File name: Pandora166s1_PhiladelphiaPA_20240110_L2Fit_fwvt1c5d20220925p1-8.txt File generation date: 20240113T082746.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 166 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora166_OF_v5d20210217.txt Instrument calibration file used: Pandora166s1_CF_v5d20220925.txt Level 1 file used: Pandora166s1_PhiladelphiaPA_20240110_L1_smca1c5d20220925p1-8.txt Full location name: Philadelphia, Pennsylvania; Philadelphia-Camden-Wilmington; North East Waste (NE Short location name: PhiladelphiaPA Country of location: United States Location latitude [deg]: 39.9919 Location longitude [deg]: -75.0811 Location altitude [m]: 6 Local noon date: 20240110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: HCHO modification of session 4 "Field cal based on session3" First and last pixel inside fitting window: 1645 1794 Nominal wavelengths inside fitting window [nm]: 492.1120 492.2329 492.3538 492.4746 492.5954 492.7162 492.8370 492.9578 493.0786 493.1993 493.3201 493.4408 493.5615 493.6821 493.8028 493.9234 494.0441 494.1647 494.2853 494.4058 494.5264 494.6469 494.7674 494.8880 495.0084 495.1289 495.2494 495.3698 495.4902 495.6106 495.7310 495.8514 495.9717 496.0921 496.2124 496.3327 496.4530 496.5732 496.6935 496.8137 496.9339 497.0541 497.1743 497.2945 497.4146 497.5348 497.6549 497.7750 497.8951 498.0151 498.1352 498.2552 498.3752 498.4952 498.6152 498.7351 498.8551 498.9750 499.0949 499.2148 499.3347 499.4545 499.5744 499.6942 499.8140 499.9338 500.0536 500.1733 500.2930 500.4128 500.5325 500.6521 500.7718 500.8915 501.0111 501.1307 501.2503 501.3699 501.4895 501.6090 501.7285 501.8480 501.9675 502.0870 502.2065 502.3259 502.4454 502.5648 502.6842 502.8035 502.9229 503.0422 503.1615 503.2809 503.4001 503.5194 503.6387 503.7579 503.8771 503.9963 504.1155 504.2347 504.3538 504.4729 504.5921 504.7112 504.8302 504.9493 505.0683 505.1874 505.3064 505.4254 505.5444 505.6633 505.7823 505.9012 506.0201 506.1390 506.2578 506.3767 506.4955 506.6143 506.7331 506.8519 506.9707 507.0894 507.2082 507.3269 507.4456 507.5643 507.6829 507.8016 507.9202 508.0388 508.1574 508.2760 508.3945 508.5131 508.6316 508.7501 508.8686 508.9870 509.1055 509.2239 509.3423 509.4607 509.5791 509.6975 509.8158 509.9341 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240110T134849.6Z 8775.575575 87 1 5.88 2 77.36 133.53 77.09 147.23 0.00 1 0.00 1 0 15 2.584e-03 2.570e-03 1.105e-04 1.103e-04 2.583200e+03 6.411639e+00 1.911522e+02 -6.000000e+00 1.383188e+02 276.40 -2.00 20.00 -2.00 505.27 0.00e+00 1.045584e-03 2.970746e-06 5.952326e-05 -6.000000e+00 7.105249e-05 276.40 -2.00 20.00 -2.00 500.48 0.00e+00 5.991329e-01 2.165309e-03 2.150499e-02 -6.000000e+00 5.102012e-02 223.70 -2.00 3.49 -2.00 502.07 0.00e+00 4.446 0.002 489.00 513.00 1 4.0071e-01 1.6530e-04 6.7632e-03 -6.0000e+00 3.8978e-03 7.0792e-03 4.3069e-05 5.9798e-04 -6.0000e+00 1.0219e-03 6.5507e-01 -4.4088e-05 1.0454e-05 3.3137e-05 -6.0000e+00 2.5220e-04 -1.6297e-02 -7.1306e-05 10 0 0 10 0 0 38.92 19.38 1.71 -0.01630 -0.01660 762 138 1 4 0 7.710 26.21 20.01 19.38 14.60 23.6 969.07 -512 -385 -140 11 126 425 507 435 401 261 257 92 -187 -179 -241 -254 -96 111 109 21 119 175 140 246 312 258 288 108 -291 -400 -354 -413 -174 183 58 -47 95 27 -160 -146 -63 -7 108 241 258 297 286 211 82 -249 -454 -599 -646 -497 -256 -175 -62 4 45 123 214 281 228 259 172 81 69 -41 -170 -364 -247 -184 -162 35 18 -133 -166 -138 -228 -309 -263 -327 -304 -145 -32 -163 -157 -138 -139 -94 17 225 262 225 268 299 56 -136 -254 -491 -565 -469 -208 -24 -191 -183 -148 -245 -156 -65 -134 -23 165 227 296 475 560 489 346 291 193 121 200 296 77 166 246 145 242 261 -5 -140 -82 -327 -303 -61 -116 -153 20 176 97 200 313 262 266 61 -121 -332 -363 -412 -488 -373 -140 11 129 443 537 448 412 274 266 94 -188 -179 -239 -254 -98 116 112 22 124 182 145 257 327 270 300 111 -302 -403 -351 -413 -178 187 61 -49 99 28 -163 -148 -64 -7 111 252 271 312 299 217 83 -246 -452 -583 -624 -485 -257 -174 -63 4 46 126 218 288 235 267 176 81 69 -41 -170 -360 -242 -181 -161 34 18 -129 -165 -135 -220 -298 -255 -319 -299 -138 -31 -159 -154 -135 -136 -92 16 225 266 228 269 295 54 -133 -242 -461 -529 -447 -197 -24 -192 -185 -148 -241 -152 -64 -133 -23 163 227 298 479 567 496 349 289 189 120 198 295 75 161 239 141 234 252 -5 -137 -79 -312 -289 -59 -115 -149 20 176 97 201 316 267 270 62 -120 -322 -346 -391 SQ 20240110T134855.5Z 8775.575643 87 2 5.88 2 77.35 133.55 77.08 147.25 0.00 1 0.00 1 0 22 2.655e-03 2.637e-03 1.078e-04 1.076e-04 2.562547e+03 6.276760e+00 1.885646e+02 -6.000000e+00 1.420993e+02 276.40 -2.00 20.00 -2.00 505.27 0.00e+00 1.000613e-03 2.903527e-06 5.701980e-05 -6.000000e+00 7.299453e-05 276.40 -2.00 20.00 -2.00 500.46 0.00e+00 6.060537e-01 2.115348e-03 2.145116e-02 -6.000000e+00 5.241484e-02 223.70 -2.00 3.49 -2.00 502.05 0.00e+00 4.441 0.002 489.00 513.00 1 3.5340e-01 1.6162e-04 6.7433e-03 -6.0000e+00 4.0044e-03 6.9114e-03 4.2054e-05 5.9600e-04 -6.0000e+00 1.0498e-03 6.8734e-01 -4.9861e-05 1.0204e-05 3.2384e-05 -6.0000e+00 2.5909e-04 -1.6171e-02 -7.2475e-05 10 0 0 10 0 0 50.71 19.38 1.71 -0.01617 -0.01652 762 138 1 4 0 7.710 26.21 20.01 19.38 14.60 23.6 969.07 -514 -398 -150 -1 127 430 499 445 417 273 243 87 -185 -201 -249 -244 -69 123 121 6 142 180 153 258 322 283 285 122 -289 -393 -388 -414 -169 188 50 -47 108 14 -139 -151 -43 -15 92 250 267 304 290 216 81 -237 -464 -586 -666 -490 -248 -158 -71 6 39 149 219 305 253 271 220 104 46 -45 -171 -346 -277 -207 -164 78 1 -151 -191 -152 -245 -319 -269 -311 -361 -160 -67 -154 -172 -115 -125 -84 -11 236 270 223 268 304 57 -152 -272 -548 -574 -472 -209 -43 -184 -186 -149 -257 -185 -59 -106 -34 158 263 328 497 570 494 344 293 193 146 223 291 93 169 237 153 244 268 22 -135 -85 -353 -342 -60 -119 -159 22 167 89 202 338 259 278 74 -124 -352 -362 -424 -500 -394 -148 -1 128 441 521 468 437 283 248 87 -190 -204 -252 -249 -69 126 126 7 150 191 162 266 333 293 294 128 -296 -391 -394 -408 -170 195 51 -49 111 15 -144 -156 -44 -16 94 257 277 316 299 220 84 -239 -456 -583 -657 -488 -244 -161 -71 6 39 150 220 309 257 275 221 107 47 -45 -169 -337 -268 -201 -161 77 1 -150 -187 -146 -233 -303 -257 -299 -350 -156 -66 -153 -172 -115 -125 -84 -11 233 270 223 266 296 56 -147 -256 -507 -530 -443 -202 -42 -183 -185 -147 -249 -178 -57 -104 -34 160 269 336 495 571 495 343 297 192 144 219 286 92 168 235 152 241 264 22 -130 -81 -333 -322 -57 -116 -158 21 164 89 201 338 260 280 74 -121 -349 -352 -411 SQ 20240110T134901.5Z 8775.575712 87 3 5.88 2 77.33 133.57 77.07 147.27 0.00 1 0.00 1 0 15 2.654e-03 2.640e-03 1.060e-04 1.058e-04 2.543154e+03 6.151773e+00 1.872507e+02 -6.000000e+00 1.420776e+02 276.40 -2.00 20.00 -2.00 505.28 0.00e+00 1.022649e-03 2.853632e-06 5.825085e-05 -6.000000e+00 7.298316e-05 276.40 -2.00 20.00 -2.00 500.50 0.00e+00 6.019593e-01 2.078029e-03 2.145457e-02 -6.000000e+00 5.240597e-02 223.70 -2.00 3.49 -2.00 502.09 0.00e+00 4.437 0.002 489.00 513.00 1 3.2649e-01 1.5869e-04 6.7430e-03 -6.0000e+00 4.0037e-03 6.9473e-03 4.1256e-05 5.9496e-04 -6.0000e+00 1.0496e-03 7.0658e-01 -3.2239e-05 1.0038e-05 3.2776e-05 -6.0000e+00 2.5905e-04 -1.7111e-02 -6.5440e-05 10 0 0 10 0 0 -6.02 19.38 1.71 -0.01711 -0.01733 762 138 1 4 0 7.710 26.21 20.01 19.38 14.60 23.6 969.07 -524 -423 -159 -4 133 421 489 430 424 272 257 73 -185 -192 -252 -267 -91 98 128 16 145 176 147 253 325 261 299 110 -281 -405 -386 -417 -170 170 57 -37 111 32 -146 -143 -57 -7 102 250 273 308 304 208 86 -233 -469 -618 -652 -502 -266 -174 -53 28 43 150 189 286 248 266 203 107 53 -41 -177 -356 -281 -182 -165 59 25 -163 -177 -163 -241 -313 -283 -336 -341 -129 -53 -153 -177 -140 -146 -118 1 229 270 234 258 288 70 -145 -289 -540 -554 -460 -207 -43 -154 -176 -136 -253 -180 -75 -103 -25 183 282 310 499 563 489 356 289 199 101 210 304 113 177 228 138 252 269 9 -140 -100 -342 -337 -59 -101 -148 26 163 82 195 336 273 265 72 -138 -357 -362 -446 -514 -408 -159 -4 136 437 516 457 448 284 265 75 -186 -190 -249 -265 -92 102 131 17 150 183 153 263 340 272 311 112 -291 -406 -381 -415 -173 172 59 -39 116 32 -149 -144 -58 -7 105 260 286 323 317 214 87 -238 -465 -599 -627 -488 -265 -173 -54 29 44 153 193 293 254 273 206 107 52 -42 -177 -351 -274 -178 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