File name: Pandora55s1_QueensNY_20200517_L2Fit_fout2c10d20200414p1-8.txt File generation date: 20260625T155811.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: James Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v3d20190723.txt Instrument calibration file used: Pandora55s1_CF_v10d20200414.txt Level 1 file used: Pandora55s1_QueensNY_20200517_L1_smca1c10d20200414p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20200517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1379 305.2779 305.4179 305.5579 305.6978 305.8378 305.9778 306.1177 306.2576 306.3976 306.5375 306.6774 306.8172 306.9571 307.0970 307.2369 307.3767 307.5165 307.6564 307.7962 307.9360 308.0758 308.2156 308.3553 308.4951 308.6349 308.7746 308.9143 309.0541 309.1938 309.3335 309.4732 309.6128 309.7525 309.8922 310.0318 310.1715 310.3111 310.4507 310.5903 310.7299 310.8695 311.0091 311.1486 311.2882 311.4277 311.5673 311.7068 311.8463 311.9858 312.1253 312.2648 312.4043 312.5437 312.6832 312.8226 312.9621 313.1015 313.2409 313.3803 313.5197 313.6591 313.7984 313.9378 314.0771 314.2165 314.3558 314.4951 314.6344 314.7737 314.9130 315.0523 315.1915 315.3308 315.4700 315.6092 315.7485 315.8877 316.0269 316.1661 316.3052 316.4444 316.5836 316.7227 316.8618 317.0010 317.1401 317.2792 317.4183 317.5574 317.6964 317.8355 317.9745 318.1136 318.2526 318.3916 318.5306 318.6696 318.8086 318.9476 319.0866 319.2255 319.3645 319.5034 319.6423 319.7812 319.9201 320.0590 320.1979 320.3368 320.4756 320.6145 320.7533 320.8922 321.0310 321.1698 321.3086 321.4474 321.5861 321.7249 321.8636 322.0024 322.1411 322.2798 322.4185 322.5572 322.6959 322.8346 322.9733 323.1119 323.2506 323.3892 323.5278 323.6665 323.8051 323.9436 324.0822 324.2208 324.3594 324.4979 324.6364 324.7750 324.9135 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200517T110017.0Z 7442.458531 1130 1 2.08 2 75.86 76.29 56.31 137.51 0.00 1 0.00 1 0 17 3.154e-01 1.592e-02 2.683e-01 1.346e-02 5.477569e-01 7.287853e-03 6.291703e-03 -6.000000e+00 1.919955e-01 231.29 -2.00 3.51 -2.00 319.83 0.00e+00 1.779215e-03 2.307865e-03 3.016366e-04 -6.000000e+00 8.502478e-03 283.94 -2.00 20.00 -2.00 319.16 0.00e+00 4.003 0.001 302.00 328.00 3 2.1507e+00 2.1182e-02 4.9504e-02 -6.0000e+00 4.8216e-01 4.3854e-02 2.5447e-02 2.9110e-02 -6.0000e+00 5.2192e-01 -3.3694e-02 2.1415e-02 1.4437e-02 -6.0000e+00 3.0900e-01 9.8467e-03 1.1039e-02 4.5565e-03 -6.0000e+00 1.2961e-01 5.9778e-04 -8.0699e-04 4.0471e-04 5.1913e-05 -6.0000e+00 9.5916e-03 2.9332e-03 4.9681e-05 12 9 9 12 1 1 999.00 22.74 0.19 0.00293 -0.00313 1 10 1 5 0 952.970 25.68 20.02 22.74 19.86 23.5 1037.03 251557 900000 -125400 -55335 -4743 35129 115428 