0470 322.1864 322.3257 322.4651 322.6045 322.7438 322.8831 323.0225 323.1618 323.3011 323.4403 323.5796 323.7189 323.8581 323.9974 324.1366 324.2758 324.4150 324.5542 324.6934 324.8326 324.9718
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20220825T123112.5Z 8272.521672 155 1 46.72 2 66.23 96.08 45.79 98.24 0.00 1 0.00 1 0 17 1.270e-02 6.035e-03 1.754e-03 3.300e-04 3.226318e-01 1.673233e-04 3.779526e-03 -6.000000e+00 7.366648e-03 230.98 -2.00 3.49 -2.00 318.30 0.00e+00 6.880886e-04 2.815426e-05 9.301496e-05 -6.000000e+00 2.933650e-04 290.19 -2.00 20.00 -2.00 317.96 0.00e+00 2.462 0.000 302.00 328.00 3 -1.5567e-01 4.5026e-04 2.9839e-02 -6.0000e+00 1.8581e-02 1.1902e-02 5.0516e-04 1.6679e-02 -6.0000e+00 2.0207e-02 -1.0385e-02 3.3672e-04 8.2314e-03 -6.0000e+00 1.1850e-02 -1.1283e-03 1.7520e-04 2.3466e-03 -6.0000e+00 4.8925e-03 3.5608e-02 -1.0255e-04 9.6944e-06 2.5307e-05 -6.0000e+00 3.4984e-04 -2.4664e-02 4.7173e-06 10 0 0 10 0 0 40.04 20.16 0.18 -0.02466 -0.02543 1041 207 1 5 0 44.700 26.62 19.99 20.16 33.45 16.1 1040.39 -1400 -1376 -2047 -4501 -4604 -4184 -2319 -2035 -1817 -3770 -4553 -2767 -1926 -431 -6 -588 -355 134 737 950 10 -280 1251 370 30 -271 -1185 -1461 -1435 186 1118 1521 1239 -1647 -3028 -2176 -2016 -1170 -492 -845 -1351 -1015 -650 -510 -192 -274 -573 -376 -970 181 987 730 1354 1299 1048 1149 380 3 176 470 1208 1873 2060 1818 52 -216 -116 -118 1456 805 594 631 338 563 -178 -231 -457 -488 -142 -724 -1092 -1403 -2208 -1544 -958 -668 -296 131 336 288 375 320 313 881 499 198 625 814 -111 -441 -448 -736 -204 158 -1171 -1197 -947 -853 -141 239 243 98 195 35 128 488 487 290 280 -127 -420 99 410 379 717 167 549 1340 564 214 -149 -263 -74 204 -123 -301 -39 310 -150 -179 -225 -411 -209 -80 -87 -133 -282 -260 -229 -133 -131 -130 -290 -355 -223 -176 -46 -1 -80 -51 20 116 155 2 -47 214 68 6 -55 -242 -283 -263 34 217 324 289 -408 -718 -506 -514 -323 -162 -327 -577 -454 -299 -237 -89 -128 -265 -171 -440 83 477 357 701 712 597 671 228 2 103 274 722 1200 1442 1366 40 -155 -78 -78 1023 646 490 543 291 464 -146 -170 -308 -317 -97 -567 -910 -1301 -2213 -1617 -1006 -749 -349 158 407 335 405 337 304 832 504 210 740 1010 -148 -583 -588 -888 -231 184 -1492 -1527 -1263 -1193 -207 356 384 158 305 54 182 656 652 407 420 -193 -651 151 639 566 1017 227 752 1835 790 325 -241 -418 -119 345 -222 -542 -72 582 -285 -332 -400 -742 -368
SS 20220825T124342.8Z 8272.530357 161 1 46.25 2 63.85 98.23 43.49 100.61 0.00 1 0.00 1 0 17 1.184e-02 6.186e-03 1.180e-03 2.780e-04 2.961952e-01 1.411143e-04 3.490611e-03 -6.000000e+00 6.864865e-03 230.98 -2.00 3.49 -2.00 317.96 0.00e+00 5.392820e-04 2.164397e-05 7.629983e-05 -6.000000e+00 2.733811e-04 290.19 -2.00 20.00 -2.00 317.63 0.00e+00 2.255 0.000 302.00 328.00 3 -2.2699e-01 3.7727e-04 2.7358e-02 -6.0000e+00 1.7315e-02 9.4322e-03 4.2188e-04 1.5318e-02 -6.0000e+00 1.8830e-02 -7.6424e-03 2.7035e-04 7.5282e-03 -6.0000e+00 1.1043e-02 -1.4835e-03 1.3814e-04 2.1283e-03 -6.0000e+00 4.5593e-03 4.8641e-02 -8.1781e-05 8.1793e-06 2.3297e-05 -6.0000e+00 3.2601e-04 -2.4859e-02 -7.6519e-08 10 0 0 10 0 0 16.19 20.15 0.22 -0.02486 -0.02547 1233 245 1 5 0 37.200 26.62 20.00 20.15 34.51 16.2 1047.06 -328 -1160 -1324 -4474 -4688 -3193 -2627 -477 -1704 -2924 -3761 -2952 -1401 -1360 15 -858 -174 186 662 1163 -211 433 893 789 123 152 -660 -1295 -953 274 1398 1282 1475 -1678 -3083 -2025 -2150 -852 -678 -845 -1162 -917 -538 -599 178 -310 -525 -410 -847 270 894 865 1180 1370 863 1141 331 -23 237 488 1182 1719 2068 1800 -11 -223 -224 -76 1393 869 466 569 262 473 -86 -248 -362 -483 39 -685 -1095 -1431 -2316 -1557 -985 -689 -392 84 296 199 382 147 412 836 571 264 610 792 -167 -417 -515 -724 -208 235 -1101 -1176 -919 -828 -162 211 311 82 220 79 107 555 506 314 285 -71 -435 94 439 359 747 189 644 1360 618 248 -100 -246 -100 206 -129 -307 -31 251 -156 -197 -222 -455 -239 -24 -93 -109 -355 -363 -236 -206 -41 -153 -279 -361 -294 -156 -176 2 -140 -30 33 123 223 -42 85 179 168 28 36 -156 -290 -200 57 307 308 385 -464 -815 -523 -610 -280 -248 -361 -546 -451 -271 -306 90 -158 -264 -202 -414 132 462 482 696 852 521 703 209 -15 147 321 745 1161 1519 1414 -9 -166 -156 -52 1005 713 394 502 231 427 -72 -188 -250 -343 27 -542 -982 -1335 -2333 -1637 -1103 -776 -464 102 359 233 439 155 398 786 572 294 711 1023 -219 -571 -662 -857 -246 269 -1382 -1565 -1277 -1139 -234 325 478 128 334 118 147 760 690 448 412 -110 -689 146 661 520 1084 262 850 1793 879 361 -155 -391 -163 330 -220 -551 -58 447 -282 -365 -396 -782 -400
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