File name: Pandora55s1_QueensNY_20210425_L2Fit_fout2c11d20210101p1-8.txt File generation date: 20260625T184224.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v4d20190723.txt Instrument calibration file used: Pandora55s1_CF_v11d20210101.txt Level 1 file used: Pandora55s1_QueensNY_20210425_L1_smca1c11d20210101p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20210425 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 261 404 Nominal wavelengths inside fitting window [nm]: 305.0145 305.1546 305.2946 305.4346 305.5746 305.7145 305.8545 305.9945 306.1344 306.2744 306.4143 306.5542 306.6941 306.8340 306.9739 307.1138 307.2536 307.3935 307.5333 307.6732 307.8130 307.9528 308.0926 308.2324 308.3722 308.5120 308.6517 308.7915 308.9312 309.0710 309.2107 309.3504 309.4901 309.6298 309.7695 309.9091 310.0488 310.1884 310.3281 310.4677 310.6073 310.7469 310.8865 311.0261 311.1657 311.3053 311.4448 311.5844 311.7239 311.8634 312.0029 312.1424 312.2819 312.4214 312.5609 312.7003 312.8398 312.9792 313.1187 313.2581 313.3975 313.5369 313.6763 313.8156 313.9550 314.0944 314.2337 314.3730 314.5124 314.6517 314.7910 314.9303 315.0695 315.2088 315.3481 315.4873 315.6265 315.7658 315.9050 316.0442 316.1834 316.3226 316.4617 316.6009 316.7401 316.8792 317.0183 317.1574 317.2966 317.4357 317.5747 317.7138 317.8529 317.9919 318.1310 318.2700 318.4090 318.5481 318.6871 318.8260 318.9650 319.1040 319.2429 319.3819 319.5208 319.6598 319.7987 319.9376 320.0765 320.2153 320.3542 320.4931 320.6319 320.7708 320.9096 321.0484 321.1872 321.3260 321.4648 321.6036 321.7423 321.8811 322.0198 322.1586 322.2973 322.4360 322.5747 322.7134 322.8520 322.9907 323.1294 323.2680 323.4066 323.5453 323.6839 323.8225 323.9611 324.0996 324.2382 324.3768 324.5153 324.6538 324.7924 324.9309 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210425T180736.7Z 7785.755286 677 1 35.42 2 31.77 216.11 130.77 49.44 0.00 1 0.00 1 0 25 9.059e-03 7.256e-03 2.158e-04 1.462e-04 1.988187e-01 7.757533e-05 2.440194e-03 -6.000000e+00 5.406749e-03 229.45 -2.00 3.51 -2.00 314.97 0.00e+00 1.562648e-05 6.631083e-06 4.045420e-05 -6.000000e+00 2.365631e-04 281.48 -2.00 20.00 -2.00 314.39 0.00e+00 1.176 0.000 302.00 328.00 3 3.7953e-01 1.9932e-04 1.5733e-02 -6.0000e+00 1.3481e-02 4.0896e-03 2.2081e-04 1.0260e-02 -6.0000e+00 1.4591e-02 6.2665e-04 1.2626e-04 5.0476e-03 -6.0000e+00 8.6828e-03 -1.6574e-03 5.4809e-05 1.4062e-03 -6.0000e+00 3.6308e-03 8.9017e-02 -2.7826e-05 4.4569e-06 2.0929e-05 -6.0000e+00 2.7037e-04 1.6021e-03 1.2511e-04 12 9 1 12 1 1 99.96 22.83 0.25 0.00160 0.00139 1372 383 1 5 0 24.760 25.68 20.00 22.83 20.44 28.6 1096.19 -966 -1907 -2933 -3181 -1401 204 1048 