File name: Pandora55s1_QueensNY_20200917_L2Fit_fout2c10d20200414p1-8.txt File generation date: 20260625T165428.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: James Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v3d20190723.txt Instrument calibration file used: Pandora55s1_CF_v10d20200414.txt Level 1 file used: Pandora55s1_QueensNY_20200917_L1_smca1c10d20200414p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20200917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1379 305.2779 305.4179 305.5579 305.6978 305.8378 305.9778 306.1177 306.2576 306.3976 306.5375 306.6774 306.8172 306.9571 307.0970 307.2369 307.3767 307.5165 307.6564 307.7962 307.9360 308.0758 308.2156 308.3553 308.4951 308.6349 308.7746 308.9143 309.0541 309.1938 309.3335 309.4732 309.6128 309.7525 309.8922 310.0318 310.1715 310.3111 310.4507 310.5903 310.7299 310.8695 311.0091 311.1486 311.2882 311.4277 311.5673 311.7068 311.8463 311.9858 312.1253 312.2648 312.4043 312.5437 312.6832 312.8226 312.9621 313.1015 313.2409 313.3803 313.5197 313.6591 313.7984 313.9378 314.0771 314.2165 314.3558 314.4951 314.6344 314.7737 314.9130 315.0523 315.1915 315.3308 315.4700 315.6092 315.7485 315.8877 316.0269 316.1661 316.3052 316.4444 316.5836 316.7227 316.8618 317.0010 317.1401 317.2792 317.4183 317.5574 317.6964 317.8355 317.9745 318.1136 318.2526 318.3916 318.5306 318.6696 318.8086 318.9476 319.0866 319.2255 319.3645 319.5034 319.6423 319.7812 319.9201 320.0590 320.1979 320.3368 320.4756 320.6145 320.7533 320.8922 321.0310 321.1698 321.3086 321.4474 321.5861 321.7249 321.8636 322.0024 322.1411 322.2798 322.4185 322.5572 322.6959 322.8346 322.9733 323.1119 323.2506 323.3892 323.5278 323.6665 323.8051 323.9436 324.0822 324.2208 324.3594 324.4979 324.6364 324.7750 324.9135 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200917T122032.8Z 7565.514268 86 1 17.52 2 71.65 103.78 71.75 98.51 0.00 1 0.00 1 0 25 1.101e-01 1.411e-02 3.853e-02 4.611e-03 3.902888e-01 2.422852e-03 4.645048e-03 -6.000000e+00 6.567876e-02 228.93 -2.00 3.51 -2.00 318.67 0.00e+00 1.352921e-03 5.334675e-04 2.892761e-04 -6.000000e+00 2.998944e-03 287.62 -2.00 20.00 -2.00 317.87 0.00e+00 3.135 0.001 302.00 328.00 3 3.7482e+00 6.6362e-03 3.7359e-02 -6.0000e+00 1.6320e-01 2.6184e-02 7.6196e-03 2.0679e-02 -6.0000e+00 1.7657e-01 3.1479e-04 5.2066e-03 9.9984e-03 -6.0000e+00 1.0549e-01 -2.6435e-03 2.7060e-03 3.1186e-03 -6.0000e+00 4.4914e-02 3.4090e-04 -6.6883e-04 1.4300e-04 3.5754e-05 -6.0000e+00 3.3101e-03 1.1135e-02 1.4259e-05 12 9 9 12 41 1 97.02 22.95 0.39 0.01114 0.00611 5 3 1 5 0 2891.730 25.79 20.01 22.95 26.22 26.4 1011.95 -6266 900000 -52234 46301 37463 -7522 24346 -34882 870 -32325 7001 -23850 4654 43609 -374 -18338 -31712 10773 14699 4603 -7336 16297 -13401 -3521 -9648 31400 -4831 -13192 -222 286 11799 8020 -8938 5442 20177 -2623 -2522 5815 6299 -4593 4658 -6755 -2035 406 4713 -1150 1134 2393 2730 789 -2452 -1681 1270 4417 670 3520 2262 1572 -1 2549 4424 -781 231 40 532 1784 -1317 3459 189 507 -1258 479 -3432 1028 -1937 2216 1560 1231 173 -281 790 -2750 282 -3100 -1071 -1760 -822 -1626 -8 -732 85 233 1671 915 1299 603 64 440 -1655 109 -1092 -70 1912 993 -1620 -581 -161 -860 505 526 -1216 -315 474 324 578 -43 1044 110 -437 -932 -604 179 1217 -146 629 188 1016 1125 251 821 524 730 349 927 -123 192 -439 80 -904 -187 -1372 23 -203 -240 900000 -3267 1087 907 -283 749 -2091 40 -2126 334 -1692 297 2279 -34 -2148 -4480 1092 1512 536 -971 1766 -1987 -508 -1553 3555 -753 -2146 -32 42 1739 1359 -1882 1017 3238 -528 -565 1417 1779 -1601 1620 -2697 -801 159 1797 -460 445 931 1076 327 -1110 -809 630 2243 362 1908 1252 873 -1 1397 2476 -485 153 28 369 1181 -866 2222 133 387 -1032 398 -2917 818 -1491 1542 1030 812 121 -218 666 -2553 270 -3167 -1128 -1947 -935 -1896 -10 -825 92 236 1612 886 1320 665 77 561 -2221 144 -1403 -84 2210 1170 -2026 -752 -214 -1190 722 788 -1915 -502 745 491 841 -61 1464 159 -656 -1453 -951 278 1849 -219 912 265 1393 1554 364 1249 833 1190 581 1583 -218 350 -822 150 -1720 -350 -2534 42 -358 SS 20200917T122655.3Z 7565.518696 89 1 50.64 2 70.48 104.93 70.61 99.60 0.00 1 0.00 1 0 25 9.011e-02 1.070e-02 1.425e-02 2.014e-03 3.746907e-01 1.054697e-03 4.487763e-03 -6.000000e+00 5.375531e-02 228.93 -2.00 3.51 -2.00 318.43 0.00e+00 -1.025381e-04 2.155595e-04 3.757188e-04 -6.000000e+00 2.421859e-03 287.62 -2.00 20.00 -2.00 317.62 0.00e+00 2.959 0.000 302.00 328.00 3 3.5485e+00 2.8657e-03 3.5438e-02 -6.0000e+00 1.3357e-01 2.3725e-02 3.2764e-03 1.9726e-02 -6.0000e+00 1.4451e-01 6.8513e-03 2.1834e-03 9.5899e-03 -6.0000e+00 8.6276e-02 -7.4899e-03 1.1263e-03 2.6554e-03 -6.0000e+00 3.6581e-02 5.0532e-04 -4.9988e-04 6.2298e-05 3.2662e-05 -6.0000e+00 2.7081e-03 1.0614e-02 6.5732e-05 12 8 8 10 0 0 97.74 22.95 0.36 0.01061 0.00686 30 6 1 5 0 1687.690 25.79 20.00 22.95 26.33 26.4 1012.35 -9424 65208 -38861 11533 -5893 870 13098 -14440 -9829 -19763 -22533 -14678 -1836 23783 -6191 -15315 40244 8458 6820 6957 -3951 2306 -6872 -4757 -6609 13143 -3037 -8527 4573 687 3448 4664 -6101 774 11374 -2432 -3677 4404 1522 -3190 2254 -4118 -2212 -35 1365 -1501 90 -700 2408 166 -74 -1688 2185 2899 774 3141 1129 2150 -144 1898 2473 854 -451 -94 -1691 1090 -847 2282 1374 -158 -1095 -538 -2020 692 -307 1110 1557 1239 12 -175 249 -1612 -1096 -2024 -783 -1066 -743 -816 -450 -565 294 977 1346 1556 1035 634 