File name: Pandora55s1_QueensNY_20200902_L2Fit_fout2c10d20200414p1-8.txt File generation date: 20260625T165415.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: James Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v3d20190723.txt Instrument calibration file used: Pandora55s1_CF_v10d20200414.txt Level 1 file used: Pandora55s1_QueensNY_20200902_L1_smca1c10d20200414p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20200902 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1379 305.2779 305.4179 305.5579 305.6978 305.8378 305.9778 306.1177 306.2576 306.3976 306.5375 306.6774 306.8172 306.9571 307.0970 307.2369 307.3767 307.5165 307.6564 307.7962 307.9360 308.0758 308.2156 308.3553 308.4951 308.6349 308.7746 308.9143 309.0541 309.1938 309.3335 309.4732 309.6128 309.7525 309.8922 310.0318 310.1715 310.3111 310.4507 310.5903 310.7299 310.8695 311.0091 311.1486 311.2882 311.4277 311.5673 311.7068 311.8463 311.9858 312.1253 312.2648 312.4043 312.5437 312.6832 312.8226 312.9621 313.1015 313.2409 313.3803 313.5197 313.6591 313.7984 313.9378 314.0771 314.2165 314.3558 314.4951 314.6344 314.7737 314.9130 315.0523 315.1915 315.3308 315.4700 315.6092 315.7485 315.8877 316.0269 316.1661 316.3052 316.4444 316.5836 316.7227 316.8618 317.0010 317.1401 317.2792 317.4183 317.5574 317.6964 317.8355 317.9745 318.1136 318.2526 318.3916 318.5306 318.6696 318.8086 318.9476 319.0866 319.2255 319.3645 319.5034 319.6423 319.7812 319.9201 320.0590 320.1979 320.3368 320.4756 320.6145 320.7533 320.8922 321.0310 321.1698 321.3086 321.4474 321.5861 321.7249 321.8636 322.0024 322.1411 322.2798 322.4185 322.5572 322.6959 322.8346 322.9733 323.1119 323.2506 323.3892 323.5278 323.6665 323.8051 323.9436 324.0822 324.2208 324.3594 324.4979 324.6364 324.7750 324.9135 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200902T145138.8Z 7550.619199 350 1 11.54 2 42.99 131.92 136.20 302.54 0.00 1 0.00 1 0 17 2.757e-02 1.692e-02 4.409e-03 3.079e-03 1.731897e-01 1.646680e-03 2.017566e-03 -6.000000e+00 1.656911e-02 230.24 -2.00 3.51 -2.00 314.85 0.00e+00 8.739352e-04 1.409353e-04 6.779653e-05 -6.000000e+00 7.453890e-04 288.89 -2.00 20.00 -2.00 314.18 0.00e+00 1.365 0.000 302.00 328.00 3 4.6317e+00 4.2289e-03 1.6246e-02 -6.0000e+00 4.1288e-02 4.6328e-02 4.6794e-03 8.8737e-03 -6.0000e+00 4.4576e-02 -9.5038e-03 2.6730e-03 4.2516e-03 -6.0000e+00 2.6606e-02 2.2177e-03 1.1676e-03 1.3723e-03 -6.0000e+00 1.1291e-02 1.1079e-03 2.3011e-03 9.4432e-05 1.7297e-05 -6.0000e+00 8.2841e-04 8.1277e-03 6.2828e-04 12 9 9 12 9 1 97.67 22.95 0.08 0.00813 0.02542 3 3 1 5 0 2841.680 25.79 20.03 22.95 31.12 26.6 1040.01 -91 4347 -1851 4209 5699 1072 3487 -147 