File name: Pandora138s1_Rome-IIA_20241008_L2Fit_fwvt1c1d20220121p1-8.txt File generation date: 20241009T161813.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 138 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora138_OF_v3d20210407.txt Instrument calibration file used: Pandora138s1_CF_v1d20220121.txt Level 1 file used: Pandora138s1_Rome-IIA_20241008_L1_smca1c1d20220121p1-8.txt Full location name: CNR-IIA Montelibretti Rome Short location name: Rome-IIA Country of location: Italy Location latitude [deg]: 42.1057 Location longitude [deg]: 12.6402 Location altitude [m]: 92 Local noon date: 20241008 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1629 1778 Nominal wavelengths inside fitting window [nm]: 492.0975 492.2186 492.3398 492.4609 492.5821 492.7032 492.8242 492.9453 493.0664 493.1874 493.3084 493.4294 493.5504 493.6714 493.7923 493.9133 494.0342 494.1551 494.2760 494.3968 494.5177 494.6385 494.7593 494.8801 495.0009 495.1217 495.2424 495.3632 495.4839 495.6046 495.7253 495.8459 495.9666 496.0872 496.2078 496.3284 496.4490 496.5696 496.6901 496.8107 496.9312 497.0517 497.1722 497.2926 497.4131 497.5335 497.6539 497.7743 497.8947 498.0151 498.1354 498.2557 498.3760 498.4963 498.6166 498.7369 498.8571 498.9773 499.0976 499.2177 499.3379 499.4581 499.5782 499.6984 499.8185 499.9386 500.0586 500.1787 500.2987 500.4188 500.5388 500.6588 500.7787 500.8987 501.0186 501.1385 501.2584 501.3783 501.4982 501.6181 501.7379 501.8577 501.9775 502.0973 502.2171 502.3368 502.4566 502.5763 502.6960 502.8157 502.9353 503.0550 503.1746 503.2942 503.4138 503.5334 503.6530 503.7725 503.8921 504.0116 504.1311 504.2505 504.3700 504.4894 504.6089 504.7283 504.8477 504.9671 505.0864 505.2058 505.3251 505.4444 505.5637 505.6829 505.8022 505.9214 506.0407 506.1599 506.2791 506.3982 506.5174 506.6365 506.7556 506.8747 506.9938 507.1129 507.2319 507.3510 507.4700 507.5890 507.7080 507.8269 507.9459 508.0648 508.1837 508.3026 508.4215 508.5403 508.6592 508.7780 508.8968 509.0156 509.1344 509.2531 509.3719 509.4906 509.6093 509.7280 509.8466 509.9653 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241008T053908.4Z 9047.235513 53 1 14.33 2 86.33 101.60 144.10 79.93 0.00 1 0.00 1 0 29 3.304e-03 3.271e-03 1.378e-04 1.376e-04 1.953846e+04 1.082546e+01 1.272235e+03 -6.000000e+00 1.971102e+02 283.70 -2.00 20.00 -2.00 505.37 0.00e+00 1.348273e-03 3.959405e-06 1.062076e-04 -6.000000e+00 9.568041e-05 283.70 -2.00 20.00 -2.00 500.73 0.00e+00 1.011308e+00 2.774988e-03 1.203572e-01 -6.000000e+00 6.746764e-02 226.46 -2.00 3.53 -2.00 502.29 0.00e+00 12.077 0.033 489.00 513.00 1 1.6269e+00 2.1347e-04 2.0657e-02 -6.0000e+00 5.2025e-03 -2.1577e-02 5.2244e-05 3.1763e-03 -6.0000e+00 1.3135e-03 6.1729e-02 7.8994e-04 1.4737e-05 1.0686e-04 -6.0000e+00 4.2393e-04 -3.6456e-03 4.0500e-05 10 0 0 10 0 0 8.93 18.83 1.05 -0.00365 0.00183 529 116 2 2 0 26.880 15.00 18.83 19.97 22.09 21.48 18.3 963.52 -412 -123 230 326 319 560 733 668 455 227 191 30 -241 -295 -185 -209 -126 157 209 -30 38 190 157 363 291 45 57 -56 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-379 -196 107 109 -54 176 426 456 606 796 607 189 57 23 26 294 472 258 174 191 -34 120 218 -252 -385 -146 -264 -287 110 69 -56 224 365 252 300 325 311 284 156 -90 -362 -335 -330 SQ 20241008T053922.9Z 9047.235681 53 2 14.33 2 86.29 101.64 144.05 79.98 0.00 1 0.00 1 0 22 3.273e-03 3.241e-03 1.385e-04 1.383e-04 1.936445e+04 1.089447e+01 1.261712e+03 -6.000000e+00 1.952456e+02 283.70 -2.00 20.00 -2.00 505.38 0.00e+00 1.331568e-03 3.982546e-06 1.055251e-04 -6.000000e+00 9.477464e-05 