File name: Pandora55s1_QueensNY_20191003_L2Fit_fout2c9d20190910p1-8.txt File generation date: 20260625T144611.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: James Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v1d20190723.txt Instrument calibration file used: Pandora55s1_CF_v9d20190910.txt Level 1 file used: Pandora55s1_QueensNY_20191003_L1_smca1c9d20190910p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20191003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1248 305.2648 305.4048 305.5448 305.6848 305.8248 305.9647 306.1047 306.2446 306.3846 306.5245 306.6644 306.8043 306.9442 307.0841 307.2240 307.3639 307.5037 307.6436 307.7834 307.9232 308.0630 308.2028 308.3426 308.4824 308.6222 308.7619 308.9017 309.0414 309.1812 309.3209 309.4606 309.6003 309.7400 309.8797 310.0193 310.1590 310.2986 310.4383 310.5779 310.7175 310.8571 310.9967 311.1363 311.2759 311.4155 311.5550 311.6945 311.8341 311.9736 312.1131 312.2526 312.3921 312.5316 312.6711 312.8105 312.9500 313.0894 313.2288 313.3682 313.5077 313.6471 313.7864 313.9258 314.0652 314.2045 314.3439 314.4832 314.6225 314.7618 314.9011 315.0404 315.1797 315.3190 315.4582 315.5975 315.7367 315.8760 316.0152 316.1544 316.2936 316.4328 316.5719 316.7111 316.8502 316.9894 317.1285 317.2676 317.4067 317.5458 317.6849 317.8240 317.9631 318.1021 318.2412 318.3802 318.5192 318.6583 318.7973 318.9362 319.0752 319.2142 319.3532 319.4921 319.6311 319.7700 319.9089 320.0478 320.1867 320.3256 320.4645 320.6033 320.7422 320.8810 321.0198 321.1587 321.2975 321.4363 321.5751 321.7138 321.8526 321.9914 322.1301 322.2688 322.4076 322.5463 322.6850 322.8237 322.9624 323.1010 323.2397 323.3783 323.5170 323.6556 323.7942 323.9328 324.0714 324.2100 324.3486 324.4871 324.6257 324.7642 324.9027 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191003T161234.6Z 7215.675400 13506 1 29.17 2 45.35 168.82 92.66 115.80 0.00 1 0.00 1 0 17 4.843e-02 1.973e-02 4.245e-02 1.962e-02 1.792290e-01 1.021664e-02 2.307121e-03 -6.000000e+00 2.877590e-02 227.27 -2.00 3.51 -2.00 316.53 0.00e+00 6.842261e-04 1.235270e-03 2.366915e-04 -6.000000e+00 1.292246e-03 285.78 -2.00 20.00 -2.00 315.78 0.00e+00 1.421 0.000 302.00 328.00 3 7.9064e+00 2.6618e-02 1.7018e-02 -6.0000e+00 7.1275e-02 6.4570e-02 2.9734e-02 9.4513e-03 -6.0000e+00 7.7157e-02 4.5975e-03 1.7178e-02 4.6522e-03 -6.0000e+00 4.6076e-02 4.2988e-03 8.0329e-03 1.3108e-03 -6.0000e+00 1.9629e-02 3.8696e-05 -4.5496e-04 6.1394e-04 1.8653e-05 -6.0000e+00 1.4541e-03 -3.1690e-04 -8.5908e-05 12 8 8 10 0 0 51.30 22.91 2.18 -0.00032 -0.00374 14 14 1 5 0 2083.100 25.79 20.02 22.91 17.23 20.0 968.37 11914 -5770 -4162 9842 11535 -5847 -23893 16544 -5688 28318 4539 13886 6907 1818 1913 -4836 304 3558 -4373 2225 1735 -5866 3992 -5095 5485 2610 -1870 2841 -3097 1935 -5986 7357 -4661 13 -1031 -5861 -6997 -3051 -776 34 1328 -4229 3233 -2110 2151 168 3317 -1750 -511 2667 -2136 707 -381 4476 -1870 -438 -2880 -2397 349 251 432 4583 851 1786 1774 -1574 2320 -1195 