File name: Pandora55s1_QueensNY_20190911_L2Fit_fout2c9d20190910p1-8.txt File generation date: 20260625T144655.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: James Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v1d20190723.txt Instrument calibration file used: Pandora55s1_CF_v9d20190910.txt Level 1 file used: Pandora55s1_QueensNY_20190911_L1_smca1c9d20190910p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20190911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1248 305.2648 305.4048 305.5448 305.6848 305.8248 305.9647 306.1047 306.2446 306.3846 306.5245 306.6644 306.8043 306.9442 307.0841 307.2240 307.3639 307.5037 307.6436 307.7834 307.9232 308.0630 308.2028 308.3426 308.4824 308.6222 308.7619 308.9017 309.0414 309.1812 309.3209 309.4606 309.6003 309.7400 309.8797 310.0193 310.1590 310.2986 310.4383 310.5779 310.7175 310.8571 310.9967 311.1363 311.2759 311.4155 311.5550 311.6945 311.8341 311.9736 312.1131 312.2526 312.3921 312.5316 312.6711 312.8105 312.9500 313.0894 313.2288 313.3682 313.5077 313.6471 313.7864 313.9258 314.0652 314.2045 314.3439 314.4832 314.6225 314.7618 314.9011 315.0404 315.1797 315.3190 315.4582 315.5975 315.7367 315.8760 316.0152 316.1544 316.2936 316.4328 316.5719 316.7111 316.8502 316.9894 317.1285 317.2676 317.4067 317.5458 317.6849 317.8240 317.9631 318.1021 318.2412 318.3802 318.5192 318.6583 318.7973 318.9362 319.0752 319.2142 319.3532 319.4921 319.6311 319.7700 319.9089 320.0478 320.1867 320.3256 320.4645 320.6033 320.7422 320.8810 321.0198 321.1587 321.2975 321.4363 321.5751 321.7138 321.8526 321.9914 322.1301 322.2688 322.4076 322.5463 322.6850 322.8237 322.9624 323.1010 323.2397 323.3783 323.5170 323.6556 323.7942 323.9328 324.0714 324.2100 324.3486 324.4871 324.6257 324.7642 324.9027 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20190911T150814.2Z 7193.630720 11 1 30.35 2 43.07 140.31 156.95 358.77 0.00 1 0.00 1 0 25 9.663e-03 7.556e-03 3.052e-04 2.028e-04 1.712872e-01 1.082402e-04 2.115299e-03 -6.000000e+00 5.792883e-03 229.58 -2.00 3.51 -2.00 315.12 0.00e+00 -7.793249e-06 9.713440e-06 3.850049e-05 -6.000000e+00 2.605862e-04 288.28 -2.00 20.00 -2.00 314.44 0.00e+00 1.367 0.000 302.00 328.00 3 8.0292e-01 2.7849e-04 1.6320e-02 -6.0000e+00 1.4415e-02 -5.2651e-03 3.0827e-04 8.9387e-03 -6.0000e+00 1.5571e-02 1.5516e-04 1.7621e-04 4.3643e-03 -6.0000e+00 9.2951e-03 -1.8292e-03 7.7843e-05 1.2120e-03 -6.0000e+00 3.9509e-03 5.2139e-02 7.9207e-05 6.2619e-06 1.8156e-05 -6.0000e+00 2.9030e-04 2.4398e-03 7.2889e-05 11 8 0 10 0 0 99.96 22.91 0.24 0.00244 0.00303 995 995 1 5 0 29.920 25.79 19.99 22.91 33.42 20.5 1056.10 -1889 -2930 -3344 -1875 406 1393 1409 1047 -420 -380 1230 1640 943 606 -460 -623 -74 303 515 -48 625 1382 1228 616 296 -629 -820 228 1717 1827 1612 1851 -666 -1133 371 908 595 589 -673 -1638 -1423 -1301 -1326 -1080 -832 -1214 -976 -799 284 824 680 659 749 458 475 808 303 476 785 1452 1362 1091 589 -792 -612 65 638 1630 1516 233 -329 -741 -517 -786 -319 205 726 1716 989 231 -659 -1417 -1444 -901 -917 -765 -588 -512 -735 -429 100 219 1213 1768 1586 893 857 -202 -794 -624 -531 -40 1000 659 -750 -406 -777 -316 -155 -113 -373 -497 -287 -200 416 948 1009 862 199 -539 -621 -411 -288 58 382 480 1326 1428 699 470 -5 101 150 420 -118 -284 18 -331 -471 -363 -246 -379 65 -609 -991 -1102 -557 117 390 425 325 -142 -130 411 565 358 258 -201 -287 -35 146 253 -24 317 694 630 332 156 -339 -429 118 827 859 785 953 -367 -621 192 467 315 365 -465 -1215 -1134 -1016 -1054 -859 -657 -950 -783 -617 211 609 523 536 603 383 406 702 267 416 677 1247 1211 982 568 -803 -607 60 561 1382 1364 223 -326 -768 -535 -788 -314 191 612 1433 855 209 -631 -1492 -1537 -1005 -1038 -925 -716 -643 -925 -521 118 247 1299 1802 1670 974 978 -242 -1011 -789 -635 -46 1156 746 -921 -504 -1015 -409 -209 -154 -529 -711 -395 -268 531 1181 1232 1088 257 -718 -862 -571 -391 80 495 618 1610 1703 870 593 -7 137 207 568 -168 -410 27 -507 -702 -558 -368 -549 96 SU 20190911T150959.1Z 7193.631934 13 1 30.20 2 42.86 140.88 156.95 359.78 0.00 1 0.00 1 0 25 9.690e-03 7.597e-03 2.789e-04 1.878e-04 1.711850e-01 1.004249e-04 2.122908e-03 -6.000000e+00 5.808344e-03 229.58 -2.00 3.51 -2.00 315.06 0.00e+00 -2.966708e-05 8.884261e-06 3.570373e-05 -6.000000e+00 2.613189e-04 288.28 -2.00 20.00 -2.00 314.38 0.00e+00 1.363 0.000 302.00 328.00 3 6.6773e-01 2.5801e-04 1.6290e-02 -6.0000e+00 1.4453e-02 -5.2869e-03 2.8553e-04 8.9521e-03 -6.0000e+00 1.5613e-02 -6.1996e-04 1.6351e-04 4.3759e-03 -6.0000e+00 9.3203e-03 -1.4365e-03 7.2020e-05 1.2159e-03 -6.0000e+00 3.9611e-03 5.9987e-02 -8.6528e-05 5.7849e-06 1.8197e-05 -6.0000e+00 2.9115e-04 2.7105e-03 4.3990e-05 11 8 0 10 0 0 96.76 22.91 0.24 0.00271 0.00206 1054 1054 1 5 0 28.240 25.79 19.99 22.91 33.51 20.4 1056.76 -1881 -2927 -3483 -1739 391 1400 1351 1210 -452 -310 1277 1677 960 575 -377 -709 31 222 533 -145 562 1362 1243 617 345 -559 -858 284 1633 1855 1600 1865 -670 -1129 405 888 641 525 -650 -1604 -1395 -1338 -1320 -1079 -775 -1207 -933 -790 253 843 650 642 721 464 453 830 285 455 807 1453 1316 1082 545 -787 -622 23 709 1653 1550 267 -378 -773 -564 -802 -323 233 723 1696 973 242 -692 -1374 -1445 -894 -922 -756 -586 -541 -751 -466 108 203 1217 1780 1593 923 859 -201 -766 -593 -546 -19 996 649 -762 -405 -793 -301 -148 -105 -377 -512 -288 -180 464 955 1048 854 186 -552 -641 -383 -289 108 391 497 1323 1447 660 494 -8 120 142 428 -120 -284 21 -348 -502 -382 -248 -364 67 -624 -1018 -1182 -531 116 403 419 385 -157 -109 438 593 375 233 -169 -336 15 110 269 -71 292 702 610 319 186 -309 -461 141 808 894 800 986 -354 -592 214 469 348 313 -461 -1220 -1076 -1071 -1076 -879 -627 -968 -724 -626 193 639 513 505 595 398 397 739 244 408 713 1279 1137 997 512 -777 -601 22 639 1436 1354 261 -384 -820 -598 -824 -326 212 624 1451 814 224 -679 -1407 -1575 -972 -1070 -894 -700 -666 -927 -579 125 223 1268 1766 1632 1031 1004 -247 -955 -735 -669 -22 1123 753 -915 -516 -1016 -399 -196 -147 -526 -720 -406 -247 581 1162 1250 1055 236 -753 -874 -523 -403 144 497 626 1646 1767 803 638 -10 159 192 593 -168 -420 30 -524 -766 -578 -365 -542 97 SU 20190911T151144.5Z 7193.633154 15 1 30.95 2 42.65 141.44 156.95 0.81 0.00 1 0.00 1 0 25 9.679e-03 7.625e-03 2.719e-04 1.834e-04 1.706150e-01 9.790811e-05 2.118008e-03 -6.000000e+00 5.801411e-03 229.58 -2.00 3.51 -2.00 315.06 0.00e+00 -2.240506e-05 8.654757e-06 3.604333e-05 -6.000000e+00 2.610238e-04 288.28 -2.00 20.00 -2.00 314.37 0.00e+00 1.358 0.000 302.00 328.00 3 6.2690e-01 2.5153e-04 1.6238e-02 -6.0000e+00 1.4436e-02 -6.2275e-03 2.7844e-04 8.9261e-03 -6.0000e+00 1.5594e-02 -1.5351e-04 1.5946e-04 4.3637e-03 -6.0000e+00 9.3093e-03 -1.5698e-03 7.0253e-05 1.2127e-03 -6.0000e+00 3.9562e-03 6.2847e-02 -1.5963e-04 5.6372e-06 1.8191e-05 -6.0000e+00 2.9083e-04 2.7598e-03 2.7271e-05 11 8 0 10 0 0 78.38 22.91 0.24 0.00276 0.00156 1108 1108 1 5 0 26.860 25.79 19.99 22.91 33.64 20.4 1057.23 -1831 -2927 -3397 -1833 350 1315 1449 1161 -481 -318 1255 1688 1009 575 -367 -653 -39 302 478 -75 629 1332 1210 603 356 -582 -890 301 1670 1799 1652 1871 -694 -1163 302 904 628 555 -699 -1554 -1427 -1291 -1300 -1093 -803 -1189 -927 -837 242 823 666 640 726 417 446 838 230 489 774 1434 1310 1127 530 -772 -620 63 643 1655 1498 243 -310 -771 -568 -849 -369 213 745 1744 1006 246 -679 -1425 -1463 -887 -943 -734 -617 -515 -756 -473 128 210 1221 1765 1570 920 879 -208 -772 -607 -518 -19 994 649 -755 -422 -831 -333 -164 -105 -372 -510 -306 -191 463 950 1025 850 175 -552 -636 -387 -284 74 407 493 1359 1412 689 487 -17 127 137 446 -112 -292 3 -355 -499 -393 -244 -358 80 -608 -1019 -1152 -560 104 379 449 370 -167 -112 431 598 394 233 -165 -309 -19 149 241 -36 327 687 595 312 193 -322 -478 161 825 868 826 988 -366 -610 160 477 341 331 -496 -1181 -1101 -1032 -1059 -891 -649 -952 -719 -662 184 623 525 503 599 358 391 745 197 438 683 1261 1130 1037 497 -761 -597 59 579 1435 1379 238 -314 -817 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