File name: Pandora100s1_PhoenixAZ_20260623_L2Fit_fout2c5d20240611p1-8.txt File generation date: 20260702T203422.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 100 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora100_OF_v3d20220425.txt Instrument calibration file used: Pandora100s1_CF_v5d20240611.txt Level 1 file used: Pandora100s1_PhoenixAZ_20260623_L1_smca1c5d20240611p1-8.txt Full location name: Phoenix, Arizona - Central Phoenix Short location name: PhoenixAZ Country of location: United States Location latitude [deg]: 33.4580 Location longitude [deg]: -112.0466 Location altitude [m]: 339 Local noon date: 20260623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 195 336 Nominal wavelengths inside fitting window [nm]: 305.0855 305.2267 305.3678 305.5090 305.6502 305.7913 305.9324 306.0736 306.2147 306.3558 306.4969 306.6379 306.7790 306.9201 307.0611 307.2021 307.3432 307.4842 307.6252 307.7661 307.9071 308.0481 308.1890 308.3300 308.4709 308.6118 308.7528 308.8937 309.0345 309.1754 309.3163 309.4571 309.5980 309.7388 309.8796 310.0204 310.1612 310.3020 310.4428 310.5836 310.7243 310.8651 311.0058 311.1465 311.2872 311.4279 311.5686 311.7093 311.8500 311.9906 312.1313 312.2719 312.4125 312.5531 312.6937 312.8343 312.9749 313.1154 313.2560 313.3965 313.5371 313.6776 313.8181 313.9586 314.0991 314.2396 314.3800 314.5205 314.6609 314.8013 314.9418 315.0822 315.2226 315.3629 315.5033 315.6437 315.7840 315.9244 316.0647 316.2050 316.3453 316.4856 316.6259 316.7662 316.9064 317.0467 317.1869 317.3271 317.4673 317.6075 317.7477 317.8879 318.0281 318.1682 318.3084 318.4485 318.5886 318.7288 318.8689 319.0089 319.1490 319.2891 319.4291 319.5692 319.7092 319.8492 319.9893 320.1293 320.2692 320.4092 320.5492 320.6891 320.8291 320.9690 321.1089 321.2488 321.3887 321.5286 321.6685 321.8083 321.9482 322.0880 322.2278 322.3677 322.5075 322.6473 322.7870 322.9268 323.0666 323.2063 323.3460 323.4858 323.6255 323.7652 323.9049 324.0445 324.1842 324.3239 324.4635 324.6031 324.7427 324.8824 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Latitude at beginning of measurement [deg], negative=South of equator, positive=North of equator, -999=no latitude retrieved Column 8: Longitude at beginning of measurement [deg], negative=West of Greenwich, positive=East of Greenwich, -999=no longitude retrieved Column 9: Altitude a.s.l. at beginning of measurement [m], -999=no altitude retrieved Column 10: Data processing type index Column 11: Solar zenith angle for center-time of measurement in degree Column 12: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 13: Lunar zenith angle for center-time of measurement in degree Column 14: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 15: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 16: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 17: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 18: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 19: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 20: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 21: rms of unweighted fitting residuals, -9=fitting not successful Column 22: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 23: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 24: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 25: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 26: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 27: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 28: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 29: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 30: Ozone effective temperature [K] Column 31: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 32: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 33: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 34: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 35: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 36: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 37: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 38: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 39: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 40: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 41: Sulfur dioxide effective temperature [K] Column 42: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 43: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 44: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 