File name: Pandora53s1_Potchefstroom-METSI_20251210_L2Fit_fout2c2d20230223p1-8.txt
File generation date: 20251210T221458.0Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c2p1-8
Local principal investigator: Stuart Piketh
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 53
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora53_OF_v5d20210210.txt
Instrument calibration file used: Pandora53s1_CF_v2d20230223.txt
Level 1 file used: Pandora53s1_Potchefstroom-METSI_20251210_L1_smca1c2d20230223p1-8.txt
Full location name: Gerhard Minnebron Mooi River Ecosystem Trails for Scientific Investigations
Short location name: Potchefstroom-METSI
Country of location: South Africa
Location latitude [deg]: -26.4907
Location longitude [deg]: 27.1322
Location altitude [m]: 1440
Local noon date: 20251210
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 103 "redoing cal analysis"
First and last pixel inside fitting window: 259 401
Nominal wavelengths inside fitting window [nm]: 305.0454 305.1861 305.3267 305.4673 305.6079 305.7485 305.8891 306.0297 306.1702 306.3108 306.4513 306.5919 306.7324 306.8729 307.0134 307.1539 307.2943 307.4348 307.5752 307.7157 307.8561 307.9965 308.1369 308.2773 308.4177 308.5581 308.6984 308.8388 308.9791 309.1194 309.2597 309.4000 309.5403 309.6806 309.8209 309.9611 310.1014 310.2416 310.3818 310.5220 310.6622 310.8024 310.9426 311.0827 311.2229 311.3630 311.5031 311.6433 311.7834 311.9234 312.0635 312.2036 312.3437 312.4837 312.6237 312.7638 312.9038 313.0438 313.1837 313.3237 313.4637 313.6036 313.7436 313.8835 314.0234 314.1633 314.3032 314.4431 314.5830 314.7228 314.8627 315.0025 315.1424 315.2822 315.4220 315.5618 315.7015 315.8413 315.9811 316.1208 316.2605 316.4002 316.5400 316.6797 316.8193 316.9590 317.0987 317.2383 317.3780 317.5176 317.6572 317.7968 317.9364 318.0760 318.2155 318.3551 318.4946 318.6342 318.7737 318.9132 319.0527 319.1922 319.3317 319.4711 319.6106 319.7500 319.8894 320.0288 320.1683 320.3076 320.4470 320.5864 320.7257 320.8651 321.0044 321.1437 321.2831 321.4224 321.5616 321.7009 321.8402 321.9794 322.1187 322.2579 322.3971 322.5363 322.6755 322.8147 322.9538 323.0930 323.2321 323.3713 323.5104 323.6495 323.7886 323.9277 324.0668 324.2058 324.3449 324.4839 324.6229 324.7620 324.9010
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Azimuth motor temperature [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SU 20251210T044504.6Z 9475.197969 284 1 50.12 2 71.35 106.93 47.91 323.89 0.00 1 0.00 1 0 25 1.378e-01 5.472e-02 1.651e-02 2.496e-03 3.733429e-01 1.304091e-03 4.103429e-03 -6.000000e+00 8.230528e-02 228.01 -2.00 3.06 -2.00 318.03 0.00e+00 -3.880695e-03 2.431144e-04 4.903770e-04 -6.000000e+00 3.646528e-03 283.05 -2.00 20.00 -2.00 317.30 0.00e+00 3.089 0.000 302.00 328.00 3 5.1082e+00 3.5053e-03 3.1373e-02 -6.0000e+00 2.0440e-01 4.5233e-02 3.9737e-03 1.8055e-02 -6.0000e+00 2.2128e-01 -1.9910e-02 2.5917e-03 8.5281e-03 -6.0000e+00 1.3186e-01 -3.7523e-03 1.3384e-03 3.2524e-03 -6.0000e+00 5.5621e-02 1.4841e-04 1.9468e-03 7.6277e-05 3.8449e-05 -6.0000e+00 4.1847e-03 1.4184e-02 0.0000e+00 12 8 8 10 0 0 -99.42 17.97 0.45 0.01418 0.02881 13 2 1 5 0 3854.160 20.96 15.01 17.97 29.21 58.10 22.1 910.09 16018 11835 5812 37862 18147 16363 64874 33964 24928 24497 47928 15965 32166 26504 20857 547 14116 14738 11231 15257 10929 10677 15249 9724 12571 14069 17218 13254 14343 13163 13059 12791 