File name: Pandora55s1_QueensNY_20210626_L2Fit_fout2c11d20210101p1-8.txt File generation date: 20260625T191200.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora55_OF_v4d20190723.txt Instrument calibration file used: Pandora55s1_CF_v11d20210101.txt Level 1 file used: Pandora55s1_QueensNY_20210626_L1_smca1c11d20210101p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20210626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 261 404 Nominal wavelengths inside fitting window [nm]: 305.0145 305.1546 305.2946 305.4346 305.5746 305.7145 305.8545 305.9945 306.1344 306.2744 306.4143 306.5542 306.6941 306.8340 306.9739 307.1138 307.2536 307.3935 307.5333 307.6732 307.8130 307.9528 308.0926 308.2324 308.3722 308.5120 308.6517 308.7915 308.9312 309.0710 309.2107 309.3504 309.4901 309.6298 309.7695 309.9091 310.0488 310.1884 310.3281 310.4677 310.6073 310.7469 310.8865 311.0261 311.1657 311.3053 311.4448 311.5844 311.7239 311.8634 312.0029 312.1424 312.2819 312.4214 312.5609 312.7003 312.8398 312.9792 313.1187 313.2581 313.3975 313.5369 313.6763 313.8156 313.9550 314.0944 314.2337 314.3730 314.5124 314.6517 314.7910 314.9303 315.0695 315.2088 315.3481 315.4873 315.6265 315.7658 315.9050 316.0442 316.1834 316.3226 316.4617 316.6009 316.7401 316.8792 317.0183 317.1574 317.2966 317.4357 317.5747 317.7138 317.8529 317.9919 318.1310 318.2700 318.4090 318.5481 318.6871 318.8260 318.9650 319.1040 319.2429 319.3819 319.5208 319.6598 319.7987 319.9376 320.0765 320.2153 320.3542 320.4931 320.6319 320.7708 320.9096 321.0484 321.1872 321.3260 321.4648 321.6036 321.7423 321.8811 322.0198 322.1586 322.2973 322.4360 322.5747 322.7134 322.8520 322.9907 323.1294 323.2680 323.4066 323.5453 323.6839 323.8225 323.9611 324.0996 324.2382 324.3768 324.5153 324.6538 324.7924 324.9309 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210626T114646.7Z 7847.490818 239 1 50.40 2 66.13 79.02 96.84 242.85 0.00 1 0.00 1 0 17 4.228e-02 8.541e-03 1.015e-02 2.045e-03 3.209746e-01 1.076578e-03 3.756823e-03 -6.000000e+00 2.556319e-02 232.90 -2.00 3.51 -2.00 318.08 0.00e+00 3.143325e-04 1.942541e-04 1.449099e-04 -6.000000e+00 1.133533e-03 287.76 -2.00 20.00 -2.00 317.24 0.00e+00 2.452 0.000 302.00 328.00 3 4.1433e+00 2.9152e-03 2.9851e-02 -6.0000e+00 6.4143e-02 3.4333e-02 3.2975e-03 1.6946e-02 -6.0000e+00 6.9166e-02 9.7505e-03 2.0659e-03 8.1457e-03 -6.0000e+00 4.1199e-02 -8.3560e-03 1.0365e-03 2.2793e-03 -6.0000e+00 1.7219e-02 4.7892e-04 5.7862e-04 6.3584e-05 2.6907e-05 -6.0000e+00 1.2632e-03 3.4037e-03 2.4268e-04 11 8 0 10 0 0 100.00 22.79 0.17 0.00340 0.00775 77 15 1 5 0 654.400 25.68 20.00 22.79 29.05 29.4 1100.00 1654 3155 24502 -20947 -2526 3469 -8333 14367 1950 -3086 -11334 -1166 -7430 -15758 11728 -3894 -6835 -758 7378 4273 2747 2259 3030 -3428 -578 -1077 8221 -5101 -1132 -3452 2738 1893 -352 -5498 39 9328 -1421 -1200 2146 348 -2900 675 -3283 -1934 -1152 1356 -2264 496 -336 1463 -249 -645 -163 1035 2766 -462 1933 927 2016 1397 1491 2654 1453 -436 212 -1374 1020 50 1961 215 -418 -316 49 -691 592 -134 584 1125 1371 -45 -700 18 -1357 -1270 -1332 -1144 -880 -428 -1133 -270 -61 366 134 1300 1050 1478 370 103 -284 -597 -385 -434 42 1222 111 -1112 -301 -826 -44 623 367 -734 -163 -242 -668 372 732 1003 512 149 -1072 -368 330 322 -111 144 175 1115 721 48 428 292 536 258 552 -165 208 271 -252 -621 -660 -238 -373 51 97 206 1382 -1758 -168 207 -565 872 147 -261 -1064 -103 -760 -1984 1319 -565 -1097 -121 1145 711 478 400 539 -674 -118 -231 1650 -1125 -231 -701 542 407 -84 -1453 10 2102 -362 -340 688 131 -1251 303 -1579 -939 -560 649 -1111 235 -160 686 -122 -335 -90 592 1630 -287 1206 589 1261 871 935 1708 1007 -327 163 -1067 741 35 1371 163 -347 -278 44 -618 507 -109 438 789 949 -33 -571 16 -1305 -1281 -1401 -1259 -1016 -509 -1379 -326 -71 407 140 1282 1035 1523 414 125 -368 -803 -514 -555 50 1424 133 -1408 -395 -1125 -62 901 556 -1162 -259 -380 -1008 531 1004 1373 722 220 -1654 -573 508 486 -164 206 242 1495 974 68 635 450 845 416 909 -283 368 490 -462 -1145 -1203 -422 -646 87 SS 20210626T115856.3Z 7847.499263 245 1 48.66 2 63.86 80.81 98.80 244.65 0.00 1 0.00 1 0 25 1.010e-02 6.449e-03 2.104e-03 6.315e-04 2.974374e-01 3.331257e-04 3.542059e-03 -6.000000e+00 6.098730e-03 232.90 -2.00 3.51 -2.00 317.37 0.00e+00 5.761098e-06 4.933283e-05 1.119412e-04 -6.000000e+00 2.706009e-04 287.76 -2.00 20.00 -2.00 316.54 0.00e+00 2.256 0.000 302.00 328.00 3 2.2156e+00 8.8936e-04 2.7553e-02 -6.0000e+00 1.5303e-02 2.7320e-02 9.9720e-04 1.5706e-02 -6.0000e+00 1.6506e-02 -4.7771e-04 5.9332e-04 7.5667e-03 -6.0000e+00 9.8310e-03 -4.3757e-03 2.8723e-04 2.0562e-03 -6.0000e+00 4.1051e-03 4.1668e-03 -1.0659e-04 1.9469e-05 2.5447e-05 -6.0000e+00 3.0175e-04 5.3804e-03 9.0031e-05 11 8 0 10 0 0 99.99 22.80 0.19 0.00538 0.00458 397 75 1 5 0 122.540 25.68 19.99 22.80 30.07 29.7 1100.00 -2352 -1602 -2053 -4844 -2456 -296 -680 1467 1184 -1712 -421 359 380 -2008 2008 -725 -787 -806 549 479 -38 962 846 575 -104 248 14 -759 76 1228 1919 1777 1815 -2059 -317 754 660 360 827 -891 -1635 -1145 -1564 -1187 -991 -371 -1253 -487 -659 556 501 550 637 871 793 465 979 397 796 878 1521 1304 1312 286 -741 -222 168 661 1533 1108 -141 -231 -665 -447 -632 -120 512 822 1597 413 41 -604 -1409 -1212 -1032 -1065 -743 -599 -569 -658 -200 260 449 1441 1497 1446 823 841 -390 -588 -479 -516 57 929 -39 -759 -255 -757 -108 -79 -116 -564 -308 -195 -113 593 833 864 597 -40 -743 -454 -255 -232 164 218 513 1425 986 312 459 -62 232 145 353 -238 -115 154 -411 -440 -309 -184 -195 93 -226 -172 -231 -547 -250 -28 -65 152 138 -221 -55 48 55 -320 354 -147 -172 -185 122 111 -9 231 206 146 -28 71 4 -215 20 313 497 498 555 -691 -104 236 213 132 338 -415 -867 -619 -885 -683 -573 -213 -721 -274 -365 304 282 330 409 563 537 326 699 288 571 621 1077 967 1002 238 -621 -182 134 497 1153 912 -125 -211 -631 -419 -591 -103 414 639 1208 322 36 -573 -1414 -1245 -1119 -1186 -880 -718 -698 -801 -241 291 476 1468 1510 1553 943 1029 -510 -778 -626 -656 69 1076 -47 -949 -337 -1013 -151 -113 -170 -873 -481 -295 -165 827 1139 1176 818 -57 -1121 -675 -387 -343 240 304 704 1862 1300 424 669 -92 356 220 559 -387 -196 261 -716 -771 -532 -315 -320 149 SS 20210626T120346.2Z 7847.502619 248 1 45.68 2 62.95 81.53 99.59 245.35 0.00 1 0.00 1 0 25 9.283e-03 6.317e-03 1.162e-03 3.732e-04 2.887249e-01 1.971364e-04 3.439986e-03 -6.000000e+00 5.608319e-03 232.90 -2.00 3.51 -2.00 317.22 0.00e+00 -6.320411e-05 2.804699e-05 9.689565e-05 -6.000000e+00 2.488279e-04 287.76 -2.00 20.00 -2.00 316.39 0.00e+00 2.187 0.000 302.00 328.00 3 1.2034e+00 5.2469e-04 2.6714e-02 -6.0000e+00 1.4072e-02 1.7294e-02 5.8711e-04 1.5223e-02 -6.0000e+00 1.5178e-02 -1.3304e-03 3.4708e-04 7.3362e-03 -6.0000e+00 9.0403e-03 -3.4122e-03 1.6673e-04 1.9887e-03 -6.0000e+00 3.7753e-03 1.2498e-02 -1.0619e-04 1.1514e-05 2.4998e-05 -6.0000e+00 2.7746e-04 4.6272e-03 8.0125e-05 10 0 0 10 0 0 99.99 22.79 0.19 0.00463 0.00383 1101 208 1 5 0 41.290 25.68 20.00 22.79 30.63 29.6 1100.00 -2076 -2076 -3212 -3779 -2494 -1024 35 858 760 -1232 -360 542 564 -144 836 -635 -586 -3 318 587 -320 1133 973 959 282 -110 -491 -904 429 1285 1565 1347 1482 -1477 -617 255 349 359 469 -754 -1417 -1091 -1299 -1059 -988 -660 -1113 -647 -701 511 753 583 764 675 713 611 843 279 772 917 1504 1392 1268 441 -715 -155 104 651 1515 1019 79 -317 -718 -464 -738 -95 445 800 1512 362 97 -739 -1411 -1251 -1048 -1030 -654 -495 -535 -644 -124 337 417 1349 1521 1338 918 736 -336 -593 -485 -530 70 800 59 -799 -363 -760 -160 -63 -132 -390 -294 -159 -95 607 787 858 616 -88 -669 -451 -347 -305 223 175 552 1373 1025 338 451 -23 212 147 263 -271 -142 181 -406 -378 -233 -214 -237 59 -216 -242 -396 -456 -274 -104 4 97 96 -170 -51 77 87 -24 157 -136 -134 -1 79 151 -86 302 263 269 79 -33 -148 -265 126 361 447 388 464 -502 -206 82 115 134 194 -373 -751 -621 -772 -641 -601 -400 -673 -382 -408 292 442 365 483 452 499 441 623 199 572 670 1100 1009 993 356 -609 -129 85 499 1160 853 70 -292 -685 -437 -699 -82 367 604 1172 286 86 -706 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