File name: Pandora187s1_PittsburghPA_20220103_L2Fit_fout2c2d20210902p1-8.txt
File generation date: 20251128T081058.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 187
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora187_OF_v4d20210517.txt
Instrument calibration file used: Pandora187s1_CF_v2d20210902.txt
Level 1 file used: Pandora187s1_PittsburghPA_20220103_L1_smca1c2d20210902p1-8.txt
Full location name: Pittsburgh, PA - Lawrenceville ACHD (USEPA AQS ID 42-003-0008)
Short location name: PittsburghPA
Country of location: United States
Location latitude [deg]: 40.4655
Location longitude [deg]: -79.9608
Location altitude [m]: 265
Local noon date: 20220103
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 194 335
Nominal wavelengths inside fitting window [nm]: 305.1270 305.2683 305.4097 305.5510 305.6924 305.8337 305.9750 306.1163 306.2576 306.3989 306.5402 306.6814 306.8227 306.9639 307.1051 307.2464 307.3876 307.5288 307.6699 307.8111 307.9523 308.0934 308.2346 308.3757 308.5168 308.6579 308.7990 308.9401 309.0812 309.2222 309.3633 309.5043 309.6454 309.7864 309.9274 310.0684 310.2094 310.3504 310.4914 310.6323 310.7733 310.9142 311.0551 311.1960 311.3369 311.4778 311.6187 311.7596 311.9004 312.0413 312.1821 312.3230 312.4638 312.6046 312.7454 312.8862 313.0269 313.1677 313.3084 313.4492 313.5899 313.7306 313.8713 314.0120 314.1527 314.2934 314.4341 314.5747 314.7154 314.8560 314.9966 315.1372 315.2778 315.4184 315.5590 315.6996 315.8401 315.9807 316.1212 316.2617 316.4022 316.5427 316.6832 316.8237 316.9642 317.1046 317.2451 317.3855 317.5259 317.6663 317.8067 317.9471 318.0875 318.2279 318.3682 318.5086 318.6489 318.7892 318.9295 319.0698 319.2101 319.3504 319.4907 319.6309 319.7712 319.9114 320.0516 320.1919 320.3321 320.4723 320.6124 320.7526 320.8928 321.0329 321.1730 321.3132 321.4533 321.5934 321.7335 321.8735 322.0136 322.1537 322.2937 322.4337 322.5738 322.7138 322.8538 322.9938 323.1337 323.2737 323.4137 323.5536 323.6935 323.8335 323.9734 324.1133 324.2532 324.3930 324.5329 324.6728 324.8126 324.9524
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20220103T145407.5Z 8038.620921 110 1 35.68 2 72.26 143.82 82.07 134.49 0.00 1 0.00 1 0 25 1.156e-01 8.123e-03 1.186e-01 5.614e-03 4.568678e-01 2.836515e-03 5.383346e-03 -6.000000e+00 6.558127e-02 223.33 -2.00 3.49 -2.00 319.69 0.00e+00 -3.728253e-04 8.209837e-04 4.382197e-04 -6.000000e+00 2.856835e-03 274.86 -2.00 20.00 -2.00 319.14 0.00e+00 3.238 0.001 302.00 328.00 3 3.7747e+00 7.9768e-03 3.8896e-02 -6.0000e+00 1.6169e-01 5.3909e-02 9.4921e-03 2.3299e-02 -6.0000e+00 1.7636e-01 3.5893e-04 8.0830e-03 1.1884e-02 -6.0000e+00 1.0490e-01 -1.0029e-02 4.2597e-03 3.5685e-03 -6.0000e+00 4.4632e-02 3.0014e-04 -1.5196e-03 1.6441e-04 4.1094e-05 -6.0000e+00 3.2231e-03 -1.0679e-02 -1.6319e-04 12 9 1 12 1 1 99.85 18.70 0.62 -0.01068 -0.02210 17 7 1 5 0 1971.890 21.98 15.00 18.70 0.88 13.0 867.58 32972 6763 49379 11008 -49549 -48868 -6523 -33331 1569 21441 -36014 57490 -36724 12658 -17700 8727 -8820 13263 -18124 7179 8228 -6293 -9262 2787 5893 -9394 2466 -4232 8209 4290 71 -3102 7271 1447 -6897 -3174 -460 -5029 -2386 -1644 -4005 -2558 1141 1556 3239 2896 -1245 -45 -2928 1450 717 -691 -1226 -161 1920 1068 