File name: Pandora52s1_RichmondCA_20190812_L2Fit_fwvt1c1d20170616p1-8.txt File generation date: 20251129T020909.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Ronald Cohen Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora52_OF_v2d20170505.txt Instrument calibration file used: Pandora52s1_CF_v1d20170616.txt Level 1 file used: Pandora52s1_RichmondCA_20190812_L1_smca1c1d20170616p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20190812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0261 492.1471 492.2680 492.3889 492.5097 492.6306 492.7515 492.8723 492.9931 493.1139 493.2347 493.3555 493.4762 493.5970 493.7177 493.8384 493.9591 494.0797 494.2004 494.3210 494.4417 494.5623 494.6829 494.8034 494.9240 495.0446 495.1651 495.2856 495.4061 495.5266 495.6470 495.7675 495.8879 496.0083 496.1287 496.2491 496.3695 496.4898 496.6102 496.7305 496.8508 496.9711 497.0913 497.2116 497.3318 497.4521 497.5723 497.6925 497.8126 497.9328 498.0529 498.1731 498.2932 498.4133 498.5333 498.6534 498.7734 498.8935 499.0135 499.1335 499.2535 499.3734 499.4934 499.6133 499.7332 499.8531 499.9730 500.0929 500.2127 500.3326 500.4524 500.5722 500.6920 500.8117 500.9315 501.0512 501.1710 501.2907 501.4104 501.5300 501.6497 501.7693 501.8890 502.0086 502.1282 502.2477 502.3673 502.4868 502.6064 502.7259 502.8454 502.9648 503.0843 503.2038 503.3232 503.4426 503.5620 503.6814 503.8008 503.9201 504.0394 504.1587 504.2781 504.3973 504.5166 504.6359 504.7551 504.8743 504.9935 505.1127 505.2319 505.3510 505.4702 505.5893 505.7084 505.8275 505.9466 506.0656 506.1847 506.3037 506.4227 506.5417 506.6607 506.7796 506.8986 507.0175 507.1364 507.2553 507.3742 507.4930 507.6119 507.7307 507.8495 507.9683 508.0871 508.2059 508.3246 508.4433 508.5620 508.6807 508.7994 508.9181 509.0367 509.1554 509.2740 509.3926 509.5112 509.6297 509.7483 509.8668 509.9853 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190812T132713.0Z 7163.560567 1 1 36.01 2 89.86 71.04 121.21 264.20 0.00 1 0.00 1 0 15 2.152e-02 2.146e-02 1.791e-02 1.775e-02 1.070209e+04 1.383405e+03 7.608051e+02 -6.000000e+00 1.292480e+03 291.80 -2.00 20.00 -2.00 505.30 0.00e+00 3.446507e-03 5.094682e-04 2.014031e-04 -6.000000e+00 6.282959e-04 291.80 -2.00 20.00 -2.00 500.15 0.00e+00 1.866165e+00 3.661493e-01 5.710899e-02 -6.000000e+00 4.330418e-01 231.72 -2.00 3.45 -2.00 501.77 0.00e+00 20.013 0.137 489.00 513.00 1 7.7363e+00 2.8267e-02 3.5451e-02 -6.0000e+00 3.3451e-02 1.2367e-01 6.9554e-03 2.3616e-03 -6.0000e+00 8.4549e-03 3.9974e-05 6.7273e-03 1.9517e-03 9.9889e-05 -6.0000e+00 2.5519e-03 1.4175e-02 -6.8320e-05 12 8 8 10 0 0 16.65 21.49 1.76 0.01417 0.06084 9 1 1 4 0 4000.000 26.83 20.00 21.49 -841 -1492 -2701 -339 537 3818 923 827 -172 -1977 1802 -1921 -1015 1450 5216 -848 675 1344 -43 2026 -3698 1419 -528 -1239 -967 -1293 -317 -1094 1074 599 -35 -1344 1195 -4684 2103 346 2623 656 -1868 3962 38 1119 -1337 2515 1671 35 2555 -1531 2902 -2355 758 -3037 2459 15 4080 1092 -1608 -729 -5380 -1078 -3810 1110 630 3642 -741 1433 1279 -1322 -962 -4559 3083 -2904 1687 350 -2442 -4 -2188 -1405 324 1563 872 3039 -2256 -479 90 2616 1240 -1564 -2628 1923 -734 2210 4073 -2382 -2988 3524 -488 2555 -1850 2000 -3953 -3339 -2232 -1312 -3054 1985 -965 657 -481 -688 1140 -928 382 1824 2926 3673 208 3700 -3340 2188 -1553 -471 -1442 494 1380 -1451 2479 -305 4669 -1875 716 174 1152 840 -1532 2915 -2335 2205 -2391 3593 -794 1469 -2308 -878 -13 -1411 559 -254 1288 -4240 1577 -818 -1482 -2790 -353 568 3990 1008 910 -191 -2206 1908 -2081 -1075 1483 5121 -889 707 1381 -45 2128 -4134 1511 -574 -1363 -1065 -1427 -344 -1180 1109 607 -35 -1378 1217 -5193 2222 375 2767 700 -2027 4037 40 1185 -1466 2683 1812 38 2734 -1685 2998 -2505 763 -3113 2369 15 3987 1127 -1736 -789 -6111 -1174 -4268 1187 677 3787 -797 1489 1311 -1369 -980 -4759 2963 -2963 1655 351 -2444 -4 -2202 -1382 309 1467 798 2733 -2152 -452 85 2424 1165 -1506 -2550 1783 -703 2072 3765 -2335 -2894 3114 -437 2156 -1596 1639 -3441 -2942 -2008 -1211 -2940 1836 -917 611 -451 -651 1071 -901 370 1752 2797 3509 207 3574 -3448 2112 -1532 -454 -1392 468 1301 -1411 2323 -294 4271 -1824 673 163 1052 766 -1394 2571 -2208 2027 -2334 3345 -779 1418 -2325 -873 -13 -1391 532 -239 1181 -4105 1455 SO 20190812T132911.0Z 7163.561933 3 1 36.01 2 89.49 71.34 121.58 264.47 0.00 1 0.00 1 0 22 1.569e-02 1.549e-02 1.289e-02 1.277e-02 1.296083e+04 1.019928e+03 7.459991e+02 -6.000000e+00 9.425006e+02 291.80 -2.00 20.00 -2.00 505.28 0.00e+00 2.579089e-03 3.676080e-04 1.489170e-04 -6.000000e+00 4.590576e-04 291.80 -2.00 20.00 -2.00 500.12 0.00e+00 1.699424e+00 2.651330e-01 9.157510e-02 -6.000000e+00 3.190634e-01 231.72 -2.00 3.45 -2.00 501.74 0.00e+00 19.465 0.126 489.00 513.00 1 7.4888e+00 2.0408e-02 3.4287e-02 -6.0000e+00 2.4589e-02 1.1701e-01 5.0971e-03 2.6889e-03 -6.0000e+00 6.3134e-03 5.6559e-05 2.1903e-03 1.3782e-03 6.8655e-05 -6.0000e+00 1.8678e-03 -1.2853e-02 1.8474e-04 12 8 8 10 0 0 -4.56 21.50 7.65 -0.01285 0.00234 9 1 1 4 0 4000.000 26.83 20.00 21.50 2880 -2551 1174 -1327 -2930 1572 -2238 -2155 -632 1075 -201 -1789 1582 968 2961 -1263 1114 -2196 -203 -2001 -749 1574 19 1370 3818 1170 -1309 667 -90 -244 -2172 405 1587 819 157 -1781 -294 -1700 1770 318 1389 1571 1386 -427 1132 -1054 -126 398 371 992 -1466 -1660 -1805 -5 2084 -1479 2510 928 -1226 380 1080 2024 -1496 1692 -725 643 -1496 -434 -1280 1089 3277 -3197 -310 -282 -882 221 539 111 1628 -1602 1800 -740 -2173 2458 -1000 127 -1357 1805 1042 -1219 1925 -2544 1453 -9 -1302 -770 -30 -4047 1083 3139 1753 2743 -1476 -1308 -1863 1166 -427 -336 76 1577 -151 -1278 -386 -826 487 451 -596 -364 2600 30 -578 1738 428 3948 -1058 1163 -282 514 -491 1839 -1437 -846 2385 -1824 -720 16 -248 127 -428 2242 1066 -2585 -1343 1474 -1424 2117 -1697 507 -1841 -1865 900000 2711 -2563 1166 -1392 -3208 1682 -2450 -2376 -686 1137 -212 -1893 1597 973 2903 -1297 1131 -2351 -217 -2207 -820 1690 21 1483 4045 1273 -1452 716 -95 -253 -2262 412 1620 864 170 -1990 -322 -1879 1872 340 1467 1666 1488 -472 1241 -1184 -139 433 397 1031 -1522 -1692 -1825 -5 2080 -1566 2607 990 -1342 409 1157 2153 -1600 1750 -762 658 -1540 -435 -1277 1049 3163 -3191 -303 -277 -875 215 517 106 1501 -1514 1642 -695 -2083 2269 -964 122 -1321 1698 984 -1177 1807 -2516 1387 -8 -1245 -712 -26 -3643 905 2536 1436 2265 -1314 -1208 -1783 1100 -409 -321 72 1475 -146 -1256 -379 -819 479 447 -602 -369 2555 30 -555 1651 408 3631 -996 1075 -265 479 -462 1683 -1348 -779 2103 -1668 -654 14 -231 120 -413 2133 1037 -2628 -1355 1448 -1435 2042 -1677 481 -1769 -1788 900000 SO 20190812T133105.0Z 7163.563252 5 1 36.01 2 89.14 71.63 121.94 264.73 0.00 1 0.00 1 0 22 1.109e-02 1.088e-02 8.808e-03 8.738e-03 1.132081e+04 6.894383e+02 7.178167e+02 -6.000000e+00 6.659988e+02 291.80 -2.00 20.00 -2.00 505.33 0.00e+00 2.468461e-03 2.520122e-04 1.280001e-04 -6.000000e+00 3.237356e-04 291.80 -2.00 20.00 -2.00 500.19 0.00e+00 2.276259e+00 1.802175e-01 7.194849e-02 -6.000000e+00 2.230561e-01 231.72 -2.00 3.45 -2.00 501.82 0.00e+00 18.761 0.113 489.00 513.00 1 7.1546e+00 1.3917e-02 3.2123e-02 -6.0000e+00 1.7232e-02 9.8285e-02 3.4164e-03 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