1150 912 -661 -87 1214 1174 920 332 -489 -395 160 375 509 -14 960 1348 1017 628 166 -650 -655 573 1666 1586 1698 1532 -942 -614 529 548 610 348 -843 -1547 -1191 -1298 -1248 -951 -868 -1115 -851 -711 386 787 539 808 619 502 530 749 259 578 858 1428 1250 1092 343 -900 -276 51 605 1534 1007 36 -419 -788 -580 -830 -236 303 787 1632 570 118 -743 -1498 -1262 -971 -1052 -805 -612 -600 -775 -308 171 319 1362 1613 1369 894 753 -392 -625 -439 -475 153 985 198 -754 -329 -763 -188 -92 -165 -422 -411 -219 -111 562 899 896 725 -6 -632 -487 -301 -285 257 345 606 1524 1171 517 490 -34 247 210 311 -258 -274 80 -476 -512 -307 -311 -324 12 -311 -637 -1019 -1065 -448 59 303 363 320 -235 -31 428 437 359 146 -224 -190 79 190 251 -7 484 678 528 343 90 -359 -366 297 854 808 859 828 -515 -346 283 298 352 226 -592 -1176 -927 -1046 -1021 -777 -705 -895 -662 -557 293 601 433 658 530 428 463 664 232 512 749 1248 1139 1026 334 -884 -271 48 543 1352 925 35 -433 -816 -595 -847 -230 275 699 1383 512 109 -741 -1581 -1363 -1066 -1195 -944 -754 -735 -946 -370 195 353 1418 1688 1452 1004 874 -485 -786 -544 -570 180 1112 234 -928 -415 -980 -250 -125 -229 -593 -578 -304 -147 721 1116 1102 901 -7 -851 -675 -415 -382 339 447 765 1879 1439 649 632 -45 332 287 428 -365 -395 119 -706 -765 -451 -455 -471 17 SS 20210425T182450.9Z 7785.767256 691 1 51.87 2 33.85 222.83 128.39 53.79 0.00 1 0.00 1 0 25 8.992e-03 6.905e-03 2.644e-04 1.661e-04 2.038444e-01 8.778998e-05 2.488865e-03 -6.000000e+00 5.366613e-03 229.45 -2.00 3.51 -2.00 315.30 0.00e+00 -2.943376e-05 7.999394e-06 3.700058e-05 -6.000000e+00 2.348032e-04 281.48 -2.00 20.00 -2.00 314.70 0.00e+00 1.203 0.000 302.00 328.00 3 9.2456e-01 2.2627e-04 1.6106e-02 -6.0000e+00 1.3380e-02 5.0957e-03 2.5133e-04 1.0503e-02 -6.0000e+00 1.4483e-02 2.4925e-03 1.4356e-04 5.1608e-03 -6.0000e+00 8.6183e-03 -2.7032e-03 6.2950e-05 1.4336e-03 -6.0000e+00 3.6039e-03 4.9685e-02 6.9906e-06 5.0631e-06 2.0573e-05 -6.0000e+00 2.6835e-04 1.6402e-03 1.3269e-04 11 8 0 10 0 0 99.99 22.85 0.24 0.00164 0.00169 2116 400 1 5 0 23.690 25.68 20.00 22.85 21.62 28.6 1100.00 -1034 -1856 -2983 -3362 -1403 132 1146 1188 976 -618 -11 1305 1178 940 336 -402 -561 69 291 516 -107 875 1286 931 609 147 -625 -655 564 1693 1612 1614 1520 -986 -606 495 564 647 329 -855 -1512 -1157 -1337 -1196 -919 -770 -1105 -853 -694 413 749 520 779 609 528 557 799 260 660 885 1475 1296 1116 420 -856 -287 24 618 1523 1017 27 -405 -749 -550 -789 -254 294 726 1617 535 102 -762 -1493 -1218 -968 -1009 -732 -530 -536 -683 -258 180 302 1310 1533 1354 888 757 -357 -613 -410 -509 129 927 192 -772 -301 -727 -147 -48 -95 -333 -344 -177 -87 556 840 869 675 -51 -606 -485 -271 -303 224 