File name: Pandora187s1_PittsburghPA_20211117_L2Fit_fout2c2d20210902p1-8.txt
File generation date: 20251128T075848.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 187
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora187_OF_v4d20210517.txt
Instrument calibration file used: Pandora187s1_CF_v2d20210902.txt
Level 1 file used: Pandora187s1_PittsburghPA_20211117_L1_smca1c2d20210902p1-8.txt
Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008)
Short location name: PittsburghPA
Country of location: United States
Location latitude [deg]: 40.4655
Location longitude [deg]: -79.9608
Location altitude [m]: 265
Local noon date: 20211117
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 194 335
Nominal wavelengths inside fitting window [nm]: 305.1270 305.2683 305.4097 305.5510 305.6924 305.8337 305.9750 306.1163 306.2576 306.3989 306.5402 306.6814 306.8227 306.9639 307.1051 307.2464 307.3876 307.5288 307.6699 307.8111 307.9523 308.0934 308.2346 308.3757 308.5168 308.6579 308.7990 308.9401 309.0812 309.2222 309.3633 309.5043 309.6454 309.7864 309.9274 310.0684 310.2094 310.3504 310.4914 310.6323 310.7733 310.9142 311.0551 311.1960 311.3369 311.4778 311.6187 311.7596 311.9004 312.0413 312.1821 312.3230 312.4638 312.6046 312.7454 312.8862 313.0269 313.1677 313.3084 313.4492 313.5899 313.7306 313.8713 314.0120 314.1527 314.2934 314.4341 314.5747 314.7154 314.8560 314.9966 315.1372 315.2778 315.4184 315.5590 315.6996 315.8401 315.9807 316.1212 316.2617 316.4022 316.5427 316.6832 316.8237 316.9642 317.1046 317.2451 317.3855 317.5259 317.6663 317.8067 317.9471 318.0875 318.2279 318.3682 318.5086 318.6489 318.7892 318.9295 319.0698 319.2101 319.3504 319.4907 319.6309 319.7712 319.9114 320.0516 320.1919 320.3321 320.4723 320.6124 320.7526 320.8928 321.0329 321.1730 321.3132 321.4533 321.5934 321.7335 321.8735 322.0136 322.1537 322.2937 322.4337 322.5738 322.7138 322.8538 322.9938 323.1337 323.2737 323.4137 323.5536 323.6935 323.8335 323.9734 324.1133 324.2532 324.3930 324.5329 324.6728 324.8126 324.9524
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20211117T150210.0Z 7991.626504 316 1 4.51 2 66.08 148.17 127.49 344.81 0.00 1 0.00 1 0 25 2.995e-02 9.134e-03 5.414e-02 1.161e-02 3.131587e-01 5.803008e-03 3.792276e-03 -6.000000e+00 1.699809e-02 223.18 -2.00 3.49 -2.00 317.95 0.00e+00 1.909905e-03 1.013327e-03 1.551646e-04 -6.000000e+00 7.535142e-04 279.10 -2.00 20.00 -2.00 317.29 0.00e+00 2.449 0.000 302.00 328.00 3 3.7832e+00 1.5370e-02 2.8468e-02 -6.0000e+00 4.1836e-02 5.8273e-02 1.7452e-02 1.6112e-02 -6.0000e+00 4.5596e-02 -8.4382e-03 1.1237e-02 7.9495e-03 -6.0000e+00 2.7193e-02 -7.1942e-03 5.8022e-03 2.7679e-03 -6.0000e+00 1.1619e-02 7.5522e-04 -5.7610e-04 3.4028e-04 2.9102e-05 -6.0000e+00 8.3530e-04 -9.3029e-03 -1.4173e-05 12 9 1 12 1 1 999.00 18.48 0.37 -0.00930 -0.01363 1 6 1 5 0 2165.130 21.79 15.00 18.48 20.79 12.7 973.97 -4188 4560 2406 -5519 -7783 9797 -13349 -1160 -15698 1814 -13371 1670 -2575 750 -3938 -3015 -4842 2625 -1994 1649 5447 -1173 463 -198 -416 -5930 3345 -3853 3029 -1648 1891 -2102 -834 -5772 -3636 -2472 -3744 162 -2569 -847 -996 541 1272 3473 1171 -251 -1219 1483 1038 1925 828 1828 332 -639 1804 773 456 2086 -210 432 