File name: Pandora147s1_SWDetroitMI_20220521_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20260322T231242.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20220521_L1_smca1c1d20210609p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20220521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220521T113556.0Z 8176.483287 197 1 35.55 2 75.31 75.83 65.95 192.65 0.00 1 0.00 1 0 17 2.443e-01 1.029e-02 2.023e-01 7.531e-03 5.367347e-01 4.001574e-03 6.257061e-03 -6.000000e+00 1.409736e-01 231.32 -2.00 3.54 -2.00 320.62 0.00e+00 3.313414e-03 1.528595e-03 1.329526e-03 -6.000000e+00 6.117626e-03 282.44 -2.00 20.00 -2.00 320.01 0.00e+00 3.863 0.001 302.00 328.00 3 3.6004e+00 1.2393e-02 4.7867e-02 -6.0000e+00 3.5352e-01 6.7012e-02 1.5596e-02 2.9341e-02 -6.0000e+00 3.8214e-01 -1.1840e-01 1.4289e-02 1.5914e-02 -6.0000e+00 2.2680e-01 4.5560e-02 7.1782e-03 5.7969e-03 -6.0000e+00 9.7303e-02 1.7562e-04 -4.6225e-04 2.1570e-04 6.6094e-05 -6.0000e+00 6.4496e-03 -1.8904e-03 1.3623e-05 12 9 9 12 1 1 95.44 16.25 0.31 -0.00189 -0.00536 11 4 1 5 0 2947.530 22.29 15.01 16.25 29.88 21.4 1100.00 900000 165112 -64686 -66253 269 -108690 -32209 -106292 -62708 -20883 -5103 -30539 -28944 -48391 -54530 32297 -34580 -2591 -10012 31867 -8750 50345 -10371 15269 -12826 9274 -13248 -3515 -19410 -7124 2850 10588 -8359 -7089 8314 -9342 -20676 -9787 18341 -9026 2875 -8016 -921 4127 7749 3498 2001 1571 -8182 -718 4434 1905 8307 8226 2009 5589 -737 722 -2550 1706 537 4694 160 4525 3220 1420 152 -1664 233 3671 2025 1169 -1292 2338 -1282 387 -423 -1424 429 -2746 -1771 -2005 -2091 -3739 -436 -1689 1656 1291 1672 1041 625 641 370 -2327 -1351 -1790 57 1729 1303 -332 -1481 -619 -2059 -147 368 -314 -1929 -1149 -1051 869 -205 994 364 -149 -167 862 -9 328 -31 160 393 123 372 225 1155 343 -330 -194 532 278 52 -207 -155 -509 64 -497 -366 585 325 391 351 -860 -424 900000 1212 -980 -1034 2 -2195 -331 -2390 -1036 -266 -57 -463 -510 -1221 -1827 585 -1301 -77 -349 775 -333 1134 -405 491 -589 362 -669 -158 -980 -320 129 525 -579 -540 538 -682 -1765 -862 1481 -1164 379 -1202 -136 636 1167 559 330 263 -1547 -130 824 380 1704 1826 506 1410 -205 200 -715 447 144 1289 52 1568 1220 540 56 -614 89 1543 981 610 -701 1182 -627 168 -177 -577 179 -1285 -961 -1249 -1449 -2802 -335 -1414 1423 1162 1520 934 531 503 271 -1704 -1043 -1575 57 1926 1536 -411 -1780 -713 -2174 -147 392 -362 -2368 -1482 -1369 1220 -320 1647 615 -245 -257 1236 -13 477 -47 264 660 202 591 346 1688 514 -475 -275 811 451 93 -395 -307 -1060 135 -1113 -845 1363 768 907 775 -1818 -897 SS 20220521T114643.4Z 8176.490780 200 1 48.43 2 73.37 77.51 66.38 195.26 0.00 1 0.00 1 0 17 1.776e-01 7.428e-03 1.886e-01 6.466e-03 4.833900e-01 3.430667e-03 5.638873e-03 -6.000000e+00 1.031417e-01 231.32 -2.00 3.54 -2.00 320.46 0.00e+00 2.925634e-03 1.232162e-03 8.380600e-04 -6.000000e+00 4.446385e-03 282.44 -2.00 20.00 -2.00 319.84 0.00e+00 3.439 0.001 302.00 328.00 3 3.4533e+00 1.0468e-02 4.2723e-02 -6.0000e+00 2.5890e-01 -5.8720e-03 1.2964e-02 2.6179e-02 -6.0000e+00 2.8005e-01 -9.7180e-03 1.1682e-02 1.3944e-02 -6.0000e+00 1.6550e-01 5.5248e-04 5.9299e-03 5.1280e-03 -6.0000e+00 7.0712e-02 3.2348e-04 -4.6292e-04 1.9016e-04 5.5452e-05 -6.0000e+00 