272 506 1416 1105 423 425 -81 188 183 278 -250 -232 101 -428 -437 -232 -259 -285 12 -279 -556 -931 -1013 -379 35 301 317 290 -199 -4 416 397 330 133 -165 -243 31 133 241 -51 420 615 460 299 75 -326 -329 279 785 744 783 788 -513 -308 254 295 356 202 -590 -1119 -869 -1042 -945 -725 -604 -857 -642 -531 306 560 409 616 507 435 469 684 226 565 746 1245 1141 1007 407 -831 -281 23 538 1303 941 27 -415 -796 -579 -799 -248 269 631 1341 471 96 -763 -1569 -1301 -1088 -1163 -865 -658 -657 -863 -312 209 331 1361 1547 1434 990 894 -447 -775 -528 -617 150 1073 223 -932 -383 -937 -197 -65 -136 -477 -494 -253 -120 723 1065 1092 850 -66 -817 -673 -373 -421 298 357 652 1725 1343 542 557 -108 255 252 383 -364 -342 154 -647 -664 -347 -388 -413 18 SS 20210425T185835.1Z 7785.790684 722 1 52.18 2 38.63 234.14 123.34 61.54 0.00 1 0.00 1 0 25 9.134e-03 7.114e-03 2.084e-04 1.276e-04 2.185665e-01 6.747857e-05 2.670587e-03 -6.000000e+00 5.451846e-03 229.46 -2.00 3.51 -2.00 315.42 0.00e+00 4.550464e-06 6.289751e-06 4.693165e-05 -6.000000e+00 2.385286e-04 281.48 -2.00 20.00 -2.00 314.81 0.00e+00 1.279 0.000 302.00 328.00 3 3.3217e-01 1.7412e-04 1.7192e-02 -6.0000e+00 1.3593e-02 4.4075e-03 1.9348e-04 1.1269e-02 -6.0000e+00 1.4713e-02 7.0133e-05 1.1052e-04 5.5384e-03 -6.0000e+00 8.7551e-03 -1.5871e-03 4.8575e-05 1.5409e-03 -6.0000e+00 3.6612e-03 8.1118e-02 -3.2224e-05 3.8868e-06 2.2189e-05 -6.0000e+00 2.7260e-04 1.2574e-03 1.2570e-04 11 8 0 10 0 0 99.98 22.85 0.23 0.00126 0.00102 2523 477 1 5 0 19.850 25.68 20.00 22.85 22.09 28.6 1100.00 -1122 -1969 -3144 -3357 -1616 28 849 1039 769 -747 -185 1123 1145 800 426 -385 -336 -348 430 546 -21 899 1387 1077 634 265 -622 -607 598 1808 1569 1698 1555 -909 -649 467 573 593 361 -820 -1521 -1185 -1268 -1179 -875 -759 -1057 -811 -700 381 743 564 813 624 484 523 757 261 604 862 1420 1265 1128 402 -824 -261 95 588 1496 1034 37 -421 -800 -558 -820 -226 318 762 1586 575 152 -734 -1485 -1277 -996 -1079 -776 -636 -586 -757 -303 171 312 1360 1595 1360 907 781 -388 -634 -450 -486 128 992 190 -762 -321 -746 -186 -89 -158 -394 -391 -210 -90 592 904 890 732 -19 -648 -494 -305 -287 243 319 577 1510 1178 531 515 -39 245 227 316 -239 -252 86 -477 -505 -306 -297 -308 28 -298 -581 -905 -1001 -433 7 207 276 228 -223 -56 335 363 284 161 -161 -140 -150 189 247 -10 418 643 516 303 133 -317 -299 289 821 713 814 799 -471 -331 239 283 327 223 -544 -1089 -906 -962 -909 -674 -581 -801 -625 -523 277 546 436 637 515 398 440 648 226 517 727 1197 1112 1021 377 -808 -248 87 517 1297 932 36 -425 -838 -578 -817 -216 295 670 1334 492 140 -725 -1550 -1363 -1119 -1249 -923 -770 -726 -934 -369 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