File name: Pandora53s1_Potchefstroom-METSI_20251205_L2Fit_fout2c2d20230223p1-8.txt
File generation date: 20251207T062513.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Stuart Piketh
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 53
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora53_OF_v5d20210210.txt
Instrument calibration file used: Pandora53s1_CF_v2d20230223.txt
Level 1 file used: Pandora53s1_Potchefstroom-METSI_20251205_L1_smca1c2d20230223p1-8.txt
Full location name: Gerhard Minnebron Mooi River Ecosystem Trails for Scientific Investigations
Short location name: Potchefstroom-METSI
Country of location: South Africa
Location latitude [deg]: -26.4907
Location longitude [deg]: 27.1322
Location altitude [m]: 1440
Local noon date: 20251205
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 103 "redoing cal analysis"
First and last pixel inside fitting window: 259 401
Nominal wavelengths inside fitting window [nm]: 305.0454 305.1861 305.3267 305.4673 305.6079 305.7485 305.8891 306.0297 306.1702 306.3108 306.4513 306.5919 306.7324 306.8729 307.0134 307.1539 307.2943 307.4348 307.5752 307.7157 307.8561 307.9965 308.1369 308.2773 308.4177 308.5581 308.6984 308.8388 308.9791 309.1194 309.2597 309.4000 309.5403 309.6806 309.8209 309.9611 310.1014 310.2416 310.3818 310.5220 310.6622 310.8024 310.9426 311.0827 311.2229 311.3630 311.5031 311.6433 311.7834 311.9234 312.0635 312.2036 312.3437 312.4837 312.6237 312.7638 312.9038 313.0438 313.1837 313.3237 313.4637 313.6036 313.7436 313.8835 314.0234 314.1633 314.3032 314.4431 314.5830 314.7228 314.8627 315.0025 315.1424 315.2822 315.4220 315.5618 315.7015 315.8413 315.9811 316.1208 316.2605 316.4002 316.5400 316.6797 316.8193 316.9590 317.0987 317.2383 317.3780 317.5176 317.6572 317.7968 317.9364 318.0760 318.2155 318.3551 318.4946 318.6342 318.7737 318.9132 319.0527 319.1922 319.3317 319.4711 319.6106 319.7500 319.8894 320.0288 320.1683 320.3076 320.4470 320.5864 320.7257 320.8651 321.0044 321.1437 321.2831 321.4224 321.5616 321.7009 321.8402 321.9794 322.1187 322.2579 322.3971 322.5363 322.6755 322.8147 322.9538 323.0930 323.2321 323.3713 323.5104 323.6495 323.7886 323.9277 324.0668 324.2058 324.3449 324.4839 324.6229 324.7620 324.9010
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Azimuth motor temperature [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SU 20251205T044905.3Z 9470.200756 246 1 51.19 2 70.22 105.85 110.13 292.17 0.00 1 0.00 1 0 25 1.559e-01 6.032e-02 1.768e-02 2.636e-03 3.646109e-01 1.378566e-03 4.082237e-03 -6.000000e+00 9.304053e-02 228.09 -2.00 3.06 -2.00 318.06 0.00e+00 -4.559408e-03 2.581780e-04 6.259900e-04 -6.000000e+00 4.121033e-03 282.83 -2.00 20.00 -2.00 317.33 0.00e+00 2.923 0.000 302.00 328.00 3 5.3759e+00 3.7126e-03 3.0189e-02 -6.0000e+00 2.3111e-01 2.4773e-02 4.2099e-03 1.8370e-02 -6.0000e+00 2.5028e-01 -2.6200e-02 2.7454e-03 8.4327e-03 -6.0000e+00 1.4911e-01 -2.8695e-03 1.4153e-03 3.8656e-03 -6.0000e+00 6.2798e-02 1.3354e-04 1.4840e-03 8.1067e-05 4.3328e-05 -6.0000e+00 4.7348e-03 2.1430e-02 0.0000e+00 12 9 8 11 8 0 93.31 17.83 0.49 0.02143 0.03258 13 2 1 5 0 3936.690 20.87 15.00 17.83 23.09 49.60 21.7 869.50 17442 23711 3558 52456 18163 32587 61010 48366 30048 25736 49713 17961 41414 29965 25413 1556 16037 17100 15781 18054 11797 14649 19971 14880 18209 16439 16614 13674 19262 13524 15333 12567 8708 8096 1934 7551 6422 -90906 9355 6496 9405 