File name: Pandora147s1_SWDetroitMI_20220423_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20260322T230734.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20220423_L1_smca1c1d20210609p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20220423 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220423T115823.6Z 8148.498884 165 1 48.75 2 76.48 85.12 67.43 181.12 0.00 1 0.00 1 0 17 2.267e-01 6.139e-03 1.177e-01 2.562e-03 5.406442e-01 1.344219e-03 6.200524e-03 -6.000000e+00 1.295550e-01 229.02 -2.00 3.54 -2.00 320.76 0.00e+00 1.482320e-03 5.399285e-04 8.867793e-04 -6.000000e+00 5.588006e-03 279.33 -2.00 20.00 -2.00 320.22 0.00e+00 4.175 0.001 302.00 328.00 3 1.4056e+00 4.2020e-03 5.0175e-02 -6.0000e+00 3.2341e-01 1.1529e-02 5.4334e-03 2.9398e-02 -6.0000e+00 3.5029e-01 -3.1092e-02 5.3123e-03 1.5486e-02 -6.0000e+00 2.0805e-01 5.8043e-03 2.6424e-03 4.9810e-03 -6.0000e+00 8.8805e-02 1.1918e-03 -4.6427e-04 7.3573e-05 5.3950e-05 -6.0000e+00 5.9317e-03 2.7142e-03 1.2059e-05 10 0 0 10 0 0 99.23 16.44 0.19 0.00271 -0.00077 167 39 1 5 0 291.890 22.50 15.00 16.44 15.02 19.8 1003.54 -117747 88043 -77001 10772 -92664 -55828 -87253 -70687 -77334 -32988 -46480 -49814 -30875 -25293 4444 -31580 3462 -22861 8732 -27123 123 -27923 5189 -18199 2556 -15692 3101 -16106 -7763 -10871 -5027 -3278 -2930 2234 -4053 -1977 -8850 1848 -5613 2738 -3177 4771 -1628 6090 -447 3097 -1368 1971 -1930 1630 2292 1192 1895 3098 1336 2188 1370 680 2025 -2212 2511 -354 4647 2125 3556 -61 886 -1193 18 312 1473 690 1068 1102 238 -792 -873 -512 -1644 -581 -1541 -274 -2232 -1338 -1599 -210 -200 458 124 1344 206 740 -21 -608 -804 -55 208 644 870 -36 -77 -732 -813 -991 -458 -1203 -648 -1030 -115 -233 631 374 753 -244 -369 -233 96 107 218 144 -93 383 232 537 390 542 -456 431 177 328 -174 -139 -386 -83 -226 185 -143 320 17 183 -26 -402 -223 -1551 220 -909 59 -1200 -469 -1050 -819 -1107 -337 -570 -668 -407 -396 65 -796 70 -659 200 -949 3 -1040 141 -678 85 -670 114 -706 -300 -437 -213 -162 -167 135 -259 -118 -595 130 -520 262 -372 562 -216 776 -62 419 -197 278 -291 246 373 219 380 666 313 530 348 176 508 -565 618 -96 1345 710 1264 -22 304 -415 7 130 687 346 542 540 109 -333 -332 -186 -637 -258 -809 -163 -1502 -950 -1210 -168 -170 404 111 1166 170 562 -15 -427 -605 -47 202 712 1069 -46 -94 -823 -826 -980 -483 -1371 -769 -1301 -154 -345 943 598 1215 -385 -594 -351 142 163 352 227 -150 656 384 857 597 797 -646 599 269 559 -327 -257 -744 -168 -486 421 -337 768 42 436 -58 -867 -458 SS 20220423T120951.9Z 8148.506851 168 1 48.57 2 74.36 87.01 67.50 183.86 0.00 1 0.00 1 0 17 1.229e-01 5.333e-03 3.246e-02 1.599e-03 4.765127e-01 8.329203e-04 5.541374e-03 -6.000000e+00 7.024403e-02 229.02 -2.00 3.54 -2.00 320.29 0.00e+00 1.419930e-03 2.859207e-04 5.942885e-04 -6.000000e+00 3.029343e-03 279.33 -2.00 20.00 -2.00 319.70 0.00e+00 3.644 0.001 302.00 328.00 3 1.1532e+00 2.4795e-03 4.3800e-02 -6.0000e+00 1.7535e-01 5.1915e-03 3.0358e-03 2.5455e-02 -6.0000e+00 1.8992e-01 -1.7955e-02 2.7155e-03 1.3178e-02 -6.0000e+00 1.1280e-01 5.4236e-04 1.3900e-03 4.2250e-03 -6.0000e+00 4.8154e-02 2.7050e-03 -3.6110e-04 4.6531e-05 4.4750e-05 -6.0000e+00 3.2159e-03 2.2322e-03 2.3131e-05 10 0 0 10 0 0 99.54 16.44 