File name: Pandora53s1_Potchefstroom-METSI_20250618_L2Fit_fwvt1c2d20230223p1-8.txt
File generation date: 20250618T221909.9Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Stuart Piketh
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 53
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora53_OF_v5d20210210.txt
Instrument calibration file used: Pandora53s1_CF_v2d20230223.txt
Level 1 file used: Pandora53s1_Potchefstroom-METSI_20250618_L1_smca1c2d20230223p1-8.txt
Full location name: Gerhard Minnebron Mooi River Ecosystem Trails for Scientific Investigations
Short location name: Potchefstroom-METSI
Country of location: South Africa
Location latitude [deg]: -26.4907
Location longitude [deg]: 27.1322
Location altitude [m]: 1440
Local noon date: 20250618
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 103 "redoing cal analysis"
First and last pixel inside fitting window: 1684 1833
Nominal wavelengths inside fitting window [nm]: 492.0989 492.2196 492.3403 492.4609 492.5815 492.7021 492.8227 492.9432 493.0638 493.1843 493.3048 493.4253 493.5458 493.6663 493.7867 493.9072 494.0276 494.1480 494.2684 494.3888 494.5091 494.6294 494.7498 494.8701 494.9903 495.1106 495.2309 495.3511 495.4713 495.5915 495.7117 495.8319 495.9520 496.0722 496.1923 496.3124 496.4325 496.5525 496.6726 496.7926 496.9127 497.0327 497.1526 497.2726 497.3926 497.5125 497.6324 497.7523 497.8722 497.9921 498.1119 498.2318 498.3516 498.4714 498.5912 498.7109 498.8307 498.9504 499.0702 499.1899 499.3095 499.4292 499.5489 499.6685 499.7881 499.9077 500.0273 500.1469 500.2664 500.3859 500.5055 500.6250 500.7444 500.8639 500.9834 501.1028 501.2222 501.3416 501.4610 501.5803 501.6997 501.8190 501.9383 502.0576 502.1769 502.2962 502.4154 502.5346 502.6538 502.7730 502.8922 503.0114 503.1305 503.2496 503.3687 503.4878 503.6069 503.7260 503.8450 503.9640 504.0830 504.2020 504.3210 504.4399 504.5589 504.6778 504.7967 504.9156 505.0344 505.1533 505.2721 505.3909 505.5097 505.6285 505.7473 505.8660 505.9848 506.1035 506.2222 506.3408 506.4595 506.5781 506.6968 506.8154 506.9339 507.0525 507.1711 507.2896 507.4081 507.5266 507.6451 507.7636 507.8820 508.0005 508.1189 508.2373 508.3557 508.4740 508.5924 508.7107 508.8290 508.9473 509.0656 509.1838 509.3020 509.4203 509.5385 509.6567 509.7748 509.8930
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Azimuth motor temperature [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250618T050737.4Z 9300.213627 278 1 20.10 2 88.98 63.07 29.89 315.55 0.00 1 0.00 1 0 29 5.082e-03 5.030e-03 2.756e-04 2.748e-04 1.153606e+04 1.801721e+01 7.721532e+02 -6.000000e+00 2.727009e+02 279.53 -2.00 20.00 -2.00 505.38 0.00e+00 2.068366e-03 7.506169e-06 1.298147e-04 -6.000000e+00 1.403719e-04 279.53 -2.00 20.00 -2.00 500.95 0.00e+00 8.873872e-01 5.277982e-03 8.490009e-02 -6.000000e+00 1.002303e-01 224.97 -2.00 3.06 -2.00 502.46 0.00e+00 18.803 0.038 489.00 513.00 1 2.2031e+00 4.0217e-04 2.4533e-02 -6.0000e+00 7.6538e-03 -4.4139e-02 1.0352e-04 2.3823e-03 -6.0000e+00 2.0241e-03 2.0062e-02 4.0047e-04 2.4026e-05 1.1369e-04 -6.0000e+00 4.8055e-04 1.2602e-02 -3.1193e-04 12 9 9 12 1 1 52.86 15.55 2.57 0.01260 0.01538 121 57 1 4 0 164.650 19.04 14.98 15.55 5.21 29.60 18.6 748.51 -744 -548 -269 417 855 937 1068 927 901 773 357 180 -123 -376 -365 -245 -79 -10 220 401 274 382 343 321 463 513 336 12 -115 -479 -757 -523 -430 -391 55 273 135 -18 -151 -221 -194 11 203 353 367 259 127 92 -281 -492 -879 -1014 -934 -1061 -835 -292 93 290 421 407 351 471 402 391 371 238 136 -29 -237 -272 -528 -360 -164 -152 -175 -141 -245 -461 -612 -722 -840 -844 -715 -793 -728 -551 -627 -620 -591 -349 -9 198 344 575 577 421 179 -400 -802 -925 -1023 -737 -579 -523 -192 -185 -203 -186 -244 -284 -166 89 299 634 1053 1155 1122 977 763 528 329 382 386 255 459 444 388 474 419 133 144 54 -150 -198 -125 -314 -91 72 239 243 291 252 260 379 275 111 -174 -501 -662 -680 -658 -494 -247 389 806 889 1018 895 869 739 343 171 -115 -351 -345 -229 -75 -10 214 395 268 373 337 317 460 505 331 12 -111 -458 -724 -503 -417 -382 54 274 134 -18 -150 -219 -192 11 203 352 371 264 127 93 -280 -487 -861 -984 -897 -1014 -821 -292 93 291 424 409 355 478 411 396 378 240 135 -29 -235 -267 -521 -356 -162 -153 -175 -141 -244 -452 -602 -708 -815 -827 -706 -781 -727 -549 -626 -618 -587 -346 -9 200 347 580 579 416 174 -386 -760 -875 -965 -696 -560 -518 -196 -189 -208 -189 -245 -287 -171 91 310 661 1084 1196 1177 1028 808 556 345 393 398 260 472 460 405 488 432 137 149 56 -153 -201 -127 -323 -94 76 252 260 312 273 280 411 298 120 -187 -536 -705 -720
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SQ 20250618T051328.5Z 9300.217691 286 1 19.07 2 87.81 62.40 30.82 313.40 0.00 1 0.00 1 0 22 3.445e-03 3.422e-03 1.284e-04 1.282e-04 8.066191e+03 8.107049e+00 5.458142e+02 -6.000000e+00 1.848662e+02 279.53 -2.00 20.00 -2.00 505.34 0.00e+00 1.390039e-03 3.492083e-06 9.048466e-05 -6.000000e+00 9.515693e-05 279.53 -2.00 20.00 -2.00 500.80 0.00e+00 8.564507e-01 2.475378e-03 6.124837e-02 -6.000000e+00 6.794042e-02 224.97 -2.00 3.06 -2.00 502.34 0.00e+00 15.696 0.022 489.00 513.00 1 1.0198e+00 1.8873e-04 2.0010e-02 -6.0000e+00 5.1882e-03 -2.3837e-02 4.8887e-05 1.7767e-03 -6.0000e+00 1.3718e-03 9.6840e-02 -1.8338e-05 1.1497e-05 8.0479e-05 -6.0000e+00 3.2576e-04 1.0556e-02 -2.8964e-04 10 0 0 10 0 0 55.34 15.55 1.62 0.01056 0.01043 506 94 1 4 0 37.230 19.04 15.01 15.55 5.44 30.10 18.6 750.39 -382 -266 -183 330 581 611 699 602 569 523 257 131 -45 -173 -211 -126 10 -84 90 258 200 259 313 207 272 345 191 -98 -13 -244 -457 -257 -227 -381 -28 153 103 -2 -40 -103 -106 18 116 190 208 66 8 -26 -239 -372 -597 -692 -659 -786 -677 -317 17 138 239 294 245 261 258 274 240 182 175 51 -147 -133 -265 -176 -31 -96 -105 -71 -79 -190 -365 -412 -585 -670 -518 -597 -601 -523 -570 -556 -550 -298 2 123 227 361 310 221 84 -282 -577 -605 -609 -381 -321 -413 -215 -157 -130 -72 -107 -134 -31 99 234 428 689 803 744 631 495 344 236 368 320 158 280 278 220 338 313 93 130 99 -46 -62 -17 -79 -29 70 115 148 219 256 249 266 136 -41 -224 -380 -389 -437 -350 -245 -173 313 557 599 690 594 561 516 251 127 -43 -166 -201 -120 10 -82 89 258 201 260 311 207 274 349 193 -98 -13 -237 -444 -250 -223 -380 -29 156 104 -2 -40 -103 -106 18 117 192 212 67 8 -26 -239 -369 -584 -669 -630 -759 -663 -316 17 139 241 296 247 265 264 280 244 183 175 50 -146 -130 -258 -172 -31 -95 -105 -71 -78 -186 -354 -398 -567 -656 -504 -588 -593 -521 -571 -557 -549 -297 2 123 231 368 312 220 83 -274 -554 -571 -578 -362 -309 -407 -217 -159 -131 -73 -107 -134 -31 101 239 440 710 833 770 654 515 358 242 374 323 160 285 285 224 344 319 95 132 101 -46 -62 -17 -80 -29 72 119 155 229 270 265 281 145 -43 -238 -395 -401 -452
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