1069 -496 -1102 -351 -574 -82 1566 325 -1299 -266 -607 -193 757 547 -802 -281 -52 51 494 690 1301 84 -502 -1456 -388 73 -115 -357 437 43 1358 1155 45 534 799 283 445 566 -268 -49 43 -187 -659 -290 -583 -128 39 -448 1652 -2579 451 -257 37 541 -871 -615 -1413 -1722 -1150 -148 1764 -687 -2018 3398 1006 865 911 -580 326 -1106 -803 -1196 2045 -537 -1525 713 115 615 908 -1392 168 2189 -542 -921 1200 494 -1207 878 -1759 -956 -15 580 -653 39 -301 1021 74 -35 -865 1147 1585 443 1815 670 1262 -85 1107 1483 553 -314 -68 -1244 757 -578 1537 994 -126 -927 -466 -1758 571 -242 808 1067 845 9 -139 215 -1519 -1080 -2092 -838 -1195 -859 -963 -528 -647 320 1004 1322 1522 1067 705 1275 -639 -1478 -468 -738 -99 1827 387 -1629 -345 -813 -266 1081 819 -1259 -447 -82 78 717 967 1813 120 -752 -2261 -607 113 -175 -533 632 61 1853 1585 64 808 1255 457 732 955 -470 -89 78 -347 -1236 -536 -1057 -225 68 SS 20200917T123226.8Z 7565.522532 92 1 49.54 2 69.47 105.93 69.62 100.56 0.00 1 0.00 1 0 25 6.803e-02 9.635e-03 1.014e-02 1.814e-03 3.579704e-01 9.494183e-04 4.274073e-03 -6.000000e+00 4.057708e-02 228.93 -2.00 3.51 -2.00 318.12 0.00e+00 -2.034572e-04 1.765148e-04 2.475166e-04 -6.000000e+00 1.828371e-03 287.62 -2.00 20.00 -2.00 317.30 0.00e+00 2.822 0.000 302.00 328.00 3 3.5309e+00 2.5561e-03 3.3772e-02 -6.0000e+00 1.0083e-01 2.2281e-02 2.9025e-03 1.8696e-02 -6.0000e+00 1.0909e-01 -1.5336e-03 1.8601e-03 9.1101e-03 -6.0000e+00 6.5128e-02 -2.6968e-03 9.4995e-04 2.5166e-03 -6.0000e+00 2.7610e-02 6.0227e-04 -4.6971e-04 5.6112e-05 3.0978e-05 -6.0000e+00 2.0445e-03 1.0748e-02 2.7576e-05 12 8 8 10 0 0 96.66 22.95 0.28 0.01075 0.00722 26 5 1 5 0 1904.920 25.79 20.01 22.95 26.44 26.4 1012.94 -6826 57346 -29374 1157 6471 -8908 16635 -12768 703 -16106 -14821 -11732 2870 13599 -6556 -8014 -1239 6377 4139 6643 -4679 4274 -5134 -825 -3972 9571 -1773 -7327 -2066 -18 4396 2779 -5806 -1100 8023 -1527 -2191 4315 982 -2786 628 -4401 -1012 -191 858 -1180 238 687 1823 362 -271 -747 2414 2672 1369 2856 1162 1568 783 2049 2162 731 -327 -35 -1140 948 -851 1778 852 -90 -506 -398 -1756 267 -722 888 1564 1553 -74 -25 -222 -1607 -1192 -2076 -702 -1062 -714 -1148 -583 -579 209 1083 785 1607 881 671 583 -303 -892 -324 -623 -253 1480 412 -999 -10 -487 -164 526 -121 -576 -386 -96 -25 662 835 936 544 -453 -1312 -470 145 503 -263 412 74 1314 1104 -41 629 517 406 280 707 -196 226 -12 -329 -783 -375 -675 -123 21 -409 2011 -2273 63 321 -522 845 -958 50 -1399 -1316 -1115 274 1363 -893 -1198 -184 930 644 1044 -827 707 -966 -159 -830 1812 -365 -1523 -401 -3 899 633 -1510 -276 1817 -385 -615 1333 360 -1172 275 -2083 -477 -90 403 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