File name: Pandora55s1_QueensNY_20220305_L2Fit_fout2c19d20211111p1-8.txt File generation date: 20250606T113046.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 55 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora55_OF_v4d20190723.txt Instrument calibration file used: Pandora55s1_CF_v19d20211111.txt Level 1 file used: Pandora55s1_QueensNY_20220305_L1_smca1c19d20211111p1-8.txt Full location name: Queens College NYSDEC (USEPA AQS ID 36-081-0124) Short location name: QueensNY Country of location: USA Location latitude [deg]: 40.7361 Location longitude [deg]: -73.8215 Location altitude [m]: 25 Local noon date: 20220305 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 261 404 Nominal wavelengths inside fitting window [nm]: 305.0379 305.1778 305.3178 305.4578 305.5977 305.7376 305.8776 306.0175 306.1574 306.2973 306.4372 306.5770 306.7169 306.8567 306.9966 307.1364 307.2762 307.4160 307.5558 307.6956 307.8354 307.9752 308.1149 308.2547 308.3944 308.5341 308.6738 308.8135 308.9532 309.0929 309.2326 309.3723 309.5119 309.6515 309.7912 309.9308 310.0704 310.2100 310.3496 310.4892 310.6287 310.7683 310.9079 311.0474 311.1869 311.3264 311.4659 311.6054 311.7449 311.8844 312.0239 312.1633 312.3028 312.4422 312.5816 312.7210 312.8604 312.9998 313.1392 313.2786 313.4179 313.5573 313.6966 313.8360 313.9753 314.1146 314.2539 314.3932 314.5324 314.6717 314.8110 314.9502 315.0895 315.2287 315.3679 315.5071 315.6463 315.7855 315.9246 316.0638 316.2030 316.3421 316.4812 316.6204 316.7595 316.8986 317.0377 317.1767 317.3158 317.4549 317.5939 317.7329 317.8720 318.0110 318.1500 318.2890 318.4280 318.5669 318.7059 318.8449 318.9838 319.1227 319.2617 319.4006 319.5395 319.6784 319.8172 319.9561 320.0950 320.2338 320.3726 320.5115 320.6503 320.7891 320.9279 321.0667 321.2054 321.3442 321.4830 321.6217 321.7604 321.8991 322.0379 322.1766 322.3152 322.4539 322.5926 322.7312 322.8699 323.0085 323.1471 323.2857 323.4243 323.5629 323.7015 323.8401 323.9786 324.1172 324.2557 324.3943 324.5328 324.6713 324.8098 324.9483 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220305T121933.1Z 8099.513578 64 1 50.82 2 80.35 106.57 98.82 76.47 0.00 1 0.00 1 0 25 5.412e-01 2.429e-02 1.470e-01 4.654e-03 7.857501e-01 2.648821e-03 8.712011e-03 -6.000000e+00 3.287718e-01 225.73 -2.00 3.51 -2.00 321.35 0.00e+00 6.848093e-03 1.275752e-03 2.078657e-03 -6.000000e+00 1.530457e-02 276.46 -2.00 20.00 -2.00 320.87 0.00e+00 5.691 0.003 302.00 328.00 3 1.9145e+00 8.7620e-03 7.1977e-02 -6.0000e+00 8.2087e-01 4.1314e-01 1.2060e-02 4.8069e-02 -6.0000e+00 9.0030e-01 -5.1779e-01 1.2251e-02 2.2420e-02 -6.0000e+00 5.2739e-01 2.0928e-01 5.8051e-03 1.0488e-02 -6.0000e+00 2.1495e-01 1.1338e-04 -2.3855e-03 1.3362e-04 1.0943e-04 -6.0000e+00 