File name: Pandora52s1_RichmondCA_20190728_L2Fit_fwvt1c1d20170616p1-8.txt File generation date: 20251129T020853.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Ronald Cohen Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora52_OF_v2d20170505.txt Instrument calibration file used: Pandora52s1_CF_v1d20170616.txt Level 1 file used: Pandora52s1_RichmondCA_20190728_L1_smca1c1d20170616p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20190728 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0261 492.1471 492.2680 492.3889 492.5097 492.6306 492.7515 492.8723 492.9931 493.1139 493.2347 493.3555 493.4762 493.5970 493.7177 493.8384 493.9591 494.0797 494.2004 494.3210 494.4417 494.5623 494.6829 494.8034 494.9240 495.0446 495.1651 495.2856 495.4061 495.5266 495.6470 495.7675 495.8879 496.0083 496.1287 496.2491 496.3695 496.4898 496.6102 496.7305 496.8508 496.9711 497.0913 497.2116 497.3318 497.4521 497.5723 497.6925 497.8126 497.9328 498.0529 498.1731 498.2932 498.4133 498.5333 498.6534 498.7734 498.8935 499.0135 499.1335 499.2535 499.3734 499.4934 499.6133 499.7332 499.8531 499.9730 500.0929 500.2127 500.3326 500.4524 500.5722 500.6920 500.8117 500.9315 501.0512 501.1710 501.2907 501.4104 501.5300 501.6497 501.7693 501.8890 502.0086 502.1282 502.2477 502.3673 502.4868 502.6064 502.7259 502.8454 502.9648 503.0843 503.2038 503.3232 503.4426 503.5620 503.6814 503.8008 503.9201 504.0394 504.1587 504.2781 504.3973 504.5166 504.6359 504.7551 504.8743 504.9935 505.1127 505.2319 505.3510 505.4702 505.5893 505.7084 505.8275 505.9466 506.0656 506.1847 506.3037 506.4227 506.5417 506.6607 506.7796 506.8986 507.0175 507.1364 507.2553 507.3742 507.4930 507.6119 507.7307 507.8495 507.9683 508.0871 508.2059 508.3246 508.4433 508.5620 508.6807 508.7994 508.9181 509.0367 509.1554 509.2740 509.3926 509.5112 509.6297 509.7483 509.8668 509.9853 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190728T131432.0Z 7148.551759 1 1 36.01 2 89.87 65.79 50.51 94.99 0.00 1 0.00 1 0 15 1.639e-02 1.617e-02 1.433e-02 1.417e-02 1.070771e+04 1.107220e+03 5.513625e+02 -6.000000e+00 9.831510e+02 291.47 -2.00 20.00 -2.00 505.28 0.00e+00 2.085244e-03 4.077896e-04 1.192084e-04 -6.000000e+00 4.779909e-04 291.47 -2.00 20.00 -2.00 500.04 0.00e+00 2.095437e+00 2.946384e-01 9.046679e-02 -6.000000e+00 3.298680e-01 232.22 -2.00 3.45 -2.00 501.69 0.00e+00 20.028 0.137 489.00 513.00 1 7.4976e+00 2.2766e-02 3.5722e-02 -6.0000e+00 2.5479e-02 1.3115e-01 5.6049e-03 2.6454e-03 -6.0000e+00 6.4371e-03 5.0726e-05 -2.3118e-03 1.5493e-03 4.3726e-05 -6.0000e+00 1.9427e-03 -2.7082e-03 7.3059e-05 12 8 8 10 0 0 -4.61 21.45 2.18 -0.00271 -0.01874 9 1 1 4 0 4000.000 26.73 20.00 21.45 -3612 -1709 55 -1225 -1648 -735 382 -362 1129 347 1123 -400 -1595 -16 -1951 -2670 482 -382 99 1795 217 -3914 -532 906 311 -456 886 946 943 2100 -2347 -2630 1224 1005 1833 3223 -543 -1187 357 -1678 2298 2681 2684 -1631 339 1981 151 1956 1115 1279 -1048 -426 -758 1107 -1817 1323 1097 -977 1775 -1447 1456 -2057 1391 1998 -1687 -839 403 1486 24 -9 -483 730 628 -2597 1728 689 -2737 759 750 -548 1908 3166 -2741 -482 3363 935 -2793 -503 37 481 1397 1018 -859 -1578 1729 -867 -541 -1845 -485 1569 5591 -1687 1240 51 -1588 1882 1155 -1948 -896 207 -345 279 1865 -276 1380 -2543 850 1283 -583 497 874 -231 1829 2948 1100 4339 -415 -427 -1690 -2868 -9 524 -603 -2488 -299 -2595 -387 -2751 -933 -1565 -2228 1541 619 -949 -1606 675 -913 -355 200 1144 644 -3614 -1686 55 -1266 -1758 -795 416 -401 1237 381 1207 -430 -1713 -16 -2064 -2847 503 -409 108 1950 242 -4552 -600 1009 349 -517 987 1042 