File name: Pandora224s1_QuezonCity_20260606_L2Fit_fwvt1c2d20220621p1-8.txt File generation date: 20260609T040052.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Ellison Castro Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 224 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora224_OF_v2d20220531.txt Instrument calibration file used: Pandora224s1_CF_v2d20220621.txt Level 1 file used: Pandora224s1_QuezonCity_20260606_L1_smca1c2d20220621p1-8.txt Full location name: Manila Observatory, Ateneo De Manila University Short location name: QuezonCity Country of location: Philippines Location latitude [deg]: 14.6350 Location longitude [deg]: 121.0780 Location altitude [m]: 63 Local noon date: 20260606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB based on session 1 for initial deployment period First and last pixel inside fitting window: 1622 1771 Nominal wavelengths inside fitting window [nm]: 492.1198 492.2406 492.3615 492.4823 492.6032 492.7240 492.8448 492.9655 493.0863 493.2070 493.3278 493.4485 493.5692 493.6898 493.8105 493.9311 494.0517 494.1724 494.2929 494.4135 494.5341 494.6546 494.7751 494.8956 495.0161 495.1366 495.2571 495.3775 495.4979 495.6183 495.7387 495.8591 495.9794 496.0998 496.2201 496.3404 496.4607 496.5809 496.7012 496.8214 496.9416 497.0618 497.1820 497.3022 497.4223 497.5424 497.6626 497.7827 497.9027 498.0228 498.1428 498.2629 498.3829 498.5029 498.6229 498.7428 498.8628 498.9827 499.1026 499.2225 499.3424 499.4622 499.5821 499.7019 499.8217 499.9415 500.0613 500.1810 500.3008 500.4205 500.5402 500.6599 500.7795 500.8992 501.0188 501.1384 501.2580 501.3776 501.4972 501.6167 501.7363 501.8558 501.9753 502.0948 502.2142 502.3337 502.4531 502.5725 502.6919 502.8113 502.9307 503.0500 503.1693 503.2886 503.4079 503.5272 503.6465 503.7657 503.8849 504.0041 504.1233 504.2425 504.3617 504.4808 504.5999 504.7190 504.8381 504.9572 505.0762 505.1953 505.3143 505.4333 505.5523 505.6712 505.7902 505.9091 506.0280 506.1469 506.2658 506.3847 506.5035 506.6223 506.7411 506.8599 506.9787 507.0975 507.2162 507.3349 507.4536 507.5723 507.6910 507.8096 507.9283 508.0469 508.1655 508.2841 508.4026 508.5212 508.6397 508.7582 508.8767 508.9952 509.1137 509.2321 509.3506 509.4690 509.5874 509.7057 509.8241 509.9424 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20260605T231611.4Z 9652.969577 260 1 52.27 2 65.83 71.42 55.12 235.82 0.00 1 0.00 1 0 22 3.094e-03 3.046e-03 5.284e-04 5.267e-04 8.256954e+03 3.585170e+01 5.503755e+02 -6.000000e+00 1.747483e+02 294.98 -2.00 20.00 -2.00 505.27 0.00e+00 1.070219e-03 1.474321e-05 6.738218e-05 -6.000000e+00 8.848692e-05 294.98 -2.00 20.00 -2.00 500.39 0.00e+00 1.560789e-01 1.025941e-02 4.616620e-02 -6.000000e+00 6.014111e-02 228.81 -2.00 3.09 -2.00 501.99 0.00e+00 2.425 0.000 489.00 513.00 1 6.3833e+00 7.8790e-04 5.4660e-03 -6.0000e+00 4.6234e-03 8.1815e-03 2.0365e-04 1.1383e-03 -6.0000e+00 1.2083e-03 2.2601e-03 1.4228e-03 4.5766e-05 5.2966e-05 -6.0000e+00 2.8431e-04 -1.0531e-02 8.0487e-05 11 1 0 11 16 0 99.61 24.12 1.60 -0.01053 -0.00066 52 8 1 4 0 1005.100 26.41 20.00 24.12 34.31 7.8 1011.02 -634 -355 31 29 278 459 607 291 307 205 197 -119 -335 -319 -387 -288 -22 190 58 131 