File name: Pandora100s1_PhoenixAZ_20260526_L2Fit_fout2c5d20240611p1-8.txt File generation date: 20260528T204016.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 100 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora100_OF_v3d20220425.txt Instrument calibration file used: Pandora100s1_CF_v5d20240611.txt Level 1 file used: Pandora100s1_PhoenixAZ_20260526_L1_smca1c5d20240611p1-8.txt Full location name: Phoenix, Arizona - Central Phoenix Short location name: PhoenixAZ Country of location: United States Location latitude [deg]: 33.4580 Location longitude [deg]: -112.0466 Location altitude [m]: 339 Local noon date: 20260526 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.0855 305.2267 305.3678 305.5090 305.6502 305.7913 305.9324 306.0736 306.2147 306.3558 306.4969 306.6379 306.7790 306.9201 307.0611 307.2021 307.3432 307.4842 307.6252 307.7661 307.9071 308.0481 308.1890 308.3300 308.4709 308.6118 308.7528 308.8937 309.0345 309.1754 309.3163 309.4571 309.5980 309.7388 309.8796 310.0204 310.1612 310.3020 310.4428 310.5836 310.7243 310.8651 311.0058 311.1465 311.2872 311.4279 311.5686 311.7093 311.8500 311.9906 312.1313 312.2719 312.4125 312.5531 312.6937 312.8343 312.9749 313.1154 313.2560 313.3965 313.5371 313.6776 313.8181 313.9586 314.0991 314.2396 314.3800 314.5205 314.6609 314.8013 314.9418 315.0822 315.2226 315.3629 315.5033 315.6437 315.7840 315.9244 316.0647 316.2050 316.3453 316.4856 316.6259 316.7662 316.9064 317.0467 317.1869 317.3271 317.4673 317.6075 317.7477 317.8879 318.0281 318.1682 318.3084 318.4485 318.5886 318.7288 318.8689 319.0089 319.1490 319.2891 319.4291 319.5692 319.7092 319.8492 319.9893 320.1293 320.2692 320.4092 320.5492 320.6891 320.8291 320.9690 321.1089 321.2488 321.3887 321.5286 321.6685 321.8083 321.9482 322.0880 322.2278 322.3677 322.5075 322.6473 322.7870 322.9268 323.0666 323.2063 323.3460 323.4858 323.6255 323.7652 323.9049 324.0445 324.1842 324.3239 324.4635 324.6031 324.7427 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Latitude at beginning of measurement [deg], negative=South of equator, positive=North of equator, -999=no latitude retrieved Column 8: Longitude at beginning of measurement [deg], negative=West of Greenwich, positive=East of Greenwich, -999=no longitude retrieved Column 9: Altitude a.s.l. at beginning of measurement [m], -999=no altitude retrieved Column 10: Data processing type index Column 11: Solar zenith angle for center-time of measurement in degree Column 12: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 13: Lunar zenith angle for center-time of measurement in degree Column 14: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 15: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 16: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 17: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 18: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 19: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 20: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 21: rms of unweighted fitting residuals, -9=fitting not successful Column 22: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 23: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 24: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 25: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 26: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 27: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 28: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 29: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 30: Ozone effective temperature [K] Column 31: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 32: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 33: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 34: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 35: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 36: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 37: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 38: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 39: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 40: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 41: Sulfur dioxide effective temperature [K] Column 42: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 43: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 44: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 45: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 