File name: Pandora55s1_QueensNY_20211206_L2Fit_fwvt1c19d20211111p1-8.txt
File generation date: 20250606T105005.8Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c19p1-8
Local principal investigator: Lukas Valin
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 55
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora55_OF_v4d20190723.txt
Instrument calibration file used: Pandora55s1_CF_v19d20211111.txt
Level 1 file used: Pandora55s1_QueensNY_20211206_L1_smca1c19d20211111p1-8.txt
Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124)
Short location name: QueensNY
Country of location: USA
Location latitude [deg]: 40.7361
Location longitude [deg]: -73.8215
Location altitude [m]: 25
Local noon date: 20211206
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1689 1839
Nominal wavelengths inside fitting window [nm]: 492.1050 492.2254 492.3459 492.4663 492.5867 492.7071 492.8275 492.9478 493.0682 493.1885 493.3088 493.4291 493.5493 493.6696 493.7898 493.9101 494.0303 494.1505 494.2706 494.3908 494.5109 494.6310 494.7511 494.8712 494.9913 495.1114 495.2314 495.3514 495.4714 495.5914 495.7114 495.8313 495.9513 496.0712 496.1911 496.3110 496.4309 496.5507 496.6706 496.7904 496.9102 497.0300 497.1498 497.2695 497.3893 497.5090 497.6287 497.7484 497.8681 497.9877 498.1073 498.2270 498.3466 498.4662 498.5857 498.7053 498.8248 498.9444 499.0639 499.1834 499.3028 499.4223 499.5417 499.6612 499.7806 499.8999 500.0193 500.1387 500.2580 500.3773 500.4966 500.6159 500.7352 500.8545 500.9737 501.0929 501.2121 501.3313 501.4505 501.5697 501.6888 501.8079 501.9270 502.0461 502.1652 502.2843 502.4033 502.5223 502.6413 502.7603 502.8793 502.9982 503.1172 503.2361 503.3550 503.4739 503.5928 503.7116 503.8305 503.9493 504.0681 504.1869 504.3057 504.4244 504.5432 504.6619 504.7806 504.8993 505.0179 505.1366 505.2552 505.3739 505.4925 505.6111 505.7296 505.8482 505.9667 506.0852 506.2037 506.3222 506.4407 506.5592 506.6776 506.7960 506.9144 507.0328 507.1512 507.2695 507.3879 507.5062 507.6245 507.7428 507.8610 507.9793 508.0975 508.2157 508.3340 508.4521 508.5703 508.6885 508.8066 508.9247 509.0428 509.1609 509.2790 509.3970 509.5150 509.6330 509.7510 509.8690 509.9870
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20211206T163901.9Z 8010.693772 190 1 0.55 2 63.33 178.07 76.75 144.55 0.00 1 0.00 1 0 15 3.133e-03 3.131e-03 1.918e-03 1.916e-03 3.020780e+03 1.106651e+02 2.217630e+02 -6.000000e+00 1.654424e+02 278.23 -2.00 20.00 -2.00 505.28 0.00e+00 5.971427e-04 5.134647e-05 3.739515e-05 -6.000000e+00 8.569228e-05 278.23 -2.00 20.00 -2.00 500.54 0.00e+00 8.119308e-02 3.685380e-02 2.289177e-02 -6.000000e+00 6.063459e-02 222.95 -2.00 3.51 -2.00 502.12 0.00e+00 2.216 0.000 489.00 513.00 1 3.2708e+00 2.8173e-03 3.8166e-03 -6.0000e+00 4.6381e-03 -8.1838e-03 7.3041e-04 5.7509e-04 -6.0000e+00 1.2098e-03 5.3327e-02 6.8771e-04 1.6910e-04 3.2122e-05 -6.0000e+00 2.8501e-04 -3.0367e-03 -1.1235e-05 12 1 1 12 1 1 999.00 22.71 0.99 -0.00304 0.00173 2 71 1 4 0 124.830 25.58 20.00 22.71 18.57 30.5 1011.89 -234 -306 283 222 350 228 531 170 410 140 235 -103 -176 -380 -219 -106 -153 -186 101 618 30 290 -122 160 126 257 399 -88 648 -432 -572 -62 -119 -287 462 509 -72 -255 -83 -439 -342 1 -307 415 89 376 89 -136 -184 -327 -486 -816 -607 -346 -233 -229 391 -151 372 98 379 545 339 534 150 -62 -380 -85 -275 -369 -285 -674 305 -213 78 120 12 -257 -335 -480 -286 -507 -2 -115 85 -201 149 -180 -211 267 -60 51 -137 169 602 -274 -145 117 -361 -461 -325 -254 -240 -446 -82 91 -59 -175 -186 -511 -58 59 273 318 319 733 179 43 303 340 -52 40 350 5 412 478 -215 256 397 -221 287 289 -41 -182 -165 -286 21 311 -132 92 459 512 55 -101 92 225 -84 39 -406 -385 -335 -226 -298 284 223 360 236 549 177 424 145 240 -106 -177 -380 -218 -106 -156 -192 105 645 31 303 -126 166 131 268 412 -92 658 -436 -570 -62 -121 -297 481 531 -74 -261 -86 -450 -350 1 -315 429 91 387 92 -140 -189 -327 -478 -798 -587 -338 -231 -231 394 -154 377 100 384 554 347 545 152 -62 -381 -84 -269 -362 -277 -662 300 -211 78 118 12 -249 -322 -461 -276 -494 -2 -112 83 -197 146 -177 -207 262 -59 50 -138 170 598 -273 -141 112 -345 -439 -307 -241 -231 -443 -82 91 -58 -172 -183 -505 -57 59 272 320 323 743 181 44 305 342 -52 39 343 5 408 474 -212 251 392 -217 282 280 -40 -174 -157 -276 21 303 -131 91 455 510 55 -101 92 227 -84 38 -396 -372 -326
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SQ 20211206T164757.2Z 8010.699967 196 1 14.37 2 63.31 180.37 75.82 146.29 0.00 1 0.00 1 0 15 2.406e-03 2.397e-03 1.888e-04 1.885e-04 3.153024e+03 1.095199e+01 2.363714e+02 -6.000000e+00 1.270607e+02 278.22 -2.00 20.00 -2.00 505.29 0.00e+00 5.837361e-04 5.051065e-06 3.762948e-05 -6.000000e+00 6.581082e-05 278.22 -2.00 20.00 -2.00 500.53 0.00e+00 8.377569e-02 3.632056e-03 2.249294e-02 -6.000000e+00 4.656181e-02 222.95 -2.00 3.51 -2.00 502.11 0.00e+00 2.214 0.000 489.00 513.00 1 2.6545e+00 2.7749e-04 3.8065e-03 -6.0000e+00 3.5617e-03 -7.9542e-03 7.1935e-05 5.8026e-04 -6.0000e+00 9.2890e-04 9.8763e-02 4.8348e-04 1.6668e-05 3.3761e-05 -6.0000e+00 2.1887e-04 -4.4227e-03 5.0097e-06 10 0 0 10 0 0 99.99 22.71 0.92 -0.00442 -0.00107 551 104 1 4 0 25.650 25.58 20.00 22.71 19.13 30.7 1015.80 -533 -235 -115 378 469 386 483 369 414 229 -120 -93 -140 -265 -274 -122 64 -82 223 371 114 135 135 15 160 249 14 -143 95 -344 -573 -158 -126 -156 238 338 33 -134 -121 -115 -125 -24 58 161 231 262 214 52 -194 -193 -479 -619 -488 -469 -331 5 190 185 165 94 113 143 196 166 121 112 26 -246 -272 -102 -300 -296 -114 -180 -52 139 43 -259 -322 -142 -408 -314 21 -109 -95 -13 -31 -13 -91 -39 171 18 -9 310 337 55 73 -100 -219 -319 -464 -246 -289 -417 -22 79 -132 -86 -181 -370 -171 18 158 229 406 395 305 198 399 152 28 180 65 -197 137 239 -21 224 217 -110 75 216 -117 -125 122 -140 -156 221 254 160 345 224 191 212 128 45 -110 -95 -314 -404 -284 -516 -232 -115 380 482 397 505 389 433 236 -122 -95 -142 -266 -274 -123 66 -85 234 384 118 140 141 16 168 260 14 -147 97 -348 -572 -158 -127 -160 249 355 35 -138 -123 -116 -127 -24 60 168 242 270 224 54 -197 -195 -470 -606 -473 -459 -327 5 193 190 169 95 115 147 203 171 124 113 26 -247 -269 -99 -291 -288 -113 -176 -51 136 42 -250 -308 -135 -392 -304 20 -107 -92 -13 -31 -13 -90 -39 170 18 -9 311 335 55 71 -97 -207 -297 -439 -231 -275 -406 -22 79 -131 -84 -178 -359 -169 18 157 229 407 398 310 202 404 153 27 178 63 -194 136 237 -21 222 215 -109 73 209 -112 -120 117 -136 -152 218 250 159 345 225 190 211 128 44 -110 -92 -306 -390 -275
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