File name: Pandora147s1_SWDetroitMI_20220529_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20260322T231340.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20220529_L1_smca1c1d20210609p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20220529 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220529T113010.8Z 8184.479292 92 1 48.70 2 75.57 73.68 69.09 82.38 0.00 1 0.00 1 0 25 4.819e-01 1.471e-02 2.592e-01 1.089e-02 5.424136e-01 5.949604e-03 6.261370e-03 -6.000000e+00 2.798357e-01 231.81 -2.00 3.54 -2.00 320.90 0.00e+00 1.645101e-03 2.460949e-03 5.356126e-04 -6.000000e+00 1.329846e-02 283.26 -2.00 20.00 -2.00 320.30 0.00e+00 3.927 0.001 302.00 328.00 3 3.2816e+00 1.9210e-02 4.8725e-02 -6.0000e+00 7.0328e-01 -3.4751e-03 2.4681e-02 3.0178e-02 -6.0000e+00 7.6041e-01 -5.2405e-02 2.2779e-02 1.5050e-02 -6.0000e+00 4.4951e-01 2.5151e-02 1.1205e-02 5.0198e-03 -6.0000e+00 1.9283e-01 2.2943e-04 -7.3361e-04 3.2357e-04 5.2960e-05 -6.0000e+00 1.2712e-02 4.3954e-04 7.2264e-06 12 8 8 10 0 0 99.99 16.31 0.44 0.00044 -0.00507 140 32 1 5 0 347.820 22.40 15.01 16.31 24.91 21.3 1058.76 -140205 900000 -37848 241288 -147632 900000 -138763 242414 -83453 900000 -151572 900000 -107137 246999 -60508 7736 -50124 65901 -12662 -8161 9967 -35810 10250 -35326 -13888 -5647 6688 -9938 58793 -17524 40934 -14733 40652 -10164 24967 -4451 14330 -24760 16587 -17178 7038 -1676 4655 5558 -5035 13453 659 12157 -5255 4372 -2306 16756 -1237 9338 116 12076 2774 8478 -4130 10517 -4205 1375 -4403 7453 2347 196 2006 -3842 2168 1859 4124 -463 6254 -1312 4156 -4763 7592 -3465 3619 -1923 1363 -2239 -34 -3554 -1820 -1956 -158 654 -1038 1208 -14 2770 -2156 1576 -2056 428 -150 1711 -1063 -52 -880 758 -2327 -93 -1025 -736 -1234 -685 -533 -907 -318 316 1404 -1055 539 -392 -146 -250 813 -625 361 -899 1631 89 1199 -149 1064 1259 1426 38 764 -93 -424 567 -337 240 -738 894 -233 138 -501 389 -1305 -2338 900000 -402 2560 -3357 900000 -2805 2572 -1328 900000 -5284 900000 -2977 2621 -1651 135 -1697 846 -352 -242 259 -1411 272 -1517 -526 -211 241 -397 1185 -726 1108 -782 1510 -668 1148 -261 731 -2066 1173 -1988 740 -209 577 708 -721 1629 92 1536 -811 637 -388 2602 -242 1783 26 2507 656 1924 -1044 2242 -1048 346 -1316 2228 798 67 644 -1298 728 717 1765 -222 2853 -625 1749 -1978 2518 -1229 1256 -814 655 -1279 -21 -2440 -1304 -1510 -127 546 -856 998 -11 1963 -1498 1028 -1481 342 -138 1769 -1207 -61 -1032 800 -2287 -87 -1029 -793 -1400 -818 -680 -1277 -492 521 2316 -1728 818 -563 -205 -362 1236 -1025 600 -1481 2528 136 1731 -209 1409 1644 2016 61 1339 -176 -835 1158 -738 558 -1792 2176 -581 337 -1169 849 -2761 SS 20220529T115819.3Z 8184.498834 108 1 48.39 2 70.52 78.03 63.99 86.69 0.00 1 0.00 1 0 17 5.263e-02 5.247e-03 8.283e-03 6.861e-04 4.187885e-01 3.532060e-04 4.905721e-03 -6.000000e+00 3.042724e-02 231.81 -2.00 3.54 -2.00 319.56 0.00e+00 1.138894e-03 9.703293e-05 4.684142e-04 -6.000000e+00 1.322122e-03 283.26 -2.00 20.00 -2.00 318.87 0.00e+00 2.965 0.000 302.00 328.00 3 6.2515e-01 1.0033e-03 3.6777e-02 -6.0000e+00 7.6375e-02 7.4470e-03 1.1786e-03 2.2320e-02 -6.0000e+00 8.2508e-02 -1.4198e-02 9.2116e-04 1.1107e-02 -6.0000e+00 4.8972e-02 -4.8873e-04 4.8316e-04 3.2885e-03 -6.0000e+00 