45: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 46: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 47: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 48: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 49: Lower limit used for wavelength scaling [nm] Column 50: Upper limit used for wavelength scaling [nm] Column 51: Order of smoothing polynomial Column 52: Smoothing polynomial coefficient, order 0 Column 53: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 55: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 56: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 57: Smoothing polynomial coefficient, order 1 Column 58: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 60: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 61: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 62: Smoothing polynomial coefficient, order 2 Column 63: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 65: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 66: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 67: Smoothing polynomial coefficient, order 3 Column 68: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 70: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 71: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 72: Mean value of measured data inside fitting window [same units as measurements] Column 73: Wavelength change polynomial coefficient, order 0 Column 74: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 77: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 78: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 79: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 80: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 82: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 84: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 85: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 86: Atmospheric variability [%], 999=no atmospheric variability was determined Column 87: Wavelength effective temperature [°C], 999=no effective temperature given Column 88: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 89: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 90: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 91: Number of bright count cycles Column 92: Number of dark count cycles Column 93: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 94: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 95: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 96: Integration time [ms] Column 97: Mean over camera offsets [deg], -9=camera not in automatic mode Column 98: Maximum of camera offsets [deg], -9=camera not in automatic mode Column 99: Temperature at electronics board [°C], 999=no temperature signal Column 100: Spectrometer control temperature [°C], 999=no temperature signal Column 101: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 102: Temperature in head sensor [°C], 999=no temperature signal Column 103: Humidity in head sensor [%], -9=no humidity signal Column 104: Pressure in head sensor [hPa], -9=no pressure signal Columns 105-246: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 247-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260623T125136.6Z 9670.535840 63 1 49.78 -999.000000 -999.000000 -999 2 84.84 65.25 148.80 307.36 0.00 1 0.00 1 0 25 8.772e-01 1.077e-01 2.307e-01 2.678e-02 1.168426e+00 2.247498e-02 2.008894e-02 -6.000000e+00 7.160616e-01 231.84 -2.00 3.34 -2.00 322.13 0.00e+00 -8.351331e-02 9.472327e-03 3.613016e-02 -6.000000e+00 7.781183e-02 289.71 -2.00 20.00 -2.00 321.45 0.00e+00 9.584 0.013 302.00 328.00 3 7.8619e-01 8.6476e-02 2.2628e-01 -6.0000e+00 1.8409e+00 2.4887e+00 1.0094e-01 2.1506e-01 -6.0000e+00 2.0508e+00 -2.6341e+00 4.9223e-02 6.5000e-02 -6.0000e+00 1.1665e+00 8.7398e-01 2.8907e-02 9.0977e-03 -6.0000e+00 5.1410e-01 5.5493e-06 -9.5630e-04 9.7491e-04 1.1677e-03 -6.0000e+00 4.4063e-02 5.2775e-03 0.0000e+00 12 9 8 11 32 0 30.13 23.52 0.25 0.00528 -0.00191 15 3 1 5 0 3318.200 -9.000 -9.000 26.73 20.00 23.52 37.06 25.5 973.92 900000 32499 900000 900000 900000 900000 49899 900000 900000 900000 900000 900000 900000 59796 900000 900000 900000 900000 900000 900000 900000 900000 -5522 900000 900000 900000 900000 900000 900000 15766 900000 -73985 900000 900000 900000 900000 900000 900000 900000 4829 -8628 382666 900000 -29041 900000 900000 900000 900000 900000 -35374 900000 900000 900000 900000 900000 900000 900000 900000 14548 900000 900000 900000 