2479 -1725 1046 -496 3005 -1223 523 -4082 -351 -2700 -2772 2197 -4956 2307 -1608 777 701 3271 2948 1574 912 796 -1695 -3335 -1606 1482 -1373 -3208 206 -62 -361 3833 -2276 925 -1243 -1566 -3799 823 -759 -259 -647 699 1704 1165 848 893 -442 -2454 1300 -2196 1015 -1560 -299 -1036 665 3086 -840 1446 -1109 1347 -1563 679 1005 323 -569 -144 223 -229 712 -451 1753 -1655 -14 -296 -146 2162 -1281 -886 1704 1809 -1059 -5457 2866 -1286 4734 938 2739 1594 490 563 -1594 98 1140 -1549 758 600 -2171 1373 -1982 2006 994 -721 990 -1079 634 -2183 2515 -1858 5 -378 -2257 -2973 -1444 -418 20 844 -2927 2132 -1466 1432 113 2104 -1127 -318 1613 -1403 476 -271 3155 -1429 -338 -2286 -1888 264 191 338 3668 751 1621 1585 -1345 1779 -923 1953 -1555 988 -493 2894 -1191 472 -3506 -265 -1983 -2093 1734 -4597 2170 -1658 823 787 3823 3635 2028 1182 1003 -2049 -3742 -1635 1405 -1380 -3525 240 -79 -482 4905 -2927 1078 -1422 -1836 -4819 1064 -1034 -365 -951 1064 2673 1852 1312 1292 -600 -3183 1598 -2867 1364 -2286 -447 -1565 973 4262 -1147 1848 -1387 1620 -1983 891 1371 454 -818 -212 341 -368 1173 -764 2948 -2838 -23 -474 -229 SU 20191003T202322.4Z 7215.849565 22310 1 30.79 2 67.08 242.20 63.67 165.94 0.00 1 0.00 1 0 17 3.440e-01 5.927e-02 2.620e-01 4.668e-02 2.719129e-01 2.436192e-02 3.548767e-03 -6.000000e+00 2.051027e-01 227.25 -2.00 3.51 -2.00 318.00 0.00e+00 -3.668955e-03 4.351198e-03 1.210067e-03 -6.000000e+00 9.197497e-03 285.76 -2.00 20.00 -2.00 317.23 0.00e+00 2.547 0.000 302.00 328.00 3 7.8025e+00 6.4545e-02 2.9475e-02 -6.0000e+00 5.0844e-01 1.1840e-01 7.3257e-02 1.7543e-02 -6.0000e+00 5.5059e-01 -2.1058e-02 4.6021e-02 6.9084e-03 -6.0000e+00 3.2823e-01 4.1136e-02 2.3053e-02 4.5643e-03 -6.0000e+00 1.4006e-01 1.1892e-05 -1.6091e-03 1.4757e-03 4.7525e-05 -6.0000e+00 1.0322e-02 -9.1307e-03 2.3421e-04 12 8 8 10 0 0 55.34 22.92 7.70 -0.00913 -0.02122 8 8 1 5 0 3847.050 25.79 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-8164 1025 -5657 1409 -72 5567 361 -173 6167 7581 3307 -9693 11556 -8951 -2045 -3853 -382 1167 1800 -5844 -4610 2098 2579 5956 2495 3039 487 1655 5623 3025 7079 157 4245 -4607 12543 -6466 5651 3046 3751 -3472 4505 -5783 2692 2095 -6708 -2277 -11217 -1778 -1298 -5676 -3062 -1802 -9703 4557 1346 3260 6245 -879 -1094 -3673 -6360 -808 12539 -9347 -1037 568 1227 -2763 2430 5301 -6543 4259 -9263 -894 -5518 6531 -8275 3455 -199 9102 1727 -5054 -3587 -5934 3699 -4552 3455 3091 3003 3039 6233 10234 4464 3509 -4319 -6649 3207 3989 -3969 8852 845 5097 -7505 8874 -10232 -4152 3836 -277 5232 -8781 -2753 SU 20191003T210952.6Z 7215.881859 23938 1 29.18 2 75.18 250.99 62.52 177.70 0.00 1 0.00 1 0 41 4.616e-01 8.838e-02 4.141e-01 9.474e-02 4.661015e-01 5.083419e-02 5.519316e-03 -6.000000e+00 2.793599e-01 227.25 -2.00 3.51 -2.00 318.90 0.00e+00 2.267296e-03 1.095328e-02 5.748150e-04 -6.000000e+00 1.294757e-02 285.76 -2.00 20.00 -2.00 318.15 0.00e+00 3.830 0.001 302.00 328.00 3 6.7919e+00 1.3961e-01 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