210 108 135 370 255 399 279 -143 -385 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64 226 285 382 621 629 458 280 228 121 49 246 182 74 294 130 128 461 294 -3 2 -125 -373 -256 -84 -168 -44 167 153 130 232 163 343 393 -6 -256 -419 -451 -459 SQ 20260605T232106.3Z 9652.972990 262 1 51.67 2 64.70 71.56 56.08 236.59 0.00 1 0.00 1 0 22 3.038e-03 3.008e-03 3.377e-04 3.370e-04 7.752094e+03 2.256855e+01 5.220249e+02 -6.000000e+00 1.715637e+02 294.98 -2.00 20.00 -2.00 505.27 0.00e+00 9.950464e-04 9.452696e-06 6.230885e-05 -6.000000e+00 8.687235e-05 294.98 -2.00 20.00 -2.00 500.46 0.00e+00 1.529296e-01 6.546780e-03 4.343249e-02 -6.000000e+00 5.905447e-02 228.81 -2.00 3.09 -2.00 502.04 0.00e+00 2.325 0.000 489.00 513.00 1 5.7453e+00 5.0303e-04 5.1791e-03 -6.0000e+00 4.5397e-03 8.9955e-03 1.2992e-04 1.0780e-03 -6.0000e+00 1.1867e-03 4.3481e-03 1.7035e-03 2.9425e-05 5.1558e-05 -6.0000e+00 2.7914e-04 -9.4670e-03 6.0090e-05 10 0 0 10 0 0 99.98 24.11 1.64 -0.00947 0.00235 124 20 1 4 0 416.650 26.41 20.00 24.11 34.49 7.8 1012.34 -623 -294 -56 7 295 483 478 374 240 173 241 -121 -224 -313 -371 -185 -15 138 27 81 178 101 216 299 310 402 382 -79 -422 -382 -426 -430 146 303 29 135 135 -42 -217 -194 -173 27 188 322 341 358 297 262 -13 -380 -605 -715 -651 -398 -196 -101 42 32 71 163 226 233 301 279 169 80 67 -74 -358 -338 -279 -222 -29 83 -41 -155 -71 -246 -410 -425 -421 -329 -356 -74 -87 -256 -127 -169 -147 17 161 513 347 307 482 322 75 -227 -592 -824 -657 -476 -132 -1 -91 -122 -279 -286 -216 -126 -123 108 223 220 386 618 614 484 378 248 131 30 235 220 99 246 200 197 405 232 -58 -27 -115 -377 -202 -33 -224 -21 100 103 144 193 316 316 245 152 -367 -414 -465 -453 -602 -291 -56 7 304 507 499 391 249 180 248 -123 -229 -316 -377 -189 -15 145 28 85 186 107 227 316 328 424 400 -81 -430 -386 -429 -429 149 314 30 143 141 -44 -221 -197 -176 27 195 338 360 377 310 270 -13 -380 -603 -700 -635 -395 -197 -102 43 32 73 166 231 240 310 287 172 79 67 -73 -352 -335 -276 -217 -29 82 -41 -153 -69 -239 -397 -411 -410 -323 -344 -72 -86 -255 -126 -167 -145 17 160 507 346 303 473 309 72 -211 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7.8 1012.18 -723 -451 -5 -86 228 448 451 398 277 283 190 -173 -255 -387 -264 -217 6 103 24 101 178 133 193 272 210 281 420 -116 -321 -434 -434 -354 154 304 132 213 188 -26 -188 -147 -97 38 215 236 404 390 355 286 -23 -412 -536 -781 -649 -414 -203 -96 37 -72 86 177 212 330 310 229 184 101 14 -51 -387 -346 -251 -116 -96 186 -64 -139 -64 -289 -417 -290 -293 -423 -199 7 -109 -158 -16 -162 -238 -90 136 415 435 333 409 274 11 -186 -573 -728 -731 -409 -101 148 -134 -40 -198 -358 -303 -60 -196 81 123 265 425 618 607 459 316 282 -20 10 259 110 80 347 195 214 383 277 2 88 -159 -373 -256 -125 -206 -42 127 57 10 204 322 186 293 164 -347 -391 -530 -435 -704 -450 -5 -87 235 471 470 415 294 296 196 -176 -261 -394 -268 -222 6 108 25 106 186 139 202 286 221 295 438 -119 -326 -440 -438 -353 157 314 139 224 195 -27 -196 -152 -98 39 222 247 425 409 368 293 -24 -412 -534 -765 -633 -411 -203 -99 38 -74 88 180 216 338 318 234 186 103 14 -51 -379 -335 -248 -113 -94 185 -64 -137 -62 -282 -404 -280 -286 -406 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