File name: Pandora52s1_RichmondCA_20190622_L2Fit_fwvt1c1d20170616p1-8.txt File generation date: 20251129T014139.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Ronald Cohen Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora52_OF_v2d20170505.txt Instrument calibration file used: Pandora52s1_CF_v1d20170616.txt Level 1 file used: Pandora52s1_RichmondCA_20190622_L1_smca1c1d20170616p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20190622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0261 492.1471 492.2680 492.3889 492.5097 492.6306 492.7515 492.8723 492.9931 493.1139 493.2347 493.3555 493.4762 493.5970 493.7177 493.8384 493.9591 494.0797 494.2004 494.3210 494.4417 494.5623 494.6829 494.8034 494.9240 495.0446 495.1651 495.2856 495.4061 495.5266 495.6470 495.7675 495.8879 496.0083 496.1287 496.2491 496.3695 496.4898 496.6102 496.7305 496.8508 496.9711 497.0913 497.2116 497.3318 497.4521 497.5723 497.6925 497.8126 497.9328 498.0529 498.1731 498.2932 498.4133 498.5333 498.6534 498.7734 498.8935 499.0135 499.1335 499.2535 499.3734 499.4934 499.6133 499.7332 499.8531 499.9730 500.0929 500.2127 500.3326 500.4524 500.5722 500.6920 500.8117 500.9315 501.0512 501.1710 501.2907 501.4104 501.5300 501.6497 501.7693 501.8890 502.0086 502.1282 502.2477 502.3673 502.4868 502.6064 502.7259 502.8454 502.9648 503.0843 503.2038 503.3232 503.4426 503.5620 503.6814 503.8008 503.9201 504.0394 504.1587 504.2781 504.3973 504.5166 504.6359 504.7551 504.8743 504.9935 505.1127 505.2319 505.3510 505.4702 505.5893 505.7084 505.8275 505.9466 506.0656 506.1847 506.3037 506.4227 506.5417 506.6607 506.7796 506.8986 507.0175 507.1364 507.2553 507.3742 507.4930 507.6119 507.7307 507.8495 507.9683 508.0871 508.2059 508.3246 508.4433 508.5620 508.6807 508.7994 508.9181 509.0367 509.1554 509.2740 509.3926 509.5112 509.6297 509.7483 509.8668 509.9853 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190622T125313.0Z 7112.536956 1 1 36.01 2 89.87 59.85 54.23 190.34 0.00 1 0.00 1 0 15 3.497e-02 3.441e-02 2.188e-02 2.164e-02 3.064835e+03 1.479378e+03 2.599465e+02 -6.000000e+00 2.079872e+03 289.07 -2.00 20.00 -2.00 505.24 0.00e+00 1.739902e-03 6.200877e-04 8.541380e-05 -6.000000e+00 1.015779e-03 289.07 -2.00 20.00 -2.00 500.04 0.00e+00 2.998818e+00 4.486199e-01 1.958515e-02 -6.000000e+00 7.129716e-01 232.81 -2.00 3.45 -2.00 501.69 0.00e+00 20.081 0.139 489.00 513.00 1 7.8783e+00 3.4611e-02 3.5081e-02 -6.0000e+00 5.4885e-02 1.1833e-01 8.7343e-03 1.9674e-03 -6.0000e+00 1.4099e-02 3.2780e-05 2.7142e-03 2.4743e-03 4.4475e-05 -6.0000e+00 4.1623e-03 -3.9695e-02 3.8459e-04 12 8 8 10 0 0 -1.15 21.50 3.08 -0.03969 -0.02087 9 1 1 4 0 4000.000 26.83 20.00 21.50 -4390 -2230 1982 -949 3698 -2959 3337 -291 2703 -78 -1345 3133 -1346 3158 -4010 736 -1101 3105 -3493 -3564 -2780 -1436 4785 3374 1706 -3287 4771 2017 2115 -654 -618 5425 886 -113 -279 1526 -2727 -1237 -1285 3415 5622 -9813 3774 -3325 -770 749 2956 -839 -183 633 -5274 -1016 -6264 2040 -3273 2252 1250 2060 -103 -1952 2891 -1723 8786 2354 5117 302 -1166 -69 1886 7573 -6026 -3493 -2510 2102 2687 -1935 925 -1374 795 491 -268 -5809 3543 -6249 2322 -4125 775 2224 -3328 1177 -2976 154 415 4495 111 1818 6031 -6501 9142 -7012 3077 -2794 1127 -889 -1979 -111 -4723 4609 2149 9583 103 4294 374 -5 -2290 315 720 -5225 842 -5433 2310 -2073 5683 2333 2008 1249 1985 -465 -6440 3185 -1327 225 -3597 718 7274 -3487 1349 -3241 3398 -1705 4810 -608 -91 -2164 -86 4519 -2541 2556 -6767 3721 900000 -4381 -2204 1926 -978 3738 -3268 3517 -321 2888 -85 -1463 3214 -1425 3164 -4298 755 -1167 3219 -3944 -4078 -3176 -1622 5092 3653 1883 -3810 5071 2174 2230 -693 -645 5340 928 -122 -310 1678 -3121 -1383 -1423 3585 5771 -11819 4003 -3822 -869 833 3198 -931 -198 662 -5532 -1032 -6433 2002 -3346 2230 1275 2105 -107 -2081 2937 -1836 8429 2400 5031 307 -1185 -68 1805 6768 -6125 -3460 -2476 1995 2544 -1906 873 -1308 732 451 -248 -5712 3192 -6256 2149 -4094 733 2075 -3281 1112 -2950 150 405 4212 108 1703 5298 -6318 7432 -6597 2610 -2545 1012 -838 -1922 -106 -4709 4147 1972 8196 98 3974 354 -5 -2264 305 697 -5371 809 -5494 2133 -1978 4994 2124 1841 1157 1828 -439 -6438 2884 -1247 206 -3374 641 6085 -3287 1234 -3159 3146 -1680 4478 -601 -90 -2191 -85 4236 -2515 2360 -6761 3337 900000 SO 20190622T125511.0Z 7112.538322 3 1 36.01 2 89.53 60.15 54.29 190.90 0.00 1 0.00 1 0 15 2.282e-02 2.248e-02 1.823e-02 1.807e-02 1.954450e+03 1.197973e+03 1.321619e+02 -6.000000e+00 1.356849e+03 289.07 -2.00 20.00 -2.00 505.28 0.00e+00 2.347833e-03 5.160936e-04 9.880432e-05 -6.000000e+00 6.615207e-04 289.07 -2.00 20.00 -2.00 500.10 0.00e+00 2.999520e+00 3.711429e-01 2.130836e-02 -6.000000e+00 4.608372e-01 232.81 -2.00 3.45 -2.00 501.76 0.00e+00 19.586 0.128 489.00 513.00 1 7.7573e+00 2.8718e-02 3.3726e-02 -6.0000e+00 3.5549e-02 1.1513e-01 7.1145e-03 1.8824e-03 -6.0000e+00 9.0038e-03 3.9469e-05 5.8694e-03 2.0696e-03 3.7736e-05 -6.0000e+00 2.7058e-03 9.4875e-03 -9.1408e-05 12 8 8 10 0 0 -7.63 21.51 4.92 0.00949 0.05020 9 1 1 4 0 4000.000 26.83 20.00 21.51 -2033 152 447 -52 -2820 -1476 -1356 -2171 -580 -3495 3343 -690 -2566 1766 -1489 1938 -3423 1467 432 3018 -575 2260 20 1221 -930 -1613 757 -3142 1082 270 1462 984 -1030 -143 -415 4418 711 1880 1090 976 -2032 -1490 2310 2773 2140 -129 2062 -872 -431 -1015 2373 -4000 -3242 3635 -3709 447 -756 3588 -923 476 -1127 -15 2300 -2746 720 263 5124 2036 651 -490 2442 -228 449 4538 -1754 3788 -4387 -579 1601 -1579 -2364 -547 2973 -4925 3561 -3575 4053 -3153 188 -3113 3890 6415 970 -769 -3731 2233 1104 766 3654 -109 -3168 -2531 3609 -2839 -1280 -389 1709 1023 61 -2400 -246 2630 -1831 -1556 2205 506 485 565 1972 -670 -1166 -1091 4120 -616 810 -1823 2270 -2718 -177 399 -4461 1227 -1065 -607 337 1361 2283 -915 4153 -365 2568 -2 823 -160 -2796 1354 -247 -3876 -1229 -289 -4190 -1992 147 444 -53 -3062 -1615 -1506 -2449 -643 -3954 3484 -738 -2759 1800 -1561 1972 -3726 1551 471 3240 -643 2465 23 1353 -1057 -1843 840 -3574 1156 284 1498 1015 -1103 -155 -447 4730 763 1977 1145 1020 -2188 -1606 2419 2920 2283 -141 2193 -942 -456 -1053 2320 -4080 -3251 3424 -3835 454 -792 3636 -982 499 -1201 -16 2373 -2970 745 270 4929 1989 636 -478 2298 -220 434 4235 -1749 3550 -4401 -551 1474 -1493 -2253 -514 2714 -4899 3276 -3550 3736 -3122 180 -3090 3624 5888 948 -767 -3691 2113 1035 704 3188 -97 -2811 -2257 3098 -2669 -1205 -365 1557 929 56 -2254 -229 2416 -1784 -1529 2104 494 475 553 1890 -651 -1124 -1040 3713 -583 759 -1759 2105 -2649 -168 375 -4375 1123 -985 -554 304 1232 2083 -878 3844 -357 2461 -2 811 -159 -2862 1318 -240 -3839 -1168 -271 -3997 SO 20190622T125705.0Z 7112.539641 5 1 36.02 2 89.20 60.44 54.36 191.45 0.00 1 0.00 1 0 15 1.846e-02 1.812e-02 1.430e-02 1.420e-02 6.414871e+03 1.028471e+03 4.008182e+02 -6.000000e+00 1.097447e+03 289.07 -2.00 20.00 -2.00 505.29 0.00e+00 1.556712e-03 4.045793e-04 1.039726e-04 -6.000000e+00 5.349522e-04 289.07 -2.00 20.00 -2.00 500.18 0.00e+00 2.251716e+00 2.918389e-01 5.182469e-02 -6.000000e+00 3.723643e-01 232.81 -2.00 3.45 -2.00 501.81 0.00e+00 18.956 0.116 489.00 513.00 1 7.6549e+00 2.2531e-02 3.2285e-02 -6.0000e+00 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