0.22 0.00223 -0.00048 304 70 1 5 0 159.740 22.50 15.00 16.44 16.27 19.9 1013.94 -53211 -38354 -40207 -34320 -41151 -52251 -41290 -36353 -31790 -31965 -38216 -23365 -31422 -14837 -9304 -11609 -5601 -5989 -8382 -1557 -6691 -5538 -4151 -1778 -718 -5422 -3432 -4573 -5782 -4274 -3500 -2618 1772 -711 -366 -6568 -4777 -2581 -929 174 -622 59 532 543 934 1197 235 988 -419 986 537 2253 2062 1805 959 1742 1718 323 -200 -645 386 1903 2037 3040 1632 433 -43 -1083 1 598 1011 845 758 362 395 -77 -927 -1623 -1198 -1356 -1153 -1092 -1593 -2035 -1336 -540 150 475 722 1189 698 455 -201 -596 -319 14 67 756 640 200 -400 -746 -888 -730 -606 -944 -763 -697 -445 221 406 387 428 98 -36 -306 -71 133 385 184 -5 124 265 306 351 262 -201 488 372 231 65 -216 -249 -180 -178 26 -144 264 142 150 -71 -193 -407 -747 -556 -652 -530 -622 -823 -605 -572 -550 -613 -810 -444 -754 -372 -271 -413 -210 -245 -379 -70 -330 -271 -203 -91 -40 -304 -215 -284 -345 -251 -224 -175 130 -59 -30 -540 -406 -248 -107 24 -100 10 96 101 175 227 46 191 -84 199 117 534 534 506 288 540 551 106 -65 -206 123 639 761 1255 730 192 -18 -451 0 293 559 499 455 211 216 -38 -418 -701 -536 -697 -688 -741 -1201 -1636 -1131 -488 143 471 724 1164 645 389 -160 -462 -261 13 70 892 768 248 -477 -889 -963 -772 -686 -1152 -974 -940 -584 314 632 640 710 157 -54 -430 -97 188 575 294 -8 201 414 462 552 396 -290 691 569 361 111 -392 -467 -352 -370 57 -329 614 335 349 -157 -406 -822 SS 20220423T122119.9Z 8148.514813 171 1 48.56 2 72.24 88.92 67.66 186.59 0.00 1 0.00 1 0 25 6.482e-02 5.400e-03 1.818e-02 1.154e-03 4.270044e-01 5.899805e-04 5.028240e-03 -6.000000e+00 3.705124e-02 229.02 -2.00 3.54 -2.00 319.86 0.00e+00 1.244710e-03 1.738404e-04 4.326313e-04 -6.000000e+00 1.597961e-03 279.34 -2.00 20.00 -2.00 319.24 0.00e+00 3.234 0.001 302.00 328.00 3 1.0786e+00 1.6959e-03 3.8982e-02 -6.0000e+00 9.2492e-02 4.2220e-03 2.0171e-03 2.2698e-02 -6.0000e+00 1.0018e-01 -1.1073e-02 1.6838e-03 1.1498e-02 -6.0000e+00 5.9498e-02 -2.5052e-03 8.8100e-04 3.5731e-03 -6.0000e+00 2.5398e-02 4.5359e-03 -3.4924e-04 3.3341e-05 3.8837e-05 -6.0000e+00 1.6963e-03 2.4265e-03 1.9449e-05 10 0 0 10 0 0 99.63 16.42 0.19 0.00243 -0.00020 404 94 1 5 0 120.180 22.50 15.01 16.42 17.02 19.9 1020.34 -19092 -23928 -11920 -29298 -8935 -34238 -7155 -30414 -4587 -23731 -934 -20444 -4937 -12286 -831 -8504 -769 -5771 1580 -522 -2568 -499 -2898 1291 -3936 1515 -3988 -474 -6127 84 -5099 3204 -2528 3204 -3386 -2569 -5453 -1254 -1359 -70 -1088 -873 189 -805 856 61 621 -956 781 -1060 1726 128 1675 606 1928 715 1704 83 868 -182 1024 903 1978 2567 1742 548 -630 -493 -764 986 286 911 236 837 -68 406 -1453 -800 -1459 -806 -1180 -900 -1724 -1959 -1244 -823 72 191 810 740 941 371 64 -630 141 -115 312 711 926 -18 7 -984 -1017 -609 -397 -1052 -871 -626 -513 289 388 636 186 338 -218 -124 -321 229 213 305 -84 180 114 271 409 337 -237 357 349 198 175 -353 -232 -288 -58 -66 -75 152 278 3 129 -347 -319 -312 -487 -234 -686 -155 -711 -129 -706 -94 -651 -21 -575 -136 -444 -32 -421 -39 -331 90 -32 -168 -32 -193 88 -306 118 -340 -38 -491 6 -432 285 -270 355 -393 -279 -640 -163 -215 -13 -237 -205 46 -204 215 16 159 -248 200 -282 475 39 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