1721 1393 3248 86 1715 2112 4106 755 1446 -1295 554 951 582 -706 274 -212 1101 574 -552 -183 -1531 433 -1436 242 -2328 -1017 -2441 -1775 -676 -20 1057 1271 717 1199 898 -798 553 -1467 -420 -611 914 410 -48 -574 -574 -987 447 234 -1277 -624 -1479 288 812 591 26 1130 45 389 -165 32 248 -340 -540 -809 -619 548 -81 69 26 -368 1136 255 1115 -90 492 196 608 145 -216 -446 247 -624 -20 -36 -43 -274 319 94 457 139 -1064 -1070 -104 -800 30 352 -1092 775 -1531 389 -872 371 -483 625 -1236 396 492 -442 -718 209 457 -883 203 -351 592 346 7 -347 806 170 -840 -389 -63 -869 -488 -385 -961 -635 281 384 857 773 -346 -12 -859 434 219 -233 -448 -62 750 434 703 560 1253 34 721 978 2059 414 768 -670 277 497 345 -475 194 -153 757 370 -324 -97 -852 228 -874 167 -1866 -884 -2280 -1625 -656 -20 1103 1335 737 1236 856 -721 482 -1385 -440 -675 1122 551 -65 -748 -683 -1083 479 269 -1588 -808 -2043 418 1190 941 44 1856 71 612 -246 47 376 -514 -863 -1315 -984 833 -127 104 37 -509 1561 384 1710 -150 859 354 1148 274 -431 -916 513 -1311 -40 -75 -85 -523
SS 20220103T150013.4Z 8038.625155 114 1 27.95 2 71.59 145.12 81.27 135.56 0.00 1 0.00 1 0 25 6.586e-02 5.737e-03 2.184e-02 1.626e-03 4.381856e-01 8.184039e-04 5.132385e-03 -6.000000e+00 3.740235e-02 223.33 -2.00 3.49 -2.00 319.49 0.00e+00 9.496041e-04 2.218331e-04 4.663404e-04 -6.000000e+00 1.628191e-03 274.86 -2.00 20.00 -2.00 318.93 0.00e+00 3.127 0.001 302.00 328.00 3 1.3722e+00 2.2844e-03 3.7457e-02 -6.0000e+00 9.2220e-02 2.9676e-02 2.6871e-03 2.2452e-02 -6.0000e+00 1.0056e-01 -1.8424e-02 2.1907e-03 1.1204e-02 -6.0000e+00 5.9812e-02 -7.7353e-04 1.1582e-03 3.4322e-03 -6.0000e+00 2.5465e-02 3.8408e-03 -6.2252e-04 4.7761e-05 3.8286e-05 -6.0000e+00 1.8360e-03 -1.2337e-02 1.5171e-05 12 1 1 12 1 1 99.98 18.67 0.27 -0.01234 -0.01702 170 86 1 5 0 162.410 21.98 14.98 18.67 1.04 13.0 868.93 -22620 -12035 -18921 -18881 -27694 -23982 -27612 -19185 -19531 -18840 -22618 -16244 -12332 -6273 -4565 -4453 -2640 -2436 -960 -1449 -161 -3931 634 -2081 -1248 -4994 -3257 -6452 -4819 -1729 -2254 523 -612 -2823 -5077 -3781 -3131 -1551 -1081 -434 -702 137 -447 357 572 -131 443 -138 -46 838 1292 936 1516 1120 1463 1425 1317 442 807 842 1661 1966 2523 1523 45 40 -395 217 302 497 518 560 515 766 21 46 -923 -1045 -917 -1142 -1082 -1922 -2134 -1363 -785 -236 569 499 795 733 601 -289 74 -433 -319 -202 626 367 -198 -214 -713 -346 283 -240 -1079 -474 -517 27 466 343 95 221 311 179 228 -89 -224 -289 -626 -513 -150 165 278 289 89 -304 859 709 596 661 260 318 239 196 -180 -126 88 -257 -279 53 -382 -423 -456 -241 -415 -384 -567 -529 -696 -505 -573 -577 -742 -564 -497 -287 -243 -266 -167 -165 -68 -107 -12 -302 49 -180 -114 -489 -309 -598 -432 -162 -241 61 -80 -374 -656 -502 -472 -276 -232 -106 -187 38 -128 102 165 -38 129 -41 -14 266 447 353 610 480 647 649 606 202 359 379 788 935 1318 849 25 21 -223 116 182 335 371 405 361 500 12 27 -526 -621 -561 -808 -864 -1699 -2002 -1349 -828 -240 596 528 817 769 582 -263 66 -407 -336 -221 765 489 -270 -276 -845 -376 331 -277 -1338 -614 -707 39 733 540 156 360 483 280 336 -131 -340 -465 -987 -821 -235 249 438 434 129 -422 1188 1065 908 1085 450 567 447 362 -351 -253 180 -528 -556 109 -747 -802
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