2514 -300 1245 49 995 2943 763 887 -27768 4481 2387 3013 2540 3916 1417 -504 -242 1047 -753 -504 1667 1784 3155 2019 -880 -610 2489 788 614 812 30 -1925 -563 -2325 -1324 -851 595 -1130 136 694 1244 339 192 478 1099 1590 531 1590 637 526 1264 1180 1566 -188 24 111 338 650 99 2531 705 253 -523 122 -1797 -497 -845 -106 718 552 -424 -626 120 -1633 -920 -1880 -592 -1308 -570 -560 -591 -190 -32 397 211 1047 -211 460 292 -204 -287 -354 -64 7 1031 439 -675 -295 -713 60 321 172 -167 69 -444 -300 48 1247 828 1175 -326 -590 -19 331 142 -187 180 -547 587 904 316 788 498 447 292 625 170 294 453 6 -1662 27 -765 -410 -345 -32 1535 -667 1357 1698 329 1108 -52 910 -112 456 19 406 1283 361 434 -16802 2218 1221 1557 1324 2022 754 -279 -137 593 -422 -271 845 896 1614 1088 -495 -340 1320 425 354 521 22 -1492 -452 -1926 -1102 -708 490 -931 109 544 957 263 153 393 928 1369 466 1403 566 466 1109 1042 1410 -178 24 111 332 608 89 2211 648 248 -537 127 -1898 -510 -835 -98 625 469 -370 -581 118 -1698 -986 -2088 -678 -1561 -699 -698 -735 -231 -37 436 221 1070 -223 507 341 -250 -362 -442 -77 8 1167 508 -816 -369 -916 79 429 236 -235 97 -614 -397 61 1511 1000 1445 -420 -789 -26 450 190 -246 230 -682 708 1083 387 997 647 588 387 842 236 419 657 9 -2481 40 -1113 -585 -489 SS 20200902T170238.6Z 7550.710169 434 1 1.28 2 33.23 183.56 149.39 350.27 0.00 1 0.00 1 0 17 9.992e-03 8.351e-03 2.300e-03 1.820e-03 1.468622e-01 9.830240e-04 1.828344e-03 -6.000000e+00 5.988227e-03 230.23 -2.00 3.51 -2.00 314.16 0.00e+00 8.124586e-05 7.363704e-05 3.899264e-05 -6.000000e+00 2.699856e-04 288.88 -2.00 20.00 -2.00 313.57 0.00e+00 1.195 0.000 302.00 328.00 3 1.7341e+00 2.5101e-03 1.4198e-02 -6.0000e+00 1.4920e-02 2.3327e-02 2.7686e-03 7.6943e-03 -6.0000e+00 1.6124e-02 3.2045e-04 1.5889e-03 3.7548e-03 -6.0000e+00 9.6238e-03 -2.7107e-03 6.8044e-04 1.0475e-03 -6.0000e+00 4.0724e-03 2.5376e-02 -3.2734e-04 5.5554e-05 1.6894e-05 -6.0000e+00 3.0043e-04 1.5329e-02 1.5015e-04 12 9 1 12 9 1 -98.52 22.96 0.24 0.01533 0.01287 7 69 1 5 0 138.140 25.79 19.97 22.96 34.15 26.8 1057.33 -1488 -2526 -3800 -1135 1365 1439 1643 747 -832 -766 1728 1724 920 836 -239 -140 -342 218 375 -237 764 1067 705 847 260 -769 -1170 93 1561 1378 1894 1835 -894 -222 1248 490 724 395 -671 -1501 -1184 -1620 -1415 -1364 -909 -1469 -1107 -851 538 902 411 951 480 536 466 1045 225 701 899 1670 1128 771 212 -872 -581 272 529 1594 1490 264 -452 -975 -478 -673 -199 906 799 1714 883 -100 -736 -1573 -1172 -1199 -988 -774 -808 -748 -620 -604 110 401 1510 1824 1250 819 957 -51 -738 -649 -476 184 1137 375 -905 -298 -940 -57 -82 -124 -599 -484 -479 -254 567 998 1213 804 -126 -569 -517 -381 -428 272 476 718 1821 1571 