46: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 47: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 48: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 49: Lower limit used for wavelength scaling [nm] Column 50: Upper limit used for wavelength scaling [nm] Column 51: Order of smoothing polynomial Column 52: Smoothing polynomial coefficient, order 0 Column 53: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 55: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 56: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 57: Smoothing polynomial coefficient, order 1 Column 58: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 60: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 61: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 62: Smoothing polynomial coefficient, order 2 Column 63: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 65: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 66: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 67: Smoothing polynomial coefficient, order 3 Column 68: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 70: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 71: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 72: Mean value of measured data inside fitting window [same units as measurements] Column 73: Wavelength change polynomial coefficient, order 0 Column 74: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 77: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 78: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 79: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 80: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 82: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 84: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 85: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 86: Atmospheric variability [%], 999=no atmospheric variability was determined Column 87: Wavelength effective temperature [°C], 999=no effective temperature given Column 88: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 89: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 90: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 91: Number of bright count cycles Column 92: Number of dark count cycles Column 93: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 94: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 95: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 96: Integration time [ms] Column 97: Mean over camera offsets [deg], -9=camera not in automatic mode Column 98: Maximum of camera offsets [deg], -9=camera not in automatic mode Column 99: Temperature at electronics board [°C], 999=no temperature signal Column 100: Spectrometer control temperature [°C], 999=no temperature signal Column 101: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 102: Temperature in head sensor [°C], 999=no temperature signal Column 103: Humidity in head sensor [%], -9=no humidity signal Column 104: Pressure in head sensor [hPa], -9=no pressure signal Columns 105-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260526T130320.9Z 9642.543991 123 1 48.51 -999.000000 -999.000000 -999 2 82.83 69.31 134.24 294.52 0.00 1 0.00 1 0 17 1.011e+00 1.705e-02 3.232e-01 6.062e-03 1.042418e+00 4.098389e-03 1.115551e-02 -6.000000e+00 6.870874e-01 231.36 -2.00 3.34 -2.00 322.22 0.00e+00 8.745596e-03 2.869667e-03 3.505744e-03 -6.000000e+00 3.583943e-02 287.30 -2.00 20.00 -2.00 321.78 0.00e+00 7.373 0.006 302.00 328.00 3 8.1462e-01 1.8353e-02 9.1402e-02 -6.0000e+00 1.7343e+00 6.8365e-01 2.9049e-02 6.1515e-02 -6.0000e+00 1.8804e+00 -7.7258e-01 2.9548e-02 3.5079e-02 -6.0000e+00 1.0937e+00 2.8465e-01 1.2684e-02 1.6523e-02 -6.0000e+00 4.4714e-01 6.3802e-05 -9.7407e-04 1.8432e-04 3.8777e-04 -6.0000e+00 3.9329e-02 3.3534e-03 0.0000e+00 12 8 8 10 0 0 -23.95 23.30 0.32 0.00335 -0.00397 67 15 1 5 0 723.900 -9.000 -9.000 26.51 20.00 23.30 27.86 29.7 966.74 -382072 -251754 900000 -305037 900000 -264692 900000 900000 900000 900000 -299773 -156608 900000 900000 900000 -180714 -116497 -140252 -129448 900000 900000 -158470 -1576 -111972 900000 -31700 -62788 -206052 900000 -30229 900000 5761 900000 -23228 -103299 -2646 691305 12724 -28708 900000 57487 75541 76477 170846 993 25798 -13069 -9455 66054 83116 81131 11050 35459 31437 15362 17936 26835 20883 6052 4357 14961 16047 11836 14327 17137 26020 20790 11491 13938 15787 