File name: Pandora55s1_QueensNY_20201106_L2Fit_fout2c10d20200414p1-8.txt File generation date: 20260625T171405.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: James Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v3d20190723.txt Instrument calibration file used: Pandora55s1_CF_v10d20200414.txt Level 1 file used: Pandora55s1_QueensNY_20201106_L1_smca1c10d20200414p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20201106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1379 305.2779 305.4179 305.5579 305.6978 305.8378 305.9778 306.1177 306.2576 306.3976 306.5375 306.6774 306.8172 306.9571 307.0970 307.2369 307.3767 307.5165 307.6564 307.7962 307.9360 308.0758 308.2156 308.3553 308.4951 308.6349 308.7746 308.9143 309.0541 309.1938 309.3335 309.4732 309.6128 309.7525 309.8922 310.0318 310.1715 310.3111 310.4507 310.5903 310.7299 310.8695 311.0091 311.1486 311.2882 311.4277 311.5673 311.7068 311.8463 311.9858 312.1253 312.2648 312.4043 312.5437 312.6832 312.8226 312.9621 313.1015 313.2409 313.3803 313.5197 313.6591 313.7984 313.9378 314.0771 314.2165 314.3558 314.4951 314.6344 314.7737 314.9130 315.0523 315.1915 315.3308 315.4700 315.6092 315.7485 315.8877 316.0269 316.1661 316.3052 316.4444 316.5836 316.7227 316.8618 317.0010 317.1401 317.2792 317.4183 317.5574 317.6964 317.8355 317.9745 318.1136 318.2526 318.3916 318.5306 318.6696 318.8086 318.9476 319.0866 319.2255 319.3645 319.5034 319.6423 319.7812 319.9201 320.0590 320.1979 320.3368 320.4756 320.6145 320.7533 320.8922 321.0310 321.1698 321.3086 321.4474 321.5861 321.7249 321.8636 322.0024 322.1411 322.2798 322.4185 322.5572 322.6959 322.8346 322.9733 323.1119 323.2506 323.3892 323.5278 323.6665 323.8051 323.9436 324.0822 324.2208 324.3594 324.4979 324.6364 324.7750 324.9135 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201106T132625.2Z 7615.560014 300 1 50.49 2 72.35 131.37 53.86 272.12 0.00 1 0.00 1 0 25 2.779e-01 1.249e-02 8.998e-02 2.599e-03 4.134810e-01 1.347757e-03 4.935433e-03 -6.000000e+00 1.627639e-01 223.96 -2.00 3.51 -2.00 319.11 0.00e+00 1.049881e-03 3.374726e-04 6.297357e-04 -6.000000e+00 7.373884e-03 281.52 -2.00 20.00 -2.00 318.43 0.00e+00 3.252 0.001 302.00 328.00 3 3.5958e+00 3.7169e-03 3.8695e-02 -6.0000e+00 4.0067e-01 2.3059e-02 4.3250e-03 2.1774e-02 -6.0000e+00 4.3539e-01 -4.1784e-03 3.2204e-03 1.0580e-02 -6.0000e+00 2.6019e-01 -3.6193e-03 1.6888e-03 3.3550e-03 -6.0000e+00 1.1141e-01 3.4938e-04 -2.3499e-04 8.0523e-05 3.8877e-05 -6.0000e+00 8.3392e-03 8.9886e-03 1.1799e-04 12 8 8 10 0 0 99.92 22.96 0.32 0.00899 0.00722 45 9 1 5 0 1121.820 25.79 20.00 22.96 21.68 26.9 995.65 13862 900000 -57344 49045 -7558 -48477 288152 -13915 15669 -44174 25930 -48425 36046 25966 -2354 -7281 -4508 45829 10779 23523 -7666 3692 -9198 -6142 -6704 27634 -4374 -11030 -11179 -6560 5900 -1579 -8168 -7154 27960 -7948 -2685 8779 3664 -1835 -1539 -5011 -1176 1701 3336 -2701 3951 4676 2744 31 -2944 -4233 3588 3817 637 2552 2301 2247 676 727 3440 715 -1403 2073 -1686 1639 -2226 2881 1807 -934 -391 1230 -2169 1366 -253 540 3764 966 276 -1392 1972 -1524 -768 -2426 -984 -1557 -1014 -1114 -412 -539 -202 746 686 1301 889 34 517 96 -1103 -370 -162 -384 1803 548 -539 -137 -847 -110 1187 -222 -872 -147 -501 -350 319 1150 1118 54 -599 -1460 -526 128 1059 -478 399 -65 1503 691 -32 237 1043 777 805 641 -413 160 335 16 -1661 -143 -332 240 -569 328 900000 -2796 853 -209 -2003 730 -516 479 -2449 792 -3270 1324 1232 -167 -597 -386 2630 896 1801 -796 351 -1030 -717 -831 2562 -537 -1398 -1400 -828 737 -236 -1389 -1223 3395 -1370 -492 1707 877 -521 -473 -1667 -389 556 1085 -929 1285 1516 923 11 -1158 -1810 1530 1713 303 1233 1128 1098 330 357 1713 391 -843 1280 -1082 988 -1341 1689 1152 -667 -296 946 -1703 1004 -177 348 2231 584 178 -1017 1548 -1334 -707 -2367 -997 -1663 -1120 -1254 -460 -587 -209 723 638 1206 876 36 605 122 -1470 -490 -205 -460 2046 636 -659 -175 -1122 -151 1688 -338 -1389 -238 -807 -543 471 1635 1583 79 -915 -2323 -841 202 1631 -724 585 -93 2069 967 -47 369 1697 1305 1383 1136 -763 306 651 32 -3322 -280 -634 443 -1038 SS 20201106T133219.0Z 7615.564108 303 1 49.90 2 71.52 132.58 54.95 273.01 0.00 1 0.00 1 0 25 9.150e-02 1.020e-02 1.674e-02 1.974e-03 3.941688e-01 1.017468e-03 4.735614e-03 -6.000000e+00 5.356962e-02 223.96 -2.00 3.51 -2.00 318.63 0.00e+00 4.681938e-04 2.203795e-04 3.271162e-04 -6.000000e+00 2.397065e-03 281.52 -2.00 20.00 -2.00 317.94 0.00e+00 3.115 0.001 302.00 328.00 3 3.3702e+00 2.7535e-03 3.6911e-02 -6.0000e+00 1.3187e-01 1.6183e-02 3.1593e-03 2.0311e-02 -6.0000e+00 1.4332e-01 -1.4717e-03 2.2094e-03 1.0050e-02 -6.0000e+00 8.5585e-02 -5.4204e-03 1.1585e-03 2.9267e-03 -6.0000e+00 3.6452e-02 5.1523e-04 -6.6144e-04 6.0652e-05 3.6043e-05 -6.0000e+00 2.7454e-03 9.4277e-03 1.7628e-05 12 8 8 10 0 0 95.71 22.96 0.26 0.00943 0.00446 32 6 1 5 0 1559.120 25.79 20.00 22.96 21.88 26.8 996.67 5158 64097 -32845 8289 -15127 -23297 45151 -3228 -3243 -19840 -6630 -26449 4542 20480 -3517 -5861 18580 19360 8647 9464 371 -3999 -4241 -7602 -5757 11152 -1614 -8120 -9534 -710 1442 -1633 -7551 -3356 -2436 -5317 -5318 6510 1858 -1614 -1097 -4024 -79 -341 1783 -2677 3295 1383 2499 -310 -1229 -3257 3106 2768 657 2416 823 3389 -153 1683 2661 1906 -845 1224 -671 1392 -933 2262 2502 -1096 209 136 -1117 245 -105 291 2132 879 -503 -464 479 -1392 -1522 -1727 -1128 -1269 -965 -799 -324 -634 -271 720 1067 1179 1366 225 976 -257 -904 -324 -325 -135 806 570 -849 -250 -808 92 454 12 -953 -247 -228 -203 398 849 1376 164 -61 -1568 -578 -68 541 -204 625 110 1575 877 150 488 531 812 346 444 -188 117 120 -2 -1501 -50 -192 -196 -263 181 1393 -1743 284 -611 -1038 1177 -148 -161 -1198 -371 -1979 298 1367 -334 -624 1693 1853 957 1073 47 -530 -591 -1165 -919 1564 -251 -1294 -1513 -109 238 -306 -1599 -692 -487 -1118 -1240 1601 554 -556 -407 -1593 -31 -136 704 -1098 1286 549 998 -131 -557 -1601 1536 1438 359 1335 466 1876 -86 935 1520 1168 -566 845 -472 934 -618 1476 1744 -853 170 114 -940 197 -80 207 1412 585 -358 -362 406 -1287 -1479 -1753 -1190 -1402 -1101 -927 -374 -715 -292 730 1037 1147 1393 249 1162 -329 -1210 -432 -417 -164 941 675 -1057 -323 -1079 126 649 18 -1499 -394 -360 -310 582 1200 1932 237 -91 -2454 -910 -106 826 -305 909 156 2165 1220 218 747 848 1330 580 763 -335 214 225 -4 -2878 -94 -353 -351 -465 SS 20201106T133745.3Z 7615.567885 306 1 38.59 2 70.77 133.71 55.95 273.82 0.00 1 0.00 1 0 25 8.134e-02 1.144e-02 1.902e-02 2.589e-03 3.833062e-01 1.332680e-03 4.612369e-03 -6.000000e+00 4.763146e-02 223.96 -2.00 3.51 -2.00 318.47 0.00e+00 5.681566e-04 2.751080e-04 2.922512e-04 -6.000000e+00 2.131034e-03 281.52 -2.00 20.00 -2.00 317.78 0.00e+00 3.000 0.000 302.00 328.00 3 3.7055e+00 3.5898e-03 3.5658e-02 -6.0000e+00 1.1725e-01 2.8207e-02 4.1029e-03 1.9739e-02 -6.0000e+00 1.2743e-01 -6.2742e-03 2.7970e-03 9.7597e-03 -6.0000e+00 7.6094e-02 -3.0160e-03 1.4610e-03 2.8805e-03 -6.0000e+00 3.2416e-02 4.1400e-04 -3.5936e-04 7.9751e-05 3.5199e-05 -6.0000e+00 2.4407e-03 9.0738e-03 5.0950e-05 12 9 9 12 41 1 98.90 22.96 0.40 0.00907 0.00637 15 4 1 5 0 2400.530 25.79 19.99 22.96 22.04 26.8 997.26 24556 21354 -35588 15499 4488 -25593 40490 5659 -6331 -19717 4130 -33237 20051 21951 -4905 -5002 -4192 -7133 14506 12064 110 1636 -6287 -8316 -3460 16010 -1023 -3943 -9097 -4275 190 861 -7831 -831 18208 -5468 -3340 5645 3537 -2250 -450 -4618 -681 -787 2316 -3362 3953 1552 1823 -43 -2474 -2902 2842 3808 472 2732 1304 2928 47 1780 2040 631 -1385 1860 -764 714 -563 2360 2100 -854 -222 738 -1856 473 -292 264 3122 904 -552 -619 -27 -1307 -1083 -2058 -1161 -1211 -1053 -856 -241 -1041 -310 596 631 1223 1268 72 1344 -133 -970 -195 -562 323 1268 787 -835 -649 -662 -258 780 12 -625 -78 -220 -410 206 881 1605 29 -377 -1417 -651 145 668 -137 371 304 1239 1096 -8 295 864 828 486 415 -148 181 47 -356 -1587 -312 -279 -225 323 824 789 -2227 567 172 -1329 1246 271 -368 -1347 236 -2974 1278 1613 -527 -589 -522 -963 1685 1476 15 227 -982 -1406 -592 2350 -173 -658 -1567 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