588 363 -177 132 284 363 -234 -376 263 -548 -547 -426 -237 -263 -75 -667 -1171 -1708 -478 546 570 703 336 -380 -351 808 789 464 443 -132 -80 -200 130 228 -141 472 656 423 529 170 -508 -746 58 891 812 1090 1112 -548 -139 734 294 458 280 -516 -1247 -1007 -1428 -1262 -1216 -801 -1279 -928 -711 448 748 342 829 422 486 415 939 205 631 829 1538 1044 736 216 -890 -592 261 484 1415 1413 260 -466 -1048 -509 -692 -196 860 715 1505 776 -94 -740 -1609 -1265 -1317 -1117 -905 -966 -918 -757 -732 127 431 1568 1819 1298 894 1103 -60 -920 -797 -568 210 1285 427 -1083 -364 -1173 -73 -107 -164 -821 -664 -647 -327 683 1160 1435 960 -157 -739 -675 -498 -562 341 583 860 2121 1811 711 449 -221 169 366 467 -309 -522 364 -783 -768 -608 -329 -363 -101 SS 20200902T170804.3Z 7550.713939 437 1 4.60 2 33.31 186.01 149.52 352.78 0.00 1 0.00 1 0 17 9.989e-03 8.220e-03 4.326e-03 3.371e-03 1.474097e-01 1.816828e-03 1.830087e-03 -6.000000e+00 5.985987e-03 230.23 -2.00 3.51 -2.00 314.26 0.00e+00 -3.379495e-04 1.384894e-04 1.458522e-05 -6.000000e+00 2.698883e-04 288.88 -2.00 20.00 -2.00 313.65 0.00e+00 1.196 0.000 302.00 328.00 3 4.0343e+00 4.6437e-03 1.4225e-02 -6.0000e+00 1.4915e-02 2.9823e-02 5.1225e-03 7.7329e-03 -6.0000e+00 1.6118e-02 2.7260e-03 2.9385e-03 3.7632e-03 -6.0000e+00 9.6201e-03 -2.7207e-03 1.2626e-03 1.0493e-03 -6.0000e+00 4.0711e-03 2.5340e-03 -3.7221e-04 1.0290e-04 1.6523e-05 -6.0000e+00 3.0032e-04 1.3926e-02 9.9243e-05 12 9 1 12 1 1 999.00 22.95 0.09 0.01393 0.01113 2 6 1 5 0 1476.100 25.79 20.01 22.95 35.18 26.9 1063.54 -2476 -1000 -3825 -488 1079 179 1722 862 -1516 -865 1884 1352 1301 454 -527 -940 552 858 599 -193 889 1346 1001 382 -543 -358 -288 148 152 1834 2437 1738 -1122 -1418 1079 133 29 1518 -896 -1621 -926 -1806 -813 -1051 -340 -947 -1235 -32 21 568 -101 59 1141 453 400 1537 943 1155 -322 1613 1421 899 -73 -1027 -675 615 747 2029 1402 -289 -72 -476 -940 -988 -848 292 982 2066 310 -499 -721 -1815 -1245 -1002 -1173 -812 -719 -391 -325 -313 421 185 922 1481 1132 1097 717 -492 -540 -630 -276 421 1237 615 -976 -382 -475 -192 161 -73 -250 -390 -166 -342 63 793 456 893 115 -871 -578 -102 -545 697 325 352 1643 1355 512 322 35 -63 624 -98 -285 273 554 -165 -998 -268 -536 -296 -198 -1096 -446 -1688 -197 408 68 684 370 -688 -393 834 617 630 236 -290 -533 314 493 351 -115 528 797 603 237 -348 -230 -180 89 87 1032 1393 1034 -693 -866 631 79 18 1052 -692 -1342 -792 -1581 -714 -924 -297 -820 -1051 -27 17 461 -84 51 998 407 363 1403 866 1056 -296 1468 1321 869 -73 -1053 -679 586 679 1810 1307 -287 -75 -503 -997 -1027 -849 274 868 1769 273 -466 -712 -1891 -1334 -1104 -1340 -961 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