4.7655e-03 -1.9310e-03 3.8716e-06 11 9 0 11 8 0 99.98 16.25 0.26 -0.00193 -0.00541 70 16 1 5 0 691.720 22.29 15.00 16.25 30.42 21.5 1100.00 900000 45976 -93013 17087 -86295 99342 -24510 900000 -33943 -19629 -31037 413 -40657 68558 17113 9667 15413 8738 -12721 -17285 17372 -22253 5411 -24735 -4470 -19309 16483 -10147 18118 -10288 10462 800 5149 -291 13228 -4236 388 -5046 -4558 136 817 -561 -5246 2719 1122 6476 -2974 2944 -1439 607 1121 3387 -741 3047 -1338 2949 -2882 3267 -1067 -182 3238 -39 428 -540 5173 -438 633 -2214 -310 612 1675 732 1584 842 392 803 -774 -590 -1620 -268 -1128 -28 -2731 -625 -1704 59 213 101 674 1127 -511 1553 20 406 -198 967 -199 319 643 -54 17 -434 -1045 -1980 -814 -940 -679 -1243 -299 -269 711 -185 554 -135 -52 -1165 384 338 603 216 239 409 252 136 639 774 -579 740 156 249 -94 190 -477 19 -316 181 -184 455 -211 70 -17 -434 -110 900000 290 -2191 144 -1775 626 -275 900000 -535 -296 -543 6 -904 712 348 241 409 270 -528 -797 594 -1137 212 -1395 -222 -1185 733 -579 745 -563 514 50 357 -22 930 -336 31 -463 -506 18 120 -91 -936 464 197 1098 -562 529 -275 117 230 753 -188 801 -391 856 -917 990 -332 -55 955 -13 155 -210 2039 -188 254 -897 -129 287 840 396 864 448 206 380 -336 -243 -700 -131 -647 -18 -1912 -455 -1329 49 187 93 622 1016 -441 1272 15 300 -156 848 -192 347 776 -68 21 -478 -1103 -2050 -891 -1108 -836 -1549 -392 -386 1108 -309 925 -219 -79 -1665 554 503 904 347 394 662 415 217 970 1125 -812 1008 231 409 -169 344 -899 37 -659 401 -423 1060 -500 163 -38 -918 -222 SS 20220521T115240.3Z 8176.494911 204 1 48.38 2 72.29 78.44 66.66 196.69 0.00 1 0.00 1 0 17 2.007e-01 1.131e-02 2.385e-01 1.129e-02 4.553090e-01 5.915731e-03 5.387668e-03 -6.000000e+00 1.156902e-01 231.32 -2.00 3.54 -2.00 320.28 0.00e+00 2.414674e-03 1.993245e-03 1.178397e-03 -6.000000e+00 5.011304e-03 282.44 -2.00 20.00 -2.00 319.63 0.00e+00 3.242 0.001 302.00 328.00 3 4.2784e+00 1.7687e-02 4.0382e-02 -6.0000e+00 2.9011e-01 6.7240e-03 2.1582e-02 2.4973e-02 -6.0000e+00 3.1349e-01 -1.4280e-02 1.8558e-02 1.2968e-02 -6.0000e+00 1.8618e-01 6.7079e-03 9.4780e-03 4.1091e-03 -6.0000e+00 7.9341e-02 1.7359e-04 -1.0073e-03 3.3093e-04 4.7635e-05 -6.0000e+00 5.2539e-03 -6.5780e-04 -7.1187e-05 12 9 8 11 8 0 99.99 16.25 0.23 -0.00066 -0.00823 64 15 1 5 0 755.800 22.29 14.99 16.25 30.83 21.5 1100.00 -116279 -19979 79088 30857 -32460 -46414 -85188 77367 -19200 -38425 -32879 -6164 24248 12833 68780 13265 45639 22392 1545 -10035 36957 -1116 11768 -28660 10385 -17298 -234 -12394 28855 24747 -6984 4315 6969 -108 1422 16043 -16686 7074 -11066 7447 -6420 5855 -6851 3795 1 6782 -6534 6843 1735 5018 4262 6804 -3057 6366 2326 -1792 919 3191 194 59 876 668 6880 -2734 4841 -4856 138 -4973 1894 883 2661 -127 -1644 148 2589 -2647 670 1835 -2235 2469 136 -1700 -1623 -1135 -1429 -763 -1159 1272 -1335 1387 467 1047 -181 -548 -1193 1245 -635 763 700 354 -444 -520 -1137 -2453 487 -2487 254 -1152 -369 585 1099 1038 432 -14 976 -336 136 -796 979 340 379 -679 -78 448 95 1151 -622 773 -204 415 -844 -277 -847 -352 -471 460 -467 551 123 296 -13 -221 -27 -3775 -312 870 340 -583 -887 -2344 852 -367 -979 -819 -121 407 297 1116 423 1243 789 72 -558 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