1020 2192 -2513 -2811 1274 1074 1989 3496 -612 -1337 392 -1866 2451 2860 2887 -1792 369 2127 165 2073 1172 1312 -1073 -423 -745 1068 -1835 1326 1126 -1038 1844 -1553 1518 -2225 1455 2075 -1807 -880 412 1477 23 -9 -472 703 607 -2615 1676 674 -2733 720 701 -515 1744 2864 -2645 -458 3101 890 -2765 -486 35 458 1321 974 -842 -1556 1628 -818 -494 -1659 -420 1306 4449 -1459 1071 47 -1510 1760 1091 -1831 -828 189 -320 260 1729 -263 1302 -2509 816 1234 -571 478 825 -217 1664 2644 1008 3861 -388 -399 -1599 -2737 -8 475 -546 -2277 -268 -2400 -356 -2637 -892 -1528 -2213 1486 605 -946 -1610 657 -891 -338 187 1052 598 SO 20190728T131630.0Z 7148.553125 3 1 36.01 2 89.52 66.09 50.13 95.30 0.00 1 0.00 1 0 15 1.500e-02 1.472e-02 1.159e-02 1.147e-02 1.200740e+04 9.086755e+02 7.714330e+02 -6.000000e+00 8.995698e+02 291.47 -2.00 20.00 -2.00 505.29 0.00e+00 9.681997e-04 3.291878e-04 5.925891e-05 -6.000000e+00 4.373602e-04 291.47 -2.00 20.00 -2.00 500.06 0.00e+00 1.838982e+00 2.369661e-01 6.998520e-02 -6.000000e+00 3.018488e-01 232.22 -2.00 3.45 -2.00 501.70 0.00e+00 19.507 0.127 489.00 513.00 1 7.3810e+00 1.8275e-02 3.3950e-02 -6.0000e+00 2.3314e-02 1.2637e-01 4.5083e-03 2.4979e-03 -6.0000e+00 5.8910e-03 6.3439e-05 6.0300e-04 1.2347e-03 4.5484e-05 -6.0000e+00 1.7776e-03 8.8079e-03 -2.9963e-06 12 8 8 10 0 0 12.57 21.45 1.43 0.00881 0.01299 9 1 1 4 0 4000.000 26.73 19.99 21.45 -1768 1272 -1069 -1931 -990 -118 -693 -1711 -804 -805 2086 -897 -592 487 1194 887 -654 1689 -2107 -284 878 -875 -43 98 238 -1737 -70 -177 -409 -1538 2219 2291 731 891 1226 -901 -872 661 -545 -44 -612 1178 919 2430 554 -307 1380 408 1543 -377 3082 -2813 -1746 49 -6 3704 -1068 500 444 -223 688 281 -1861 414 2002 -620 -1068 -2214 1319 -3862 -805 257 2760 1267 -969 1003 281 1123 -3617 1501 -1299 1970 -208 1293 1301 -355 1629 297 609 -622 805 421 -1305 1037 -1217 3556 227 11 -787 1473 200 -1544 2580 -1754 -130 -1972 1749 -2695 3201 -328 45 -3015 554 669 -1821 -1614 1716 471 788 2020 2578 -339 65 -2584 745 1996 3492 -2715 -275 308 -1573 -2723 -409 542 1414 -74 -1051 -2216 42 1354 1043 -652 -62 -1404 873 -1446 324 31 66 466 -2287 -1774 1249 -1100 -1999 -1043 -126 -758 -1910 -890 -885 2199 -961 -624 503 1216 908 -689 1771 -2343 -315 968 -984 -48 110 267 -1984 -78 -195 -444 -1651 2256 2324 765 954 1337 -1015 -981 727 -601 -48 -669 1270 1001 2631 616 -345 1518 447 1645 -401 3082 -2917 -1769 48 -6 3715 -1113 519 463 -234 715 294 -1992 432 2042 -641 -1092 -2256 1280 -3898 -782 247 2597 1220 -959 969 269 1052 -3507 1372 -1219 1794 -195 1204 1223 -342 1541 284 579 -598 766 404 -1282 991 -1168 3167 203 9 -673 1215 166 -1331 2203 -1626 -122 -1926 1649 -2641 2942 -312 43 -3005 537 651 -1772 -1576 1633 456 761 1909 2385 -318 60 -2443 683 1813 3129 -2588 -255 284 -1463 -2533 -367 479 1242 -67 -974 -2116 40 1285 1004 -644 -61 -1408 854 -1438 312 29 61 432 -2196 SO 20190728T131824.0Z 7148.554445 5 1 36.01 2 89.17 66.38 49.77 95.61 0.00 1 0.00 1 0 15 1.167e-02 1.165e-02 9.387e-03 9.306e-03 9.643641e+03 7.116815e+02 6.176617e+02 -6.000000e+00 7.001044e+02 291.47 -2.00 20.00 -2.00 505.28 0.00e+00 2.035944e-03 2.681919e-04 1.073827e-04 -6.000000e+00 3.404318e-04 291.47 -2.00 20.00 -2.00 500.11 0.00e+00 1.966063e+00 1.923116e-01 6.131373e-02 -6.000000e+00 2.350935e-01 232.22 -2.00 3.45 -2.00 501.75 0.00e+00 18.839 0.114 489.00 513.00 1 7.2386e+00 1.4871e-02 3.2140e-02 -6.0000e+00 1.8156e-02 1.1944e-01 3.6604e-03 2.2420e-03 -6.0000e+00 4.5914e-03 7.8827e-05 1.9754e-03 1.0259e-03 5.3241e-05 -6.0000e+00 1.3839e-03 -7.4573e-04 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