11110 19889 1352 4110 4236 1484 14500 5112 19538 3215 16 -414 3334 1454 -331 2003 -2144 1230 1340 -2036 -3526 2081 -2707 -1470 -831 -711 -735 -900 -1528 -2355 312 -952 -504 -584 554 -3418 -483 -1310 -1704 -1212 -2440 -1402 -876 -274 109 1692 1148 1655 633 -377 562 640 1135 111 2279 1013 702 706 649 478 691 -392 -531 -50 12 579 -147 -337 -40 -125 -505 -400 -5894 -1483 900000 -2715 900000 -1559 900000 900000 900000 900000 -3832 -923 900000 900000 900000 -2602 -1049 -1781 -1597 900000 900000 -2795 -9 -1367 900000 -188 -516 -7134 900000 -251 900000 51 900000 -334 -3320 -33 4073 180 -716 900000 792 943 995 1007 29 617 -486 -369 1383 1662 1881 568 1601 1596 965 1137 1576 1286 421 311 1029 1220 1068 1412 1781 2618 2338 1548 2062 2531 1979 3295 258 710 669 227 1986 848 3328 764 5 -135 1158 549 -134 831 -955 534 571 -862 -1464 811 -1155 -692 -454 -457 -547 -746 -1345 -2074 252 -716 -356 -413 403 -2731 -405 -1224 -1805 -1444 -3229 -1948 -1240 -385 151 2320 1619 2396 945 -564 807 878 1497 144 2844 1274 920 1019 1063 880 1392 -858 -1242 -125 31 1528 -393 -899 -103 -309 -1186 -903 SS 20260526T131343.6Z 9642.551199 126 1 48.81 -999.000000 -999.000000 -999 2 80.79 70.63 136.14 296.76 0.00 1 0.00 1 0 17 7.138e-01 9.542e-03 1.413e-01 2.285e-03 8.679972e-01 1.405705e-03 9.456678e-03 -6.000000e+00 4.736075e-01 231.37 -2.00 3.34 -2.00 321.58 0.00e+00 8.089176e-03 8.303194e-04 3.526627e-03 -6.000000e+00 2.125537e-02 287.30 -2.00 20.00 -2.00 321.05 0.00e+00 5.934 0.003 302.00 328.00 3 7.2333e-01 5.3508e-03 7.3654e-02 -6.0000e+00 1.1837e+00 2.7735e-01 7.8234e-03 4.7945e-02 -6.0000e+00 1.2739e+00 -2.8604e-01 7.7931e-03 3.0374e-02 -6.0000e+00 7.5649e-01 9.8954e-02 3.5148e-03 1.3961e-02 -6.0000e+00 3.1188e-01 3.2732e-04 -6.1824e-04 6.8428e-05 2.6284e-04 -6.0000e+00 2.6553e-02 3.2982e-03 0.0000e+00 12 8 8 10 0 0 2.87 23.26 0.27 0.00330 -0.00135 171 39 1 5 0 285.410 -9.000 -9.000 26.41 19.99 23.26 28.46 29.7 966.85 -345958 -254317 -210330 -224535 -190247 -231201 900000 -195812 -172361 -197203 -141207 -223143 -137314 -140061 -45445 -148721 -68311 -118918 -84165 -35842 -46841 -43678 -82471 -41046 -75393 -46561 -84331 -84395 -89650 -4321 -21180 -32896 148 -23831 -24607 -17535 13285 -20757 -5230 3558 5598 -9730 5726 4348 4561 5156 -1856 6819 9323 11278 6343 3927 3571 10826 2418 5788 5630 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1039 494 -115 -712 -911 539 205 -167 -213 -234 331 -521 -58 -1014 SS 20260526T132324.8Z 9642.557927 131 1 16.10 -999.000000 -999.000000 -999 2 78.88 71.85 137.89 298.98 0.00 1 0.00 1 0 17 5.308e-01 7.756e-03 2.535e-01 3.530e-03 7.522946e-01 2.116164e-03 8.153965e-03 -6.000000e+00 3.497538e-01 231.37 -2.00 3.34 -2.00 320.99 0.00e+00 5.668600e-03 1.040720e-03 1.871520e-03 -6.000000e+00 1.578908e-02 287.30 -2.00 20.00 -2.00 320.40 0.00e+00 5.001 0.002 302.00 328.00 3 1.6211e+00 7.1848e-03 6.1943e-02 -6.0000e+00 8.7366e-01 1.4581e-01 9.7403e-03 3.9390e-02 -6.0000e+00 9.3978e-01 -1.1732e-01 9.3556e-03 2.3540e-02 -6.0000e+00 5.6002e-01 3.1645e-02 4.4237e-03 1.0765e-02 -6.0000e+00 2.3190e-01 3.5561e-04 -4.8338e-04 1.1005e-04 1.6780e-04 -6.0000e+00 1.9562e-02 2.2454e-03 0.0000e+00 12 9 1 12 1 1 11.28 23.25 0.29 0.00225 -0.00139 33 24 1 5 0 473.520 -9.000 -9.000 26.41 20.00 23.25 28.94 29.7 966.84 -269913 -165889 -141121 -582 -156831 -173880 77966 158357 59347 -133693 -152706 -129289 -9203 -23326 288858 -77177 -23751 -66387 -53832 -157 -55745 -25427 -59225 20272 -29284 -19870 -40026 -33667 -29295 1195 2889 -8813 -8849 -23367 -10829 -13619 23577 -18352 1989 2663 -5277 -10318 -276 -3630 -2259 1538 -2313 4431 3634 4655 1480 2668 2696 3855 -728 2882 975 892 2276 -678 6099 1474 3856 2639 3757 2284 3310 912 2602 1556 860 1895 -478 -746 -1376 743 -613 150 1611 66 -881 -1229 -762 -971 -1178 -818 -389 85 -200 -101 11 288 382 176 706 539 88 -190 -559 -929 -222 275 -249 1017 -672 -1050 -753 -609 -461 -175 -405 -482 -461 -211 713 1115 973 848 210 -380 -377 47 46 472 919 814 -14 796 503 -92 -114 -500 -371 117 202 -156 -253 -60 70 -135 120 -188 -3885 -986 -706 -2 -932 -1251 268 545 204 -962 -1529 -1254 -38 -145 994 -1135 -262 -1142 -982 -2 -1151 -403 -1386 230 -585 -376 -951 -776 -696 24 68 -276 -314 -929 -432 -537 795 -1016 107 165 -396 -885 -23 -320 -204 139 -227 433 387 540 198 395 439 671 -141 558 196 179 449 -140 1256 352 1006 763 1131 714 1055 320 998 612 364 810 -204 -300 -561 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