8401 6238 2928 5586 6863 -87189 8877 5797 7424 7239 5388 6684 4483 4575 3138 2372 1868 4222 3585 4385 4702 5336 4675 4303 5112 5841 5563 3439 4431 4189 3004 3243 2363 1524 1230 926 2415 3351 860 1600 695 -25444 1242 327 864 903 1715 1177 1261 -164 -559 -440 555 318 369 200 -324 456 74 10 966 954 2955 1274 1396 996 -188 -1164 -1501 -1608 -697 102 -377 -566 -331 -339 -16 509 120 -693 -284 -698 -294 -262 233 100 288 -192 -688 -418 -514 -172 253 74 602 1319 1329 1119 492 302 291 220 -12 362 -33 -54 -1 -302 -610 -553 -66 753 634 338 1557 845 771 2107 1677 1480 1568 2581 1231 2380 2335 2224 77 1858 2034 1684 2281 1705 1699 2491 1777 2410 2784 3291 2503 2539 2355 2503 2700 1965 1536 725 1355 1766 -54459 3049 2354 3220 3261 2545 3138 2141 2171 1492 1123 891 2024 1809 2329 2672 3145 2852 2728 3288 3726 3494 2185 2859 2845 2166 2444 1814 1144 882 666 1833 2726 759 1442 631 -26659 1032 257 631 649 1268 950 1112 -158 -565 -464 601 363 430 240 -392 535 83 11 976 966 3062 1421 1667 1268 -251 -1559 -1960 -1996 -834 121 -472 -733 -443 -465 -23 752 185 -1092 -442 -1059 -424 -367 322 142 420 -293 -1061 -636 -770 -253 358 103 812 1779 1864 1657 754 477 469 362 -20 631 -58 -97 -2 -540 -1075 -947 -110
SU 20251210T044753.5Z 9475.199925 287 1 50.63 2 70.75 106.68 48.27 323.13 0.00 1 0.00 1 0 25 3.774e-02 7.020e-03 1.315e-02 2.363e-03 3.674543e-01 1.234227e-03 3.819917e-03 -6.000000e+00 2.254299e-02 228.01 -2.00 3.06 -2.00 317.97 0.00e+00 -1.824202e-04 2.203826e-04 1.713758e-04 -6.000000e+00 9.987672e-04 283.05 -2.00 20.00 -2.00 317.25 0.00e+00 2.998 0.000 302.00 328.00 3 5.0842e+00 3.3058e-03 3.0222e-02 -6.0000e+00 5.5983e-02 3.4162e-02 3.7398e-03 1.6613e-02 -6.0000e+00 6.0608e-02 1.1111e-02 2.4060e-03 8.1284e-03 -6.0000e+00 3.6115e-02 -1.4494e-02 1.2332e-03 2.2762e-03 -6.0000e+00 1.5234e-02 1.6205e-04 2.7511e-04 7.2529e-05 2.8168e-05 -6.0000e+00 1.1462e-03 1.4197e-02 0.0000e+00 11 9 0 11 32 0 -104.33 17.98 0.45 0.01420 0.01626 14 3 1 5 0 3616.100 20.96 14.98 17.98 29.53 57.40 22.1 912.36 -7917 -16134 -6375 -11071 -817 8082 20533 17454 -4707 2892 6976 -4616 13815 2576 5137 -12314 1800 2916 1959 1953 1326 1754 2334 495 -2224 1022 561 1603 1500 2585 2862 4546 1891 -520 -3253 -1763 -2025 -2117 -735 -2988 -2319 -1448 -2270 -1286 -1563 352 -325 -1107 -993 464 -519 159 601 1400 1341 512 649 1965 2105 1433 639 1699 -131 1390 529 730 326 -417 1510 1011 -627 -297 -984 -320 685 -684 -23 167 -506 -1396 -502 -688 -1270 -1680 -780 -252 -269 -201 -157 108 638 1008 1030 369 1552 942 418 1004 -2 34 -435 -760 -85 -213 -405 -798 -709 -972 -414 124 31 -364 -93 -65 -70 212 459 187 -45 -165 -278 -285 -472 402 779 408 410 593 870 738 566 446 -2 193 -585 122 46 -329 -133 -168 -283 -282 -113 -445 -1068 -396 -693 -44 399 953 939 -344 209 501 -388 1105 271 597 -1869 256 435 311 323 226 301 413 95 -457 213 118 319 294 504 586 1013 462 -135 -847 -451 -565 -675 -265 -1264 -1061 -684 -1120 -638 -781 173 -160 -544 -488 231 -272 88 348 854 839 333 422 1286 1354 922 418 1180 -97 1075 419 552 240 -306 1156 826 -552 -270 -901 -285 580 -550 -17 122 -383 -1156 -452 -659 -1282 -1778 -860 -286 -318 -242 -189 128 720 1075 1054 372 1606 1053 504 1284 -3 45 -565 -940 -101 -255 -502 -1040 -945 -1333 -591 184 48 -569 -144 -98 -101 294 634 264 -66 -249 -425 -435 -712 586 1105 562 549 794 1219 1078 863 703 -4 316 -997 213 81 -593 -240 -302 -493 -482 -190
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