File name: Pandora166s1_PhiladelphiaPA_20230629_L2Fit_fout2c5d20220925p1-8.txt
File generation date: 20230704T152609.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c5p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 166
Spectrometer number: 1
Processing software version used: BlickP v1.8.49
Instrument operation file used: Pandora166_OF_v5d20210217.txt
Instrument calibration file used: Pandora166s1_CF_v5d20220925.txt
Level 1 file used: Pandora166s1_PhiladelphiaPA_20230629_L1_smca1c5d20220925p1-8.txt
Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE
Short location name: PhiladelphiaPA
Country of location: United States
Location latitude [deg]: 39.9919
Location longitude [deg]: -75.0811
Location altitude [m]: 6
Local noon date: 20230629
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: HCHO modification of session 4 "Field cal based on session3"
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0654 305.2061 305.3468 305.4875 305.6282 305.7689 305.9096 306.0503 306.1910 306.3316 306.4722 306.6129 306.7535 306.8941 307.0347 307.1753 307.3158 307.4564 307.5969 307.7375 307.8780 308.0185 308.1590 308.2995 308.4400 308.5805 308.7209 308.8614 309.0018 309.1422 309.2827 309.4231 309.5635 309.7038 309.8442 309.9846 310.1249 310.2652 310.4056 310.5459 310.6862 310.8265 310.9668 311.1070 311.2473 311.3875 311.5278 311.6680 311.8082 311.9484 312.0886 312.2288 312.3690 312.5091 312.6493 312.7894 312.9295 313.0696 313.2097 313.3498 313.4899 313.6300 313.7700 313.9101 314.0501 314.1901 314.3301 314.4701 314.6101 314.7501 314.8901 315.0300 315.1700 315.3099 315.4498 315.5897 315.7296 315.8695 316.0094 316.1493 316.2891 316.4290 316.5688 316.7086 316.8484 316.9882 317.1280 317.2678 317.4076 317.5473 317.6871 317.8268 317.9665 318.1062 318.2459 318.3856 318.5253 318.6650 318.8046 318.9443 319.0839 319.2235 319.3631 319.5027 319.6423 319.7819 319.9215 320.0610 320.2006 320.3401 320.4796 320.6191 320.7586 320.8981 321.0376 321.1770 321.3165 321.4559 321.5954 321.7348 321.8742 322.0136 322.1530 322.2923 322.4317 322.5711 322.7104 322.8497 322.9891 323.1284 323.2677 323.4069 323.5462 323.6855 323.8247 323.9640 324.1032 324.2424 324.3816 324.5208 324.6600 324.7992 324.9383
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20230629T120453.5Z 8580.503397 164 1 14.58 2 63.97 80.62 152.71 319.32 0.00 1 0.00 1 0 17 1.939e-02 7.038e-03 1.111e-02 2.445e-03 3.282090e-01 1.252938e-03 3.858330e-03 -6.000000e+00 1.135162e-02 232.87 -2.00 3.49 -2.00 317.95 0.00e+00 1.050806e-03 1.919657e-04 8.661753e-05 -6.000000e+00 4.480828e-04 288.60 -2.00 20.00 -2.00 317.62 0.00e+00 2.265 0.000 302.00 328.00 3 3.2629e+00 3.3640e-03 2.8607e-02 -6.0000e+00 2.8766e-02 3.7097e-02 3.7545e-03 1.7099e-02 -6.0000e+00 3.1213e-02 -1.5340e-02 2.4214e-03 8.3845e-03 -6.0000e+00 1.8278e-02 7.4361e-04 1.2406e-03 2.3593e-03 -6.0000e+00 7.5367e-03 1.3628e-03 -2.4072e-04 7.1141e-05 2.5675e-05 -6.0000e+00 5.3400e-04 -8.1541e-03 1.3194e-05 12 9 1 12 1 1 98.42 19.74 0.27 -0.00815 -0.00996 13 9 1 5 0 1029.820 26.41 19.99 19.74 28.46 21.0 1059.79 -7945 -608 -8124 -2496 -9315 -4498 1166 -1247 1189 -5336 -4267 -3316 -684 -1755 -1028 2362 -2588 1561 1136 3266 -541 1507 3714 1973 3107 -3283 59 -3588 -385 1061 2911 1577 1430 -416 -4693 -1531 -2995 -798 -1134 -2697 -405 -1818 -358 -765 484 -273 -91 -235 -1639 305 862 1380 1044 776 871 396 1586 95 315 1052 1052 1605 1765 2397 -36 17 -536 192 450 1251 407 126 866 26 293 -332 -734 -1077 -13 -595 -1407 -1267 -2663 -1443 -1158 -341 -173 -57 695 -146 597 566 183 1248 523 591 55 1003 -397 -277 -205 -1002 -107 -323 -942 -1088 -786 -957 -151 328 -16 -24 -58 278 -30 581 773 503 301 -112 -426 -130 372 87 849 467 383 1698 617 288 -168 -249 -28 228 112 -203 -154 207 -2 -416 -278 -447 -283 -562 -45 -663 -185 -665 -296 77 -93 97 -488 -389 -312 -71 -214 -143 356 -433 264 202 592 -104 283 700 398 654 -760 13 -802 -80 216 622 373 368 -113 -1265 -394 -838 -251 -420 -1158 -186 -880 -177 -384 241 -137 -45 -116 -811 151 444 756 605 472 545 253 1021 62 203 669 684 1101 1295 1852 -29 13 -388 136 334 1013 357 114 784 23 247 -260 -536 -762 -9 -476 -1242 -1207 -2704 -1505 -1263 -388 -204 -69 839 -173 673 601 184 1218 533 648 66 1276 -535 -372 -264 -1231 -125 -382 -1179 -1419 -1056 -1330 -217 491 -24 -38 -90 418 -43 795 1049 701 439 -170 -660 -200 560 128 1206 645 512 2253 862 425 -258 -393 -44 373 191 -358 -275 375 -3 -751 -490 -768 -477
SS 20230629T120922.0Z 8580.506504 167 1 50.73 2 63.12 81.27 153.24 321.23 0.00 1 0.00 1 0 17 1.515e-02 5.978e-03 4.360e-03 8.693e-04 3.191448e-01 4.448241e-04 3.745657e-03 -6.000000e+00 8.866888e-03 232.87 -2.00 3.49 -2.00 318.28 0.00e+00 6.493604e-04 7.388035e-05 9.199211e-05 -6.000000e+00 3.500630e-04 288.60 -2.00 20.00 -2.00 317.95 0.00e+00 2.200 0.000 302.00 328.00 3 2.3169e+00 1.2010e-03 2.7814e-02 -6.0000e+00 2.2470e-02 3.3059e-02 1.3439e-03 1.6658e-02 -6.0000e+00 2.4381e-02 -1.3484e-02 8.9280e-04 8.1850e-03 -6.0000e+00 1.4278e-02 -2.7803e-04 4.6216e-04 2.3166e-03 -6.0000e+00 5.8864e-03 3.8046e-03 -1.8211e-04 2.5643e-05 2.5474e-05 -6.0000e+00 4.1719e-04 -7.6960e-03 -3.8076e-06 10 0 0 10 0 0 79.77 19.74 0.21 -0.00770 -0.00906 149 27 1 5 0 340.430 26.41 19.99 19.74 28.80 21.0 1062.13 -2625 -1411 -4395 -4345 -7085 -4352 -2423 -2425 -2947 -5833 -4210 -4600 -1788 -2035 812 -416 -376 725 -688 1331 -307 -546 1620 290 77 -602 -465 -1962 -985 428 1158 1713 1975 -870 -3276 -1528 -2336 -862 -715 -859 -1055 -1232 -463 -740 330 -269 -697 92 -1036 390 585 915 1167 1075 1202 999 704 -186 509 371 1145 1648 1984 2071 -127 -186 -275 -49 1369 860 667 423 460 299 1 -291 -484 -705 34 -445 -1167 -1091 -2319 -1604 -911 -683 -350 -52 282 238 436 338 213 697 387 238 332 795 -199 -314 -350 -868 -393 94 -867 -1196 -830 -820 -259 321 185 2 147 167 -11 634 502 330 320 -200 -316 38 526 401 714 280 374 1366 612 366 -30 -299 -19 143 17 -251 -144 211 -139 -205 -207 -481 -256 -164 -97 -299 -300 -452 -259 -150 -168 -230 -496 -354 -403 -173 -215 97 -56 -54 108 -109 214 -51 -91 271 52 15 -121 -93 -379 -177 75 217 351 442 -208 -762 -341 -570 -242 -241 -341 -463 -535 -206 -335 148 -121 -313 43 -454 182 271 455 617 602 699 596 430 -115 305 220 694 1068 1400 1569 -94 -137 -189 -32 959 685 552 368 401 251 1 -219 -331 -460 23 -342 -961 -998 -2310 -1668 -949 -761 -410 -62 342 279 475 356 207 652 383 262 385 1021 -262 -412 -457 -1046 -442 107 -1076 -1581 -1145 -1125 -373 492 287 4 239 255 -15 881 691 472 465 -310 -504 60 800 587 1046 393 498 1799 868 533 -46 -481 -31 245 30 -457 -269 401 -269 -387 -375 -839 -433
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