1.6704e-02 2.9534e-03 -8.6362e-05 12 8 8 10 0 0 94.37 22.70 0.36 0.00295 -0.01497 35 7 1 5 0 1451.860 25.58 19.99 22.70 5.72 29.8 1045.66 -152149 -92835 900000 -228128 -11198 900000 -214959 900000 900000 -133390 -219962 -137375 -159806 -129465 900000 -31586 -125732 900000 900000 900000 900000 16446 25519 -67409 -52995 -44765 900000 -57634 -36556 -65838 20087 107959 10197 -47594 41344 900000 7546 -13967 116482 48034 9920 63136 -13496 6971 29264 138601 -8913 55739 32414 45335 16143 7242 -2323 53906 52742 18312 42894 23262 28841 9841 13998 27426 9802 -7374 23222 -3504 16562 -4315 4796 8422 -1089 2959 8429 -2945 16336 1954 7304 15603 74 -283 -6653 5181 1684 150 -5368 -1358 -4174 -1995 -4144 -525 -2670 -2564 900 333 -2732 -1371 -3303 -1937 -453 -1987 -487 -718 605 2873 60 93 -2082 -678 536 2364 428 -2677 -769 -924 -868 -101 644 2485 126 503 -1329 744 1475 3258 -636 146 317 1377 1 -680 518 1465 1301 772 858 -543 353 -54 -657 -973 -349 -468 56 -813 -1754 -719 900000 -6887 -51 900000 -5135 900000 900000 -1808 -7154 -2300 -4120 -3267 900000 -493 -5493 900000 900000 900000 900000 241 344 -2291 -1666 -1356 900000 -1972 -1029 -2607 412 1169 330 -2901 1111 900000 281 -717 2073 1924 641 2709 -1252 553 1926 3357 -876 3130 2383 3171 1619 877 -340 5095 5399 2688 5184 3370 3906 1548 2122 3878 1821 -1816 4751 -955 3760 -1205 1311 2493 -390 1092 3005 -1127 4903 611 2005 3881 23 -99 -2907 2337 876 86 -3392 -872 -2880 -1405 -3019 -366 -1829 -1666 542 202 -1805 -1007 -2820 -1866 -478 -2254 -544 -760 582 2553 54 89 -2123 -718 602 2847 577 -4015 -1193 -1450 -1337 -150 933 3582 192 790 -2155 1171 2239 4737 -930 207 437 1860 1 -1074 895 2710 2545 1582 1841 -1226 820 -127 -1572 -2324 -807 -1039 119 -1684 SS 20220305T122718.2Z 8099.518961 68 1 35.46 2 78.94 107.91 97.41 77.72 0.00 1 0.00 1 0 17 6.265e-01 1.420e-02 1.727e-01 3.188e-03 7.099381e-01 1.750111e-03 8.014912e-03 -6.000000e+00 3.748152e-01 225.73 -2.00 3.51 -2.00 320.88 0.00e+00 4.369791e-03 7.550556e-04 1.773841e-03 -6.000000e+00 1.706530e-02 276.46 -2.00 20.00 -2.00 320.38 0.00e+00 5.030 0.002 302.00 328.00 3 1.6880e+00 5.4743e-03 6.3328e-02 -6.0000e+00 9.2844e-01 1.5558e-01 7.3234e-03 4.0814e-02 -6.0000e+00 1.0124e+00 -1.6495e-01 7.5059e-03 1.9600e-02 -6.0000e+00 5.9886e-01 5.8857e-02 3.6545e-03 7.7378e-03 -6.0000e+00 2.4812e-01 3.0038e-04 -1.9325e-03 9.1457e-05 8.0233e-05 -6.0000e+00 1.9165e-02 3.5291e-03 -8.4783e-05 12 9 9 12 1 1 99.02 22.70 0.30 0.00353 -0.01099 45 12 1 5 0 766.860 25.58 20.00 22.70 5.97 29.9 1047.51 -85781 -132520 900000 -213871 -161709 900000 -226875 900000 -102413 -55491 -211933 -106914 -136600 -95397 900000 -51941 -92165 900000 368503 114964 241967 -20171 27517 -64474 -30884 -49590 900000 -24350 -25851 -27213 -41403 52365 -18300 -24123 -4824 