File name: Pandora55s1_QueensNY_20201115_L2Fit_fout2c10d20200414p1-8.txt File generation date: 20260625T172652.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: James Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v3d20190723.txt Instrument calibration file used: Pandora55s1_CF_v10d20200414.txt Level 1 file used: Pandora55s1_QueensNY_20201115_L1_smca1c10d20200414p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20201115 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 262 404 Nominal wavelengths inside fitting window [nm]: 305.1379 305.2779 305.4179 305.5579 305.6978 305.8378 305.9778 306.1177 306.2576 306.3976 306.5375 306.6774 306.8172 306.9571 307.0970 307.2369 307.3767 307.5165 307.6564 307.7962 307.9360 308.0758 308.2156 308.3553 308.4951 308.6349 308.7746 308.9143 309.0541 309.1938 309.3335 309.4732 309.6128 309.7525 309.8922 310.0318 310.1715 310.3111 310.4507 310.5903 310.7299 310.8695 311.0091 311.1486 311.2882 311.4277 311.5673 311.7068 311.8463 311.9858 312.1253 312.2648 312.4043 312.5437 312.6832 312.8226 312.9621 313.1015 313.2409 313.3803 313.5197 313.6591 313.7984 313.9378 314.0771 314.2165 314.3558 314.4951 314.6344 314.7737 314.9130 315.0523 315.1915 315.3308 315.4700 315.6092 315.7485 315.8877 316.0269 316.1661 316.3052 316.4444 316.5836 316.7227 316.8618 317.0010 317.1401 317.2792 317.4183 317.5574 317.6964 317.8355 317.9745 318.1136 318.2526 318.3916 318.5306 318.6696 318.8086 318.9476 319.0866 319.2255 319.3645 319.5034 319.6423 319.7812 319.9201 320.0590 320.1979 320.3368 320.4756 320.6145 320.7533 320.8922 321.0310 321.1698 321.3086 321.4474 321.5861 321.7249 321.8636 322.0024 322.1411 322.2798 322.4185 322.5572 322.6959 322.8346 322.9733 323.1119 323.2506 323.3892 323.5278 323.6665 323.8051 323.9436 324.0822 324.2208 324.3594 324.4979 324.6364 324.7750 324.9135 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201115T131147.6Z 7624.549857 96 1 29.25 2 76.56 129.82 80.09 125.31 0.00 1 0.00 1 0 25 7.345e-01 1.968e-02 1.533e-01 5.088e-03 4.674124e-01 2.660073e-03 5.536449e-03 -6.000000e+00 4.286735e-01 223.26 -2.00 3.51 -2.00 319.67 0.00e+00 2.849452e-03 7.919128e-04 5.114124e-04 -6.000000e+00 1.988080e-02 280.43 -2.00 20.00 -2.00 319.04 0.00e+00 4.199 0.001 302.00 328.00 3 3.2941e+00 7.5285e-03 4.8091e-02 -6.0000e+00 1.0533e+00 8.9509e-02 8.9937e-03 2.4768e-02 -6.0000e+00 1.1463e+00 -6.8303e-02 7.3376e-03 1.2178e-02 -6.0000e+00 6.8456e-01 2.6627e-02 3.8070e-03 4.3896e-03 -6.0000e+00 2.9335e-01 1.7742e-04 -2.2589e-03 1.5717e-04 4.8650e-05 -6.0000e+00 2.2284e-02 1.3749e-02 -2.1207e-04 12 9 9 12 33 1 99.85 23.01 0.21 0.01375 -0.00323 10 4 1 5 0 2642.350 25.90 20.00 23.01 13.23 26.2 952.69 