283.70 -2.00 20.00 -2.00 500.73 0.00e+00 1.011253e+00 2.792331e-03 1.200756e-01 -6.000000e+00 6.682753e-02 226.46 -2.00 3.53 -2.00 502.29 0.00e+00 11.990 0.032 489.00 513.00 1 1.6512e+00 2.1485e-04 2.0514e-02 -6.0000e+00 5.1531e-03 -2.1171e-02 5.2504e-05 3.1635e-03 -6.0000e+00 1.3010e-03 6.1025e-02 7.1947e-04 1.4863e-05 1.0633e-04 -6.0000e+00 4.1992e-04 -2.5469e-03 3.5854e-05 10 0 0 10 0 0 7.39 18.83 1.03 -0.00255 0.00244 529 116 2 2 0 26.880 15.00 18.83 19.97 22.09 21.48 18.3 963.52 -363 -120 212 347 345 567 725 666 478 215 160 1 -282 -254 -176 -235 -127 134 207 -58 31 177 175 340 284 42 72 -6 -481 -557 -232 -298 -147 269 105 -270 -232 -68 -122 -71 33 119 150 295 325 235 88 -20 -134 -421 -580 -558 -577 -344 -52 -34 7 44 136 254 423 434 319 272 145 -35 -154 -112 -273 -444 -374 -330 -321 -147 -169 -496 -607 -396 -353 -391 -272 -215 -336 -179 -20 -128 -141 -41 132 259 372 617 659 378 258 212 38 -74 -403 -770 -821 -733 -429 -210 -358 -398 -352 -353 -185 124 105 -33 197 436 440 603 747 587 223 94 55 23 284 456 228 195 193 -42 94 232 -272 -373 -85 -282 -281 143 54 -61 196 314 249 260 282 277 282 170 -64 -334 -314 -334 -344 -112 203 334 341 558 723 668 480 215 157 1 -280 -251 -174 -228 -126 135 206 -59 32 181 179 350 293 43 74 -6 -478 -558 -230 -299 -147 274 107 -277 -237 -69 -123 -71 33 121 154 305 338 244 91 -21 -134 -424 -573 -544 -563 -339 -53 -34 7 45 140 257 428 441 325 276 146 -35 -155 -111 -269 -445 -374 -324 -317 -146 -168 -491 -593 -391 -344 -380 -265 -211 -333 -175 -20 -127 -140 -40 130 255 367 610 647 365 248 201 35 -68 -367 -703 -764 -688 -409 -204 -358 -395 -350 -351 -184 124 105 -33 200 445 442 611 764 604 229 95 55 24 284 457 230 193 191 -41 93 233 -273 -372 -84 -280 -277 143 55 -63 202 328 258 271 295 290 293 176 -66 -347 -324 -347 SQ 20241008T053937.2Z 9047.235848 53 3 14.28 2 86.24 101.68 144.01 80.03 0.00 1 0.00 1 0 22 3.213e-03 3.183e-03 1.370e-04 1.368e-04 1.921621e+04 1.075114e+01 1.254648e+03 -6.000000e+00 1.916874e+02 283.70 -2.00 20.00 -2.00 505.37 0.00e+00 1.314598e-03 3.935203e-06 1.043535e-04 -6.000000e+00 9.304495e-05 283.70 -2.00 20.00 -2.00 500.74 0.00e+00 9.990134e-01 2.757639e-03 1.183867e-01 -6.000000e+00 6.560211e-02 226.46 -2.00 3.53 -2.00 502.29 0.00e+00 11.904 0.032 489.00 513.00 1 1.6431e+00 2.1216e-04 2.0323e-02 -6.0000e+00 5.0588e-03 -1.9912e-02 5.1905e-05 3.1296e-03 -6.0000e+00 1.2769e-03 6.2351e-02 5.7828e-04 1.4704e-05 1.0512e-04 -6.0000e+00 4.1225e-04 -7.6639e-03 7.5782e-05 10 0 0 10 0 0 6.57 18.83 1.01 -0.00766 -0.00365 529 116 2 2 0 26.880 15.00 18.83 20.06 22.09 21.48 18.3 963.52 -373 -106 231 311 332 543 724 640 479 209 179 40 -235 -249 -154 -198 -159 135 180 -65 6 160 157 332 302 64 78 -24 -483 -566 -217 -281 -176 263 107 -305 -259 -65 -98 -73 48 161 170 285 313 249 78 -4 -143 -435 -582 -549 -523 -345 -82 -16 -3 60 112 253 417 411 304 248 163 -24 -158 -94 -247 -486 -367 -312 -311 -141 -161 -514 -580 -396 -383 -381 -261 -184 -303 -181 17 -91 -151 -54 141 238 373 610 645 353 268 249 59 -88 -388 -736 -847 -748 -378 -234 -354 -356 -353 -350 -142 125 95 -49 194 396 436 591 773 559 165 104 45 10 272 443 211 188 193 -53 69 208 -299 -344 -65 -256 -279 151 73 -63 171 318 230 268 262 262 261 161 -84 -332 -297 -267 -348 -101 219 303 324 541 730 634 475 211 178 39 -230 -242 -150 -194 -159 134 182 -67 6 162 159 337 307 66 79 -25 -484 -559 -212 -278 -178 264 109 -316 -267 -66 -100 -74 48 165 176 291 322 255 80 -4 -145 -432 -581 -540 -514 -343 -81 -16 -3 61 114 259 427 421 312 254 165 -24 -161 -95 -245 -481 -362 -309 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