File name: Pandora52s1_RichmondCA_20200106_L2Fit_fwvt1c1d20170616p1-8.txt File generation date: 20251129T032345.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Ronald Cohen Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 52 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora52_OF_v2d20170505.txt Instrument calibration file used: Pandora52s1_CF_v1d20170616.txt Level 1 file used: Pandora52s1_RichmondCA_20200106_L1_smca1c1d20170616p1-8.txt Full location name: University Of California Berkeley Short location name: RichmondCA Country of location: USA Location latitude [deg]: 37.9130 Location longitude [deg]: -122.3360 Location altitude [m]: 5 Local noon date: 20200106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.0261 492.1471 492.2680 492.3889 492.5097 492.6306 492.7515 492.8723 492.9931 493.1139 493.2347 493.3555 493.4762 493.5970 493.7177 493.8384 493.9591 494.0797 494.2004 494.3210 494.4417 494.5623 494.6829 494.8034 494.9240 495.0446 495.1651 495.2856 495.4061 495.5266 495.6470 495.7675 495.8879 496.0083 496.1287 496.2491 496.3695 496.4898 496.6102 496.7305 496.8508 496.9711 497.0913 497.2116 497.3318 497.4521 497.5723 497.6925 497.8126 497.9328 498.0529 498.1731 498.2932 498.4133 498.5333 498.6534 498.7734 498.8935 499.0135 499.1335 499.2535 499.3734 499.4934 499.6133 499.7332 499.8531 499.9730 500.0929 500.2127 500.3326 500.4524 500.5722 500.6920 500.8117 500.9315 501.0512 501.1710 501.2907 501.4104 501.5300 501.6497 501.7693 501.8890 502.0086 502.1282 502.2477 502.3673 502.4868 502.6064 502.7259 502.8454 502.9648 503.0843 503.2038 503.3232 503.4426 503.5620 503.6814 503.8008 503.9201 504.0394 504.1587 504.2781 504.3973 504.5166 504.6359 504.7551 504.8743 504.9935 505.1127 505.2319 505.3510 505.4702 505.5893 505.7084 505.8275 505.9466 506.0656 506.1847 506.3037 506.4227 506.5417 506.6607 506.7796 506.8986 507.0175 507.1364 507.2553 507.3742 507.4930 507.6119 507.7307 507.8495 507.9683 508.0871 508.2059 508.3246 508.4433 508.5620 508.6807 508.7994 508.9181 509.0367 509.1554 509.2740 509.3926 509.5112 509.6297 509.7483 509.8668 509.9853 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20200106T153106.0Z 7310.646597 1 1 36.01 2 89.87 119.14 125.28 340.22 0.00 1 0.00 1 0 15 2.537e-02 2.504e-02 1.862e-02 1.851e-02 6.065986e+03 1.275552e+03 3.012893e+02 -6.000000e+00 1.447075e+03 278.49 -2.00 20.00 -2.00 505.32 0.00e+00 1.241804e-03 5.179448e-04 7.530095e-05 -6.000000e+00 7.185905e-04 278.49 -2.00 20.00 -2.00 500.31 0.00e+00 2.322971e+00 3.781469e-01 7.049187e-02 -6.000000e+00 5.149364e-01 223.85 -2.00 3.45 -2.00 501.94 0.00e+00 20.404 0.145 489.00 513.00 1 7.7936e+00 2.9068e-02 3.6367e-02 -6.0000e+00 3.9517e-02 9.5277e-02 7.2665e-03 2.3928e-03 -6.0000e+00 1.0170e-02 3.6072e-05 2.1661e-03 2.0832e-03 2.9552e-05 -6.0000e+00 3.0160e-03 -1.1611e-02 1.7151e-04 12 8 8 10 0 0 -1.84 20.99 4.26 -0.01161 0.00341 9 1 1 4 0 4000.000 26.41 19.99 20.99 2210 -1455 4416 -3381 -1694 -479 -2963 251 -773 2460 -589 -2049 -1356 -894 -558 -336 1818 -2807 98 -2380 2930 408 521 -1900 1559 1792 -535 3576 -1134 622 -5468 1776 -1636 2117 2916 -2242 169 -249 4966 -1841 4831 1717 -633 -1599 4994 742 -3360 -637 -2872 1967 -86 701 -48 -1762 3543 1255 1630 -2802 -608 634 -603 -421 -191 2707 -1555 5413 -1111 3603 -2994 952 -29 3691 -953 -2024 2175 -3498 3291 -1608 3410 -1151 -2421 -335 810 -1938 -3658 2718 -2904 833 -3081 3356 -919 -1990 1235 954 1643 -4123 5446 -5534 1897 177 3477 861 -5943 3718 196 -452 1687 -1165 -2313 3052 58 -2822 1233 1835 4870 -36 4327 2239 1404 -108 -1953 1685 -90 1769 -4521 5038 -3232 115 -4603 -1239 2066 -2975 3192 -2968 2867 -1945 2085 -1037 -216 -234 -127 334 694 1781 -2816 3242 -4508 3278 -75 -3312 900000 1991 -1375 4038 -3444 -1744 -498 -3215 267 -829 2532 -618 -2150 -1395 -907 -561 -339 1821 -3005 104 -2625 3085 442 566 -2119 1685 1932 -587 3719 -1212 638 -5879 1779 -1724 2206 3081 -2440 185 -263 5096 -1946 4932 1761 -671 -1728 5091 791 -3713 -677 -3065 1954 -85 674 -46 -1728 3359 1247 1647 -2993 -638 658 -633 -442 -201 2754 -1638 5251 -1133 3455 -3027 915 -28 3428 -933 -2021 2092 -3542 3074 -1554 3100 -1089 -2321 -316 761 -1888 -3656 2566 -2908 803 -3089 3161 -909 -2007 1215 940 1589 -4138 4845 -5194 1668 156 2960 764 -5630 3306 185 -434 1581 -1115 -2230 2797 55 -2809 1192 1779 4611 -36 4170 2209 1392 -107 -1954 1605 -87 1674 -4574 4648 -3245 112 -4680 -1215 1946 -2913 2904 -2854 2607 -1879 1970 -1030 -216 -237 -130 343 713 1818 -3005 3232 -4645 3163 -74 -3356 900000 SO 20200106T153304.0Z 7310.647963 3 1 36.01 2 89.53 119.44 125.40 340.76 0.00 1 0.00 1 0 15 1.871e-02 1.854e-02 1.493e-02 1.485e-02 5.947425e+03 1.023075e+03 5.165593e+02 -6.000000e+00 1.066996e+03 278.49 -2.00 20.00 -2.00 505.35 0.00e+00 1.862939e-03 4.121461e-04 8.360427e-05 -6.000000e+00 5.287777e-04 278.49 -2.00 20.00 -2.00 500.38 0.00e+00 2.053480e+00 3.011068e-01 2.499550e-02 -6.000000e+00 3.756628e-01 223.85 -2.00 3.45 -2.00 501.99 0.00e+00 19.885 0.134 489.00 513.00 1 7.6500e+00 2.3105e-02 3.4527e-02 -6.0000e+00 2.8895e-02 9.6397e-02 5.7494e-03 2.0409e-03 -6.0000e+00 7.3154e-03 4.5369e-05 1.0443e-03 1.6790e-03 6.7830e-05 -6.0000e+00 2.2148e-03 -1.4721e-02 1.6239e-04 12 8 8 10 0 0 10.17 21.00 1.19 -0.01472 -0.00748 9 1 1 4 0 4000.000 26.41 20.00 21.00 -2893 97 606 4373 -2577 -1720 -21 -1444 -1675 -159 3504 -1869 -807 -698 -1393 324 855 -3543 1255 -416 -894 1078 9 2571 2575 -198 -378 1609 1314 -1911 2312 365 1930 2379 1157 -2747 -2982 -153 -968 2468 213 318 1347 2696 -148 -2126 2064 -1131 2025 -2718 3971 -812 -1726 -791 -3151 -1093 -2858 -712 -731 1783 -442 1017 -842 2322 234 -1852 27 -475 529 -1892 1441 1318 685 2169 312 -2936 -1562 2781 1069 1794 3251 603 -1421 2111 1520 -1631 673 1454 2177 -97 2200 4598 -1 868 -267 2900 918 -771 -3236 -1633 412 2234 -1370 1263 -2800 -1755 -1328 -3200 42 -182 -1985 -958 309 1534 -1906 2413 2010 -506 -835 1591 -1437 -2159 -2545 1897 325 1464 39 -2463 2624 -1953 2549 -110 -1009 -927 -1872 1624 -424 2240 912 -1919 584 1123 -1995 -1652 183 -278 2948 4769 -1075 -2456 -2065 -2769 91 579 4148 -2695 -1826 -22 -1570 -1827 -170 3557 -1975 -832 -712 -1424 326 867 -3833 1321 -451 -982 1164 10 2668 2681 -212 -404 1664 1337 -1963 2240 360 1906 2400 1209 -3017 -3281 -163 -1027 2513 222 333 1407 2809 -160 -2351 2180 -1220 2080 -2862 3815 -801 -1699 -775 -3220 -1121 -3047 -753 -776 1848 -469 1065 -900 2401 246 -1959 28 -481 524 -1896 1387 1269 668 2100 310 -2995 -1552 2607 1008 1670 2981 570 -1380 1997 1458 -1576 637 1366 2029 -93 2065 4254 -1 840 -259 2673 842 -701 -2949 -1442 355 1913 -1250 1160 -2746 -1723 -1295 -3157 39 -174 -1952 -944 305 1508 -1953 2384 2007 -520 -858 1579 -1449 -2165 -2543 1814 317 1416 38 -2484 2513 -1953 2421 -106 -969 -883 -1804 1527 -402 2107 883 -1936 580 1118 -2060 -1706 185 -281 2844 4437 -1044 -2409 -2031 SO 20200106T153457.0Z 7310.649271 5 1 36.02 2 89.21 119.73 125.51 341.28 0.00 1 0.00 1 0 15 1.466e-02 1.459e-02 1.256e-02 1.250e-02 7.337510e+03 8.763012e+02 4.627989e+02 -6.000000e+00 8.356550e+02 278.49 -2.00 20.00 -2.00 505.34 0.00e+00 1.204448e-03 3.493185e-04 6.581995e-05 -6.000000e+00 4.142416e-04 278.49 -2.00 20.00 -2.00 500.41 0.00e+00 1.906854e+00 2.530447e-01 6.239612e-02 -6.000000e+00 2.946758e-01 223.85 -2.00 3.45 -2.00 502.03 0.00e+00 19.234 0.122 489.00 513.00 1 7.5793e+00 1.9465e-02 3.3049e-02 -6.0000e+00 2.2659e-02 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