2916 1960 2023 -252 584 -698 128 1365 164 713 -449 1014 -254 552 -1097 561 -2319 1446 -1780 -569 -1123 -2075 -2320 -1607 -760 -655 -460 778 457 1056 -67 938 1369 -158 -1134 -643 975 24 278 -1596 -932 -616 644 24 -1466 -790 -1043 203 654 812 -451 759 644 -28 227 -287 -297 -637 -48 125 -100 621 -536 523 605 89 1141 451 1268 585 585 603 515 327 243 -51 112 -539 -464 -359 -998 -757 -295 317 171 -388 -510 539 -1004 -86 -1472 147 -1265 160 -279 92 -583 -483 -830 439 -364 300 956 -220 89 -41 -89 -1376 690 -801 612 -364 443 -522 -220 -1568 -914 -638 -1108 55 -1064 -390 -458 255 611 1638 567 -123 -593 743 523 934 437 1023 200 -406 1145 506 301 1330 -135 280 1958 1453 1524 -201 441 -528 93 1006 128 617 -417 940 -231 468 -857 414 -1654 1013 -1439 -484 -1072 -2041 -2407 -1758 -885 -762 -554 935 537 1219 -71 968 1346 -165 -1238 -782 1228 33 382 -2117 -1128 -732 760 29 -1911 -1071 -1490 286 983 1233 -713 1158 975 -39 314 -393 -421 -918 -73 196 -155 928 -781 756 833 117 1487 632 1806 891 922 973 821 554 414 -89 200 -976 -819 -639 -1716 -1267
SS 20211117T150621.5Z 7991.629415 319 1 45.78 2 65.67 149.16 127.67 346.04 0.00 1 0.00 1 0 25 2.148e-02 6.083e-03 2.486e-02 3.733e-03 3.005894e-01 1.875472e-03 3.638626e-03 -6.000000e+00 1.219332e-02 223.18 -2.00 3.49 -2.00 318.86 0.00e+00 4.094573e-04 4.159303e-04 3.181037e-04 -6.000000e+00 5.404770e-04 279.10 -2.00 20.00 -2.00 318.20 0.00e+00 2.410 0.000 302.00 328.00 3 3.3881e+00 5.1134e-03 2.7849e-02 -6.0000e+00 3.0010e-02 -1.6608e-03 5.8748e-03 1.5494e-02 -6.0000e+00 3.2706e-02 1.7486e-02 4.0918e-03 7.6682e-03 -6.0000e+00 1.9506e-02 -1.2333e-02 2.1434e-03 2.2678e-03 -6.0000e+00 8.3348e-03 1.2176e-03 -3.4328e-04 1.1460e-04 2.7125e-05 -6.0000e+00 5.9906e-04 -9.1654e-03 2.8239e-05 10 0 0 10 0 0 99.99 18.47 0.44 -0.00917 -0.01174 383 118 1 5 0 119.520 21.79 15.00 18.47 21.21 12.7 977.47 893 -4856 -4181 -9230 -2248 -9847 -9115 -6042 -4321 -4536 -7280 -2702 -4217 1324 -3126 -204 -981 3662 -676 2424 -42 1282 -1265 2065 -963 241 -2167 -1991 -3362 805 288 756 1095 -2081 -3696 -3521 -1317 -2484 -707 -860 -1324 -625 -527 293 298 -55 196 -569 -1006 596 484 312 556 769 873 956 860 769 1289 1380 1536 1952 2069 1344 -302 -540 -444 193 626 99 503 455 481 579 422 317 -175 -932 -703 -1020 -1270 -1731 -2325 -1226 -718 -275 115 479 625 719 281 94 157 -105 -366 5 840 275 -103 -224 -787 -553 330 -414 -1272 -625 -455 178 555 281 62 229 343 -93 -70 51 -465 -269 -737 -531 -267 43 132 578 116 -117 1269 944 893 731 496 346 429 234 -73 -153 117 -358 -262 -44 -396 -641 40 -249 -213 -452 -94 -446 -449 -326 -252 -273 -453 -174 -320 110 -311 -21 -109 408 -82 295 -5 159 -169 285 -144 37 -328 -281 -509 121 48 136 211 -406 -694 -687 -286 -650 -217 -301 -453 -221 -190 116 118 -22 76 -219 -388 235 206 143 269 389 453 507 460 404 664 721 851 1174 1347 911 -199 -330 -261 116 420 74 400 368 377 427 282 192 -99 -544 -456 -753 -1050 -1560 -2219 -1230 -770 -312 135 565 718 771 278 85 136 -95 -365 6 1032 367 -138 -286 -928 -606 361 -492 -1626 -832 -635 260 864 467 105 381 536 -135 -95 68 -647 -398 -1171 -863 -429 67 198 821 158 -152 1625 1293 1321 1148 808 578 745 430 -142 -306 239 -740 -529 -86 -739 -1173
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