900000 -106414 -70336 12290 -18408 25665 -2569 86987 -35170 900000 -22135 -8945 -10090 24694 2914 17966 -4214 -17510 52635 821 40788 -18733 2150 -2007 8267 -22291 -12902 17596 -13748 -15168 5320 3256 -9747 12844 -7970 -2082 752 15084 -256 5661 -3684 2990 3599 2333 1896 -1574 9997 -7017 8603 -3020 5545 -5561 2456 4297 2825 -99 -1589 3120 3202 2624 572 -448 -1125 2734 2603 -943 1256 -3323 5630 -1938 2584 -2301 2426 -1004 -1116 -1309 -2181 -3282 -1905 1417 -2288 90 -591 986 -3205 3840 880 948 722 1999 -243 -1539 -115 -1986 1558 1177 2132 -3260 731 -1179 -1187 1057 -657 130 -44 644 -1615 670 210 707 523 405 -941 192 1131 -461 678 165 -28 935 1666 -1614 1052 -66 -565 47 543 94 447 382 -741 -308 -685 890 -715 -253 3301 900000 -4001 -888 -62 461 1515 900000 -3718 -1879 165 -378 428 -68 1199 -1701 900000 -1129 -431 -513 937 138 784 -243 -1221 1999 50 1689 -1358 139 -154 665 -2602 -1427 1454 -1553 -1941 671 496 -1909 2263 -1790 -461 165 2970 -59 1249 -902 717 910 648 577 -529 3251 -2750 3065 -1207 2057 -2238 924 1655 1190 -47 -813 1577 1587 1288 292 -250 -694 1753 1721 -636 802 -2069 3030 -1054 1367 -1361 1553 -735 -893 -1112 -1957 -3105 -1869 1409 -2377 92 -593 937 -2981 3294 781 898 749 2249 -299 -2008 -149 -2514 1820 1318 2382 -3923 893 -1511 -1584 1463 -976 203 -71 1031 -2558 1012 309 1036 783 629 -1515 309 1787 -720 1030 246 -41 1319 2368 -2470 1689 -113 -1000 86 1014 182 893 780 -1536 -638 -1404 1760 -1381 -479 SU 20200517T110230.4Z 7442.460074 1132 1 50.76 2 75.45 76.63 56.03 138.07 0.00 1 0.00 1 0 25 2.393e-01 9.799e-03 1.010e-01 2.231e-03 5.457566e-01 1.204175e-03 6.264807e-03 -6.000000e+00 1.440515e-01 231.29 -2.00 3.51 -2.00 320.03 0.00e+00 1.935974e-03 4.054985e-04 3.736973e-04 -6.000000e+00 6.414482e-03 283.94 -2.00 20.00 -2.00 319.36 0.00e+00 3.897 0.001 302.00 328.00 3 2.3950e+00 3.5508e-03 4.8691e-02 -6.0000e+00 3.6048e-01 6.1190e-02 4.3432e-03 2.9337e-02 -6.0000e+00 3.8947e-01 -1.2829e-02 3.7511e-03 1.4493e-02 -6.0000e+00 2.3169e-01 -6.2700e-03 1.9093e-03 4.8586e-03 -6.0000e+00 9.7935e-02 5.0932e-04 -7.2194e-04 6.7402e-05 5.3213e-05 -6.0000e+00 7.1954e-03 5.0400e-03 4.0140e-05 12 8 8 10 0 0 99.89 22.75 0.19 0.00504 -0.00038 95 18 1 5 0 528.610 25.68 20.00 22.75 19.80 23.5 1036.71 77462 900000 -70311 15904 111327 -96920 92542 -37161 -50607 -106000 -2379 -83161 -14241 7451 22547 -27980 53158 48128 15391 33443 -15290 23272 -21439 883 -14519 37986 -11926 -17106 -20398 -9768 8732 -2984 -10780 -17123 27618 -6078 -7697 8538 2655 -4382 968 -3909 -4680 1653 5882 -3735 3634 2194 3597 68 -1735 -2059 5853 2689 3267 3407 567 2103 1835 1093 5626 1999 -1718 1533 -1465 2597 -665 3215 1800 121 10 476 -1311 177 -463 