43988 900000 -91901 900000 136754 -47485 9533 -20805 70202 -74199 6938 -92340 107668 765148 -25054 -37675 170926 160560 72070 76517 -8147 6325 -30150 -22418 -11179 -530 1347 6795 -26790 29567 27913 -5138 -7587 5293 12347 -13528 989 16976 21656 -5836 -6484 -7843 2738 5995 12161 -4039 16119 13102 5994 -80 -6016 -7813 7107 -3728 768 13383 6181 6379 294 1438 7029 -125 -3896 2633 -2352 3669 -3373 6032 5194 -2169 164 3964 -4459 4441 -819 2003 5884 1289 -2722 -1995 4704 -1577 -491 -3676 -546 -3629 -1021 -2749 304 -1918 -1104 1604 1029 1050 -861 -667 -94 855 -2460 749 -638 120 1482 1188 -1038 -925 526 -460 1668 -211 -1387 54 -949 -1192 -352 1057 1488 334 617 -1668 -616 1460 2006 -327 824 -79 1551 458 -783 344 1418 812 916 285 429 169 263 -481 -822 -325 -1012 -121 -723 511 900000 -4047 900000 678 -1272 165 -531 831 -3484 163 -6192 1371 3796 -1523 -2866 2060 2271 2426 2554 -605 415 -2901 -2144 -1016 -45 110 518 -2786 1957 2115 -598 -979 616 1316 -1875 134 2339 3372 -1322 -1608 -2073 681 1471 2862 -1111 3732 3158 1582 -23 -2000 -2860 2441 -1488 305 4921 2451 2512 120 585 2841 -58 -2045 1393 -1318 1890 -1802 3038 2860 -1397 110 2673 -3188 2827 -511 1128 3029 695 -1634 -1341 3325 -1279 -421 -3384 -517 -3682 -1058 -2940 317 -1975 -1077 1448 898 926 -822 -697 -108 1053 -3257 969 -799 141 1643 1334 -1239 -1156 675 -619 2332 -318 -2219 87 -1544 -1880 -530 1523 2136 497 952 -2699 -1002 2309 3094 -501 1219 -114 2165 651 -1184 553 2381 1417 1640 529 825 337 534 -993 -1707 -663 -2021 -233 -1371 SS 20201115T133715.2Z 7624.567538 105 1 48.50 2 73.00 134.87 76.47 129.99 0.00 1 0.00 1 0 25 1.901e-02 6.443e-03 2.902e-03 4.487e-04 3.917713e-01 2.300835e-04 4.724553e-03 -6.000000e+00 1.109689e-02 223.26 -2.00 3.51 -2.00 318.44 0.00e+00 2.780889e-04 4.681574e-05 2.340798e-04 -6.000000e+00 4.956454e-04 280.43 -2.00 20.00 -2.00 317.77 0.00e+00 3.369 0.001 302.00 328.00 3 2.6196e-01 6.1886e-04 3.8893e-02 -6.0000e+00 2.7284e-02 7.8669e-03 7.0672e-04 2.0080e-02 -6.0000e+00 2.9673e-02 -7.2101e-03 4.7931e-04 9.9464e-03 -6.0000e+00 1.7717e-02 -2.4320e-03 2.5031e-04 2.8643e-03 -6.0000e+00 7.5495e-03 9.2303e-03 -6.2179e-04 1.3730e-05 3.6146e-05 -6.0000e+00 5.7012e-04 9.6417e-03 2.6500e-05 11 8 0 10 0 0 68.96 23.01 0.21 0.00964 0.00497 623 118 1 5 0 76.840 25.90 20.00 23.01 14.35 26.2 958.60 -5214 -3591 -10782 -6505 -6543 -7441 -1772 -3463 -5657 -5695 -3664 -3842 -1000 682 -1791 -1182 2633 925 277 -757 263 370 -598 -693 -650 -324 -1360 -565 192 1248 1207 1209 -1271 -848 339 -373 1 577 -605 -1711 -1257 -1183 -1068 -682 -352 -851 -365 -398 701 954 472 806 1086 869 483 927 212 619 596 1464 1408 1248 625 -454 23 441 699 1660 1215 170 -205 -650 -527 -661 -50 388 687 1413 380 44 -562 -1445 -1409 -1165 -1080 -868 -650 -450 -663 -133 372 573 1479 1610 1417 887 867 -379 -742 -550 -626 -19 826 116 -973 -512 -832 -188 -66 -109 -376 -250 -107 33 689 929 879 585 -206 -852 -643 -347 -317 139 235 409 1408 1152 471 490 59 335 221 324 -227 -241 68 -357 -554 -248 -202 -204 207 -237 -172 -552 -299 -284 -333 -83 -187 -341 -359 -237 -278 -76 61 -188 -137 314 119 38 -108 38 54 -93 -116 -106 -54 -245 -97 32 215 214 239 -278 -187 72 -82 0 169 -198 -650 -485 -481 -447 -288 -149 -363 -154 -169 298 423 226 393 566 480 279 549 129 371 352 860 865 786 433 -320 16 312 473 1131 858 136 -169 -558 -447 -536 -39 291 477 965 283 35 -488 -1331 -1398 -1166 -1153 -941 -741 -525 -771 -149 404 573 1449 1576 1493 1001 1048 -492 -984 -724 -811 -23 962 138 -1199 -667 -1097 -260 -94 -160 -592 -389 -170 49 999 1330 1250 833 -313 -1320 -1012 -538 -477 208 338 584 1919 1589 673 733 95 540 368 545 -406 -439 128 -663 -1034 -453 -366 -368 361 SS 20201115T143334.2Z 7624.606646 152 1 48.36 2 66.29 147.17 69.42 141.33 0.00 1 0.00 1 0 25 9.563e-03 6.583e-03 1.407e-03 4.525e-04 2.889166e-01 2.320253e-04 3.537256e-03 -6.000000e+00 5.585464e-03 223.25 -2.00 3.51 -2.00 317.28 0.00e+00 -7.970988e-05 3.386962e-05 9.836289e-05 -6.000000e+00 2.494050e-04 280.43 -2.00 20.00 -2.00 316.61 0.00e+00 2.469 0.000 302.00 328.00 3 1.2394e+00 6.0647e-04 2.8524e-02 -6.0000e+00 1.3733e-02 4.9679e-03 6.8229e-04 1.4710e-02 -6.0000e+00 1.4934e-02 2.2993e-03 4.1168e-04 7.3052e-03 -6.0000e+00 8.9171e-03 -4.9268e-03 2.0336e-04 2.0899e-03 -6.0000e+00 3.8008e-03 9.4869e-03 -1.8403e-04 1.4030e-05 2.7735e-05 -6.0000e+00 2.8689e-04 9.0307e-03 8.3033e-05 11 8 0 10 0 0 99.99 23.02 0.21 0.00903 0.00765 668 126 1 5 0 71.460 25.90 20.00 23.02 17.83 26.9 978.88 -2125 -3389 -4182 -2577 -1281 -298 278 504 -1366 -1326 28 -126 336 1120 -656 -927 433 438 2 -278 770 804 727 426 251 -333 -483 454 1374 1788 1570 1340 -1383 -785 332 374 103 519 -728 -1478 -1297 -1273 -1187 -955 -463 -1166 -691 -721 478 741 510 670 806 657 577 850 309 757 824 1546 1484 1268 500 -629 -221 182 600 1554 1277 153 -199 -655 -503 -707 -215 345 765 1553 499 238 -634 -1373 -1309 -1038 -1019 -744 -579 -523 -678 -308 297 358 1354 1607 1462 912 863 -296 -667 -549 -560 13 802 196 -898 -406 -830 -127 -66 -20 -336 -340 -148 -45 548 876 946 577 -95 -775 -612 -374 -283 138 279 418 1402 1159 497 534 57 306 174 337 -248 -176 119 -426 -480 -268 -241 -278 160 -238 -405 -493 -277 -127 -29 30 61 -182 -182 4 -19 53 203 -136 -208 101 106 1 -73 202 212 200 116 72 -99 -139 123 381 500 442 413 -464 -261 106 121 37 209 -352 -769 -729 -707 -673 -544 -263 -663 -408 -418 273 433 300 421 537 459 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