173771 -20083 -2624 27573 8595 833 9082 -4049 -629 10563 18110 -93 9303 13708 11501 7019 -65 -783 13722 12427 8914 10203 8872 4315 2758 2848 7834 3831 -226 7133 -1573 5565 -2026 3429 -331 676 -787 2885 -2329 3761 -335 1440 5314 -1832 1947 -3144 2488 -1655 -832 -2981 -845 -2733 -1054 -2214 -810 -445 -779 1166 -343 997 71 -74 -166 -314 -708 -458 -420 624 1973 -282 -530 -948 -944 -346 997 94 -1424 -365 -494 -294 284 984 1439 446 -419 -527 -108 635 1095 -177 261 371 1471 151 -9 499 548 665 561 133 -674 47 -44 -152 -829 46 -340 176 -379 -387 -1132 900000 -4399 -1946 900000 -5138 900000 -893 -335 -6100 -1295 -2727 -1670 900000 -940 -2815 900000 1145 644 752 -433 386 -2293 -872 -1766 900000 -703 -763 -864 -1732 1098 -875 -1337 -229 1517 -1139 -145 1377 606 72 801 -428 -67 1041 1710 -11 1016 1510 1383 959 -11 -142 2361 2320 1803 2121 1884 945 600 626 1739 980 -67 2172 -535 1763 -696 1192 -132 297 -373 1351 -1110 1605 -137 536 1857 -721 837 -1635 1398 -1068 -572 -2193 -643 -2213 -873 -1875 -671 -356 -594 837 -247 748 59 -69 -176 -363 -864 -555 -483 659 1963 -288 -566 -1064 -1106 -426 1311 136 -2213 -585 -794 -462 431 1454 2135 686 -671 -861 -174 995 1669 -266 381 527 2051 221 -14 857 1003 1275 1114 277 -1462 104 -99 -347 -1894 103 -729 362 -768 SS 20220305T123323.2Z 8099.523186 71 1 49.29 2 77.85 108.98 96.30 78.68 0.00 1 0.00 1 0 25 5.358e-01 9.601e-03 1.330e-01 1.642e-03 6.632909e-01 8.759383e-04 7.606074e-03 -6.000000e+00 3.163782e-01 225.73 -2.00 3.51 -2.00 320.54 0.00e+00 5.091516e-03 3.421602e-04 1.757555e-03 -6.000000e+00 1.369608e-02 276.46 -2.00 20.00 -2.00 320.02 0.00e+00 4.611 0.002 302.00 328.00 3 1.2300e+00 2.6413e-03 5.8514e-02 -6.0000e+00 7.8434e-01 1.0126e-01 3.3873e-03 3.8253e-02 -6.0000e+00 8.5359e-01 -8.6763e-02 3.3579e-03 1.7914e-02 -6.0000e+00 5.0569e-01 2.5341e-02 1.6772e-03 7.8826e-03 -6.0000e+00 2.1035e-01 7.4104e-04 -1.9816e-03 4.6698e-05 7.2669e-05 -6.0000e+00 1.6243e-02 3.6930e-03 -9.5926e-05 12 8 8 10 0 0 83.64 22.71 0.20 0.00369 -0.01120 135 26 1 5 0 365.010 25.58 19.99 22.71 6.20 29.9 1049.04 -111718 29790 502052 -112178 -99004 57557 -139409 900000 -84321 -88638 -115300 -99453 -59891 -59682 110307 -23832 -30566 -114255 50954 16599 9423 -9840 -15329 -19067 -26745 -4670 28402 -3707 -24900 -18156 -10054 11657 -5130 -13136 1653 25168 -672 -8365 12979 -1395 -753 82 -2460 -1325 1813 8932 -3035 6250 1511 9645 1499 2490 776 7131 4840 2619 3047 1086 1949 148 2329 3244 3959 -36 3366 -575 2739 527 1454 1647 -345 -160 -533 -807 110 225 13 2548 749 252 -831 325 -958 -1520 -1938 -1803 -951 -1208 -900 -564 3 215 698 1065 783 909 34 664 -650 -367 -392 65 370 1320 -97 -996 -453 -895 52 89 -38 -803 -182 -286 -16 549 843 1150 222 -237 -758 -251 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