900000 900000 -13761 900000 900000 16150 900000 900000 900000 -15225 85565 -35546 284968 900000 900000 900000 900000 900000 442463 -33789 127343 93767 92338 173394 23784 56109 74826 40209 -26782 62665 128840 39360 -29786 49864 23500 19242 13567 8107 32562 45673 1074 19346 51618 -38395 24488 8542 8996 8062 -9278 -4775 14661 -127 7214 15777 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7437 9827 -6471 -60 1148 SS 20260623T130325.0Z 9670.544040 66 1 48.68 -999.000000 -999.000000 -999 2 82.59 66.77 150.66 311.44 0.00 1 0.00 1 0 17 6.287e-01 1.261e-02 2.770e-01 5.350e-03 8.367126e-01 3.443724e-03 9.108094e-03 -6.000000e+00 4.248462e-01 231.84 -2.00 3.34 -2.00 321.83 0.00e+00 8.692249e-03 2.198616e-03 2.572597e-03 -6.000000e+00 2.129968e-02 289.71 -2.00 20.00 -2.00 321.30 0.00e+00 7.173 0.005 302.00 328.00 3 1.0732e+00 1.4242e-02 8.1897e-02 -6.0000e+00 1.0713e+00 3.3758e-01 2.0950e-02 4.5878e-02 -6.0000e+00 1.1577e+00 -3.4381e-01 2.0427e-02 2.7786e-02 -6.0000e+00 6.7565e-01 1.1814e-01 9.0947e-03 1.3862e-02 -6.0000e+00 2.7792e-01 7.9235e-05 -7.3811e-04 1.7424e-04 2.6683e-04 -6.0000e+00 2.4037e-02 4.5393e-03 0.0000e+00 12 8 8 10 0 0 26.17 23.52 0.27 0.00454 -0.00101 65 15 1 5 0 748.850 -9.000 -9.000 26.73 20.00 23.52 37.35 25.4 974.30 -300559 -209256 900000 -270286 900000 -244513 900000 900000 900000 900000 -105643 -154097 900000 900000 67048 -112277 -102472 -76972 -158398 900000 -107625 -7753 -36845 -47701 -26038 -86844 -57715 -135588 -46557 -25054 900000 -63457 243973 -75723 27043 -38714 43075 -50173 -24497 41294 -8837 -6719 10798 46266 -4303 29275 -22625 23460 19290 24662 15811 -182 3191 15430 5224 -4472 12728 5837 10107 4054 14626 4742 6175 3153 11488 10460 2827 2573 4612 10960 36 14987 -2984 4647 -1894 3807 -173 -3119 10757 538 905 -3552 2648 -3651 1894 -1136 -868 -1531 1809 -2036 -246 -1100 -320 127 -869 1320 -903 1139 -1443 -511 160 761 -1655 -198 -806 -2495 -714 -778 -12 -594 -838 -1142 76 -649 868 1014 660 176 44 -227 -273 574 482 582 1883 1155 -22 931 309 62 520 -361 -659 174 311 102 -13 -547 570 -547 -238 -212 -2969 -1089 900000 -2542 900000 -1785 900000 900000 900000 900000 -550 -938 900000 900000 349 -1220 -1185 -779 -3845 900000 -1757 -49 -324 -496 -232 -1444 -742 -3858 -614 -312 900000 -1663 1270 -2702 371 -1049 596 -2003 -903 931 -359 -290 417 1329 -208 1077 -1445 1034 965 1301 1017 -15 286 1328 524 -510 1251 613 1013 440 1535 608 878 509 1820 1728 523 517 1013 2500 10 3568 -822 1122 -450 810 -38 -767 2669 173 335 -1540 1182 -1847 965 -625 -494 -885 1003 -1128 -129 -569 -168 72 -569 978 -777 1058 -1438 -501 147 650 -1386 -165 -707 -2352 -709 -841 -14 -784 -1196 -1702 113 -956 1241 1444 964 266 68 -356 -421 850 693 815 2551 1556 -31 1397 517 114 1033 -767 -1487 410 768 260 -33 -1413 1435 -1341 -556 -482 SS 20260623T131335.1Z 9670.551101 69 1 22.68 -999.000000 -999.000000 -999 2 80.64 68.05 152.16 315.30 0.00 1 0.00 1 0 17 5.321e-01 1.041e-02 2.179e-01 4.378e-03 7.056390e-01 2.648750e-03 7.829910e-03 -6.000000e+00 3.545603e-01 231.84 -2.00 3.34 -2.00 321.14 0.00e+00 7.024924e-03 1.360875e-03 2.464620e-03 -6.000000e+00 1.627587e-02 289.71 -2.00 20.00 -2.00 320.51 0.00e+00 5.844 0.003 302.00 328.00 3 1.5386e+00 9.3261e-03 6.7136e-02 -6.0000e+00 8.8560e-01 1.9705e-01 1.2591e-02 3.7531e-02 -6.0000e+00 9.5244e-01 -1.8879e-01 1.1546e-02 2.2703e-02 -6.0000e+00 5.6562e-01 6.1533e-02 5.4280e-03 1.0168e-02 -6.0000e+00 2.3346e-01 1.9262e-04 -9.4997e-04 1.4369e-04 1.7638e-04 -6.0000e+00 1.9850e-02 3.2028e-03 0.0000e+00 12 9 9 12 1 1 -78.46 23.52 0.32 0.00320 -0.00394 34 17 1 5 0 647.900 -9.000 -9.000 26.73 20.00 23.52 37.93 25.6 974.52 -210577 -133064 304466 -158712 900000 -228261 900000 -112426 -35822 -91939 -175164 -153422 -112738 -66494 7836 -59375 -54058 -55432 -76785 125358 -28771 -22581 -62077 -3969 -39268 -32441 -11273 -69786 -29561 -3379 15932 -20218 41703 -19835 -17459 -16271 19565 -15712 -12785 30973 728 6690 5504 11841 -3982 5595 -6561 4512 2362 7203 5267 1039 6245 8722 4305 -857 2716 -2107 1929 1585 3640 3643 4125 4121 3504 3150 4889 1337 2160 5506 -1341 4811 -1034 1384 -841 -148 287 -47 5781 -561 -1316 -2490 153 -2234 -961 -192 -787 -1138 237 -991 -717 788 765 410 1683 548 -650 -412 -847 -913 76 -1 -217 -98 -463 -1510 -585 -835 -485 -314 -605 -1338 77 178 816 1015 1321 504 316 60 -433 541 38 741 1065 670 -4 824 659 106 128 -405 -182 -96 34 -99 -69 -458 158 -452 -75 131 -2465 -848 1299 -1413 900000 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