8053 7406 6757 4753 4985 4351 3576 3529 4556 3861 5249 5059 6850 3854 5845 4983 7079 6919 4945 4845 5201 3760 2946 2005 1190 1058 2081 3236 3420 1213 1181 1367 -27343 1694 147 835 627 1448 1524 1084 47 -385 20 222 948 951 612 -250 -59 -561 264 1202 853 2525 1569 1224 827 -231 -1516 -1723 -1842 -1067 592 215 -327 -730 -299 -172 528 282 -529 -466 -882 -299 -432 151 320 674 -131 -396 -536 -781 -626 105 -5 452 1630 1227 1293 1035 309 93 236 -148 299 130 183 -254 -657 -469 -457 37 850 1179 220 1933 876 1357 2150 2164 1776 1703 2749 1415 2898 2696 2656 222 2106 2338 2288 2654 1888 2319 3154 2623 3356 3229 3239 2599 3349 2480 2945 2652 2019 1940 479 1782 1689 -59816 3258 2609 4061 3646 3467 3198 2281 2368 2050 1676 1655 2176 1942 2758 2855 3961 2359 3633 3196 4440 4266 3080 3098 3479 2720 2244 1524 883 762 1483 2403 2741 1050 1068 1233 -29100 1403 114 611 446 1076 1227 957 45 -387 21 240 1068 1111 727 -299 -69 -633 281 1204 860 2612 1733 1451 1057 -307 -2032 -2218 -2258 -1267 703 266 -425 -973 -412 -245 781 439 -829 -724 -1333 -430 -604 209 451 992 -200 -609 -815 -1173 -915 148 -7 613 2204 1730 1916 1596 488 149 392 -254 526 234 331 -464 -1190 -824 -790 62
SU 20251205T045150.5Z 9470.202668 249 1 50.35 2 69.62 105.60 110.67 291.96 0.00 1 0.00 1 0 25 1.258e-01 5.465e-02 1.467e-02 2.509e-03 3.567019e-01 1.312205e-03 3.936206e-03 -6.000000e+00 7.516833e-02 228.09 -2.00 3.06 -2.00 317.92 0.00e+00 -3.615776e-03 2.356388e-04 4.718098e-04 -6.000000e+00 3.327054e-03 282.83 -2.00 20.00 -2.00 317.20 0.00e+00 2.843 0.000 302.00 328.00 3 5.3520e+00 3.5178e-03 2.9251e-02 -6.0000e+00 1.8672e-01 2.3166e-02 3.9798e-03 1.7214e-02 -6.0000e+00 2.0216e-01 -1.6622e-02 2.5540e-03 8.1532e-03 -6.0000e+00 1.2044e-01 -7.8250e-03 1.3086e-03 3.0167e-03 -6.0000e+00 5.0772e-02 1.4692e-04 2.0822e-03 7.7244e-05 3.6467e-05 -6.0000e+00 3.8217e-03 1.5718e-02 0.0000e+00 12 8 8 10 0 0 61.56 17.85 0.39 0.01572 0.03136 13 2 1 5 0 3872.430 20.87 15.00 17.85 23.18 48.10 21.6 870.30 20694 1267 13405 36060 14919 17720 51079 39764 17741 23101 27441 17846 29525 25747 17576 2369 14065 8657 11112 8598 9213 9567 17246 11313 13318 13639 13659 10047 14000 13880 11205 15753 6760 5917 1558 3722 5431 -84964 7783 5658 7569 6848 5141 5916 4279 4705 1855 1636 2227 4001 3614 4152 4688 5048 4338 4754 4518 5582 5155 3891 3744 5004 3319 2879 1244 1412 585 1262 2365 3205 1142 946 1269 -25075 1487 702 1130 905 1631 2089 939 707 -525 -595 -148 915 570 348 -135 16 -16 251 549 535 2638 1616 833 1355 -204 -939 -1451 -1785 -714 318 -146 -317 -693 -569 133 441 118 -276 -540 -725 -624 -126 16 553 103 -48 -419 -516 -598 -492 404 -221 294 1351 1073 1279 674 166 195 355 -277 499 49 -323 -81 -210 -432 -357 21 1049 83 811 1692 783 922 2074 2066 1259 1662 1954 1452 2465 2505 2065 349 2012 1344 1762 1451 1580 1661 2907 2187 2655 2834 2823 2090 2651 2625 2323 3416 1696 1538 402 967 1491 -54557 2836 2359 3355 3230 2487 2858 2092 2321 910 810 1096 1987 1882 2277 2687 3062 2720 3014 2933 3581 3323 2519 2447 3394 2442 2223 982 1058 428 914 1785 2638 1013 865 1156 -26407 1245 555 845 656 1215 1680 834 676 -531 -629 -162 1039 674 418 -163 18 -18 269 557 542 2730 1787 994 1729 -272 -1258 -1873 -2196 -847 379 -181 -407 -928 -779 189 655 182 -432 -841 -1083 -900 -176 22 776 150 -73 -644 -785 -898 -719 572 -306 394 1803 1511 1866 1027 262 312 579 -470 864 86 -580 -146 -374 -759 -609 35
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