2.1010e-02 9.2576e-03 -3.4897e-04 1.9644e-05 3.3835e-05 -6.0000e+00 1.3892e-03 -3.1298e-03 4.2340e-05 10 0 0 10 0 0 98.26 16.31 0.24 -0.00313 -0.00575 443 103 1 5 0 109.220 22.40 14.99 16.31 25.33 21.2 1060.74 900000 -22982 -9341 -20920 -10931 -23330 -16320 -20467 -9280 -19505 -11205 -16906 -8816 -12130 -5120 -3500 -3438 -1620 -1931 -67 -2382 284 -3844 919 -1949 891 -2870 -1220 -5097 -1751 -2381 1463 -139 613 -3437 -3725 -3770 -2863 -761 -598 -146 -628 309 -323 537 36 339 -843 95 -700 1042 534 1448 1325 1268 791 1318 738 286 139 454 1442 1594 2813 1597 605 -257 -274 33 1284 536 856 336 495 -4 -59 -691 -1222 -1239 -871 -994 -1049 -1496 -1951 -1261 -885 -120 141 679 559 799 344 -21 -296 174 -127 240 737 625 -51 -303 -664 -1030 -438 -452 -962 -968 -699 -452 178 344 519 264 236 -81 -9 -23 187 91 221 -90 75 258 386 582 306 -46 441 566 208 89 -226 -159 -210 -57 -46 -59 227 119 48 -122 -311 -335 900000 -589 -227 -575 -248 -552 -370 -542 -252 -647 -353 -577 -315 -541 -257 -203 -221 -109 -140 -5 -191 22 -317 77 -181 86 -295 -121 -494 -161 -236 159 -17 83 -480 -491 -519 -449 -141 -122 -34 -159 81 -88 146 10 94 -235 26 -198 308 174 507 498 505 328 560 319 122 58 191 639 780 1504 918 341 -137 -141 18 766 365 621 250 356 -3 -36 -385 -643 -668 -529 -699 -835 -1319 -1677 -1140 -858 -123 150 731 592 795 316 -20 -263 160 -120 256 882 828 -70 -398 -804 -1141 -471 -521 -1199 -1262 -958 -654 256 537 854 436 372 -120 -14 -33 278 144 344 -146 119 397 624 896 452 -64 604 826 335 144 -387 -279 -384 -110 -95 -127 457 243 97 -255 -619 -641 SS 20220529T120852.9Z 8184.506168 111 1 4.79 2 68.60 79.67 62.07 88.34 0.00 1 0.00 1 0 17 6.033e-02 9.495e-03 4.033e-02 5.994e-03 3.848887e-01 3.075040e-03 4.600683e-03 -6.000000e+00 3.487270e-02 231.81 -2.00 3.54 -2.00 318.51 0.00e+00 4.777290e-04 6.163476e-04 4.812548e-04 -6.000000e+00 1.515928e-03 283.26 -2.00 20.00 -2.00 317.78 0.00e+00 2.716 0.000 302.00 328.00 3 3.1094e+00 8.3980e-03 3.3747e-02 -6.0000e+00 8.7532e-02 2.8453e-02 9.5456e-03 2.0526e-02 -6.0000e+00 9.4573e-02 -1.8394e-02 6.5091e-03 1.0019e-02 -6.0000e+00 5.6133e-02 3.8068e-03 3.4198e-03 2.7819e-03 -6.0000e+00 2.4072e-02 1.0103e-03 -6.4328e-04 1.6762e-04 2.8288e-05 -6.0000e+00 1.5929e-03 -1.3870e-03 7.1099e-06 12 9 9 12 1 1 99.71 16.31 0.34 -0.00139 -0.00622 3 10 1 5 0 1155.090 22.40 15.00 16.31 25.37 21.4 1062.55 900000 -20611 -18886 14717 -18601 6064 -34909 14929 -27963 2029 -15790 4354 -19451 -6550 -7381 5279 -5452 2948 -1706 -3472 882 1150 4336 -952 2283 -2747 3266 -4683 3129 -7731 6708 -1453 5567 -3076 21 -9728 -1683 -1947 558 939 2520 2186 779 -1217 -1356 1836 -2811 2223 -1782 1420 -504 3239 1248 1308 453 3351 -365 1595 -1974 702 -938 2547 1886 2520 2690 195 -366 -1988 809 -135 1005 439 1632 -834 549 -2195 -75 -2211 -1262 -1882 -232 -1853 -1217 -1910 -1480 -868 -229 444 856 1111 -206 1254 -1114 34 -1038 238 -133 1353 697 -44 -787 -663 -1869 -574 -291 -804 -928 -434 266 -458 345 552 975 465 364 -356 956 -493 526 -125 493 -554 593 1000 623 574 -314 236 83 -25 -41 676 -619 -85 27 64 -990 367 -145 285 -268 285 -754 900000 -1066 -1036 576 -920 215 -1915 557 -1835 109 -1036 237 -1504 -530 -717 525 -615 349 -209 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