File name: Pandora147s1_SWDetroitMI_20220921_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20260322T234425.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20220921_L1_smca1c1d20210609p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20220921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220921T120141.3Z 8299.501173 204 1 49.46 2 82.92 95.67 34.40 113.40 0.00 1 0.00 1 0 25 5.861e-01 3.756e-02 3.826e-01 2.081e-02 7.892221e-01 1.248548e-02 9.199543e-03 -6.000000e+00 3.458362e-01 228.42 -2.00 3.54 -2.00 322.02 0.00e+00 -7.376363e-03 6.448865e-03 9.163131e-03 -6.000000e+00 1.731653e-02 285.26 -2.00 20.00 -2.00 321.51 0.00e+00 7.455 0.008 302.00 328.00 3 1.2469e+00 4.6534e-02 1.0328e-01 -6.0000e+00 8.6720e-01 9.5011e-01 6.1191e-02 9.6126e-02 -6.0000e+00 9.4616e-01 -1.3881e+00 4.8293e-02 3.3117e-02 -6.0000e+00 5.5549e-01 5.7504e-01 2.2737e-02 1.0364e-02 -6.0000e+00 2.3902e-01 4.8779e-05 -1.9419e-03 6.1928e-04 8.6349e-05 -6.0000e+00 1.6339e-02 -8.0570e-03 3.1683e-05 12 8 8 10 0 0 95.22 16.26 0.57 -0.00806 -0.02265 25 6 1 5 0 1978.320 22.40 14.98 16.26 26.10 24.6 981.29 900000 82387 900000 10305 111356 265 900000 -70397 900000 -71734 900000 -129504 900000 -33885 900000 -25317 900000 23600 900000 49498 900000 -24774 127916 99466 42378 900000 136281 148463 -63227 900000 -45581 900000 -16776 119942 -37022 900000 -7843 900000 31705 175931 46988 135809 53627 225763 88481 44075 204649 2151 171750 10312 83036 -22113 172201 19919 85968 43675 128041 38535 60320 -6254 78499 -12149 27610 16518 30199 31091 30341 11878 21888 34478 12472 23316 -1567 33975 12174 26100 -6081 29449 -9039 2092 -12390 14591 -6023 11888 -4880 5617 -4064 4183 11329 -3025 -360 -1176 3225 -9715 -737 -14622 -62 -8387 4984 -10677 -114 -8429 -96 -9482 4404 -6472 -1650 -3317 -839 -622 283 754 -775 2075 -1466 2627 -691 2634 -1955 3898 -65 3788 -933 6255 -285 2383 -341 2580 -251 64 581 190 143 233 -229 -573 1324 -815 1770 -1272 596 -2716 -476 900000 1667 900000 282 2253 6 900000 -3184 900000 -3842 900000 -11645 900000 -1573 900000 -1416 900000 899 900000 1565 900000 -1415 2588 2012 1447 900000 2757 3004 -4966 900000 -2983 900000 -1078 2427 -3084 900000 -466 900000 1684 3559 2971 3778 3458 4567 3804 2842 4140 204 3475 952 3990 -3184 4413 2368 5653 4584 5990 4434 5339 -945 5161 -1908 3421 2590 4544 4678 4450 1993 3764 5973 2879 5161 -449 6916 2651 4653 -1338 4394 -2114 483 -3952 4150 -2394 4273 -2201 2440 -2056 2026 5164 -1559 -171 -523 1313 -4520 -344 -9136 -39 -6737 3998 -10622 -99 -7313 -68 -6974 2967 -5253 -1345 -2941 -792 -664 343 1013 -1113 2902 -2055 3379 -902 3443 -2834 5646 -100 5391 -1330 8062 -381 3004 -426 3119 -347 102 1049 378 305 526 -560 -1506 3535 -2258 4820 -3489 1505 -6578 -1056 SS 20220921T121248.6Z 8299.508896 207 1 48.42 2 80.88 97.58 32.59 116.53 0.00 1 0.00 1 0 17 4.843e-01 1.286e-02 2.428e-01 6.599e-03 6.671852e-01 3.680046e-03 7.951399e-03 -6.000000e+00 2.767700e-01 228.42 -2.00 3.54 -2.00 321.66 0.00e+00 5.810518e-03 1.950481e-03 3.776663e-03 -6.000000e+00 1.227079e-02 285.26 -2.00 20.00 -2.00 321.12 0.00e+00 5.985 0.004 302.00 328.00 3 1.0469e+00 1.3588e-02 7.0462e-02 -6.0000e+00 6.8858e-01 1.9505e-01 1.8925e-02 4.1609e-02 -6.0000e+00 7.4529e-01 -3.0286e-01 1.8326e-02 2.3857e-02 -6.0000e+00 4.4415e-01 1.2168e-01 8.5532e-03 8.4668e-03 -6.0000e+00 1.9248e-01 2.8071e-04 -8.1773e-04 1.9139e-04 1.3014e-04 -6.0000e+00 1.2773e-02 -8.5746e-03 2.8656e-05 12 8 8 10 0 0 87.21 16.27 0.51 -0.00857 -0.01472 74 17 1 5 0 654.240 22.40 15.00 16.27 27.00 24.6 988.15 900000 -201526 -32301 -163961 -147801 -210807 23773 -166523 -140525 -170639 56713 -164333 -141374 -114329 -32438 -102012 18486 -1242 -34007 -54792 -48174 -13337 -43189 8994 -59656 36369 -55060 -10279 -66912 -22602 -57004 12135 -4272 21451 -12967 20969 -18675 8328 -7419 -10527 9554 4533 17403 6056 13154 -4924 15481 3803 11334 2261 11160 7554 19135 -1 16572 4379 11667 9134 12408 6948 2545 7049 3964 10590 6930 6681 3832 2924 1891 6184 4725 7021 143 6180 113 1416 -2038 1402 -7352 -443 -2228 1661 -2495 -923 -655 -1734 690 -261 1864 728 1633 -474 1295 -4130 -606 -2962 672 -968 519 -463 -997 -1961 -1925 -1376 -1202 -2179 -2207 -1306 -1734 347 -18 756 -503 219 -292 438 -305 130 -105 737 216 1143 1353 1124 758 664 523 192 566 142 545 14 -100 -195 250 -271 -282 216 593 -82 -320 -545 -634 900000 -3419 -208 -2206 -1556 -3823 153 -2143 -1718 -2795 365 -3067 -2547 -2060 -334 -2626 167 -15 -635 -1340 -1147 -223 -973 127 -1804 445 -1736 -205 -2282 -509 -2091 273 -135 594 -509 553 -757 295 -372 -664 572 312 1120 456 940 -392 1136 323 934 196 966 764 1914 0 1997 623 1597 1298 1669 959 369 1047 689 1976 1484 1450 829 643 447 1606 1421 2214 49 1923 35 385 -520 335 -2056 -136 -831 693 -1223 -479 -359 -1032 426 -170 1207 469 987 -272 689 -2298 -353 -2041 522 -886 530 -502 -1049 -1906 -1671 -1131 -1044 -2058 -2193 -1371 -1982 434 -26 1160 -806 343 -438 619 -426 187 -160 1186 356 1814 2056 1662 1084 917 694 254 820 237 1013 28 -214 -440 602 -702 -756 588 1625 -222 -823 -1317 -1452 SS 20220921T122331.5Z 8299.516336 212 1 47.93 2 78.92 99.44 30.90 119.80 0.00 1 0.00 1 0 25 3.177e-01 7.244e-03 9.296e-02 2.961e-03 5.793172e-01 1.587629e-03 6.820196e-03 -6.000000e+00 1.815501e-01 228.42 -2.00 3.54 -2.00 321.07 0.00e+00 3.389554e-03 7.285665e-04 2.178022e-03 -6.000000e+00 8.048791e-03 285.26 -2.00 20.00 -2.00 320.49 0.00e+00 5.020 0.002 302.00 328.00 3 8.3149e-01 5.3185e-03 5.8594e-02 -6.0000e+00 4.5168e-01 4.8748e-02 7.1392e-03 3.3236e-02 -6.0000e+00 4.8886e-01 -7.8026e-02 6.9032e-03 1.8091e-02 -6.0000e+00 2.9133e-01 2.2356e-02 3.3375e-03 6.0171e-03 -6.0000e+00 1.2627e-01 9.4350e-04 -5.4392e-04 8.4455e-05 7.9019e-05 -6.0000e+00 8.3769e-03 -9.1204e-03 3.5687e-05 11 8 0 10 0 0 96.00 16.27 0.32 -0.00912 -0.01321 143 33 1 5 0 335.100 22.40 15.00 16.27 27.71 24.7 993.50 900000 -96511 -97220 -96875 -117627 -114343 -78837 -120111 -108634 -91164 -90738 -70479 -91526 -73617 -59057 -39763 -52420 -30140 -19406 -8638 -30723 -16682 -26665 -13160 -20071 -3159 -8089 -13581 -14289 -18412 -10723 -11327 -4826 -679 -5291 -9982 -5844 -12242 -2942 -6704 1783 -3671 570 483 1740 2341 -358 3401 2617 1118 2816 3072 5032 5752 3746 3276 3053 953 815 882 2937 2969 1606 5262 3084 1893 885 909 1503 2263 1821 2572 2090 510 653 -671 -1337 -2159 -2255 -1781 -683 -1280 -1527 -2243 -938 -455 346 527 836 990 1433 382 -269 -1227 -372 -414 -260 501 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