1094 2575 233 843 -1710 1185 -753 -648 -2246 -754 -1245 -809 -900 -926 -120 79 735 1318 649 1143 13 358 -241 -1097 -650 -311 -79 1402 253 -725 -1033 -541 -127 737 -59 -936 -183 -213 -119 223 1165 1201 548 -15 -778 -496 199 464 -119 106 -92 1446 523 -173 537 408 497 331 499 -609 -147 62 -238 -547 -61 -572 60 167 304 900000 -1223 121 331 -2056 379 -572 -966 -3542 -34 -2818 -316 165 518 -1147 1153 1180 540 1041 -760 835 -1220 44 -892 1502 -741 -1093 -1364 -642 556 -242 -1031 -1787 1891 -581 -836 950 371 -747 172 -771 -969 330 1147 -803 747 467 785 16 -458 -598 1710 862 1087 1175 204 746 641 387 1984 792 -772 720 -723 1212 -314 1513 933 70 6 305 -848 108 -266 574 1266 118 460 -1078 816 -580 -531 -1962 -686 -1195 -803 -914 -938 -117 74 644 1113 558 1053 13 403 -297 -1430 -849 -388 -92 1544 282 -851 -1271 -688 -169 1028 -88 -1492 -300 -349 -189 339 1712 1762 828 -24 -1272 -813 320 729 -184 158 -134 2030 750 -265 876 705 892 614 955 -1223 -304 131 -509 -1174 -128 -1173 118 323 SU 20200517T110353.6Z 7442.461037 1134 1 3.18 2 75.19 76.84 55.86 138.42 0.00 1 0.00 1 0 25 1.784e-01 9.643e-03 1.673e-01 6.345e-03 5.398081e-01 3.401832e-03 6.229344e-03 -6.000000e+00 1.081540e-01 231.29 -2.00 3.51 -2.00 319.62 0.00e+00 1.111691e-03 1.005398e-03 2.531966e-04 -6.000000e+00 4.721534e-03 283.94 -2.00 20.00 -2.00 318.93 0.00e+00 3.834 0.001 302.00 328.00 3 1.7655e+00 9.7474e-03 4.7898e-02 -6.0000e+00 2.7093e-01 5.7260e-02 1.1598e-02 2.8641e-02 -6.0000e+00 2.9293e-01 -2.5261e-02 9.4875e-03 1.4091e-02 -6.0000e+00 1.7339e-01 1.5211e-03 4.9161e-03 4.1625e-03 -6.0000e+00 7.2607e-02 1.0302e-03 -8.2671e-04 1.8917e-04 4.8352e-05 -6.0000e+00 5.4528e-03 4.7954e-03 -2.3537e-05 12 9 9 12 1 1 -110.70 22.75 0.13 0.00480 -0.00142 4 16 1 5 0 600.730 25.68 19.98 22.75 19.76 23.5 1036.49 42293 102797 -60466 89192 -36059 -38750 900000 -45416 -25622 -77368 -19082 -42840 5406 -14076 31345 -19139 -22034 14332 19201 18681 -20141 6112 -20687 10233 -11727 15842 -4347 -8173 -9503 8467 132 -5338 -709 -11658 17340 -2418 3026 -1960 -365 -439 -126 -3624 -5047 -307 93 -84 1290 968 -3432 4457 680 506 4013 328 2550 1716 1609 -205 86 833 3900 2189 732 63 86 1271 1793 2469 127 -523 -306 1109 -1546 1284 -252 1514 314 1534 -329 -1882 259 -682 -1281 -1903 -403 -615 -418 -1408 -1039 -1149 522 618 1167 1758 1680 681 387 517 -1153 -216 -1158 548 751 -53 -1133 -842 -1045 302 208 554 -1826 -453 -389 272 -16 1362 1591 983 -506 -947 -420 634 369 345 51 12 1083 624 913 227 321 -638 631 602 -331 -356 -140 16 -880 46 -437 396 -173 310 636 -1270 552 -561 -639 900000 -1001 -517 -2665 -414 -1333 131 -496 864 -942 -1222 615 841 855 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