File name: Pandora147s1_SWDetroitMI_20221102_L2Fit_fout2c1d20210609p1-8.txt File generation date: 20260322T235222.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20221102_L1_smca1c1d20210609p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20221102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 235 377 Nominal wavelengths inside fitting window [nm]: 305.0003 305.1412 305.2821 305.4229 305.5638 305.7046 305.8454 305.9863 306.1271 306.2679 306.4086 306.5494 306.6902 306.8309 306.9716 307.1124 307.2531 307.3938 307.5345 307.6752 307.8158 307.9565 308.0971 308.2378 308.3784 308.5190 308.6596 308.8002 308.9408 309.0813 309.2219 309.3624 309.5029 309.6435 309.7840 309.9245 310.0649 310.2054 310.3459 310.4863 310.6268 310.7672 310.9076 311.0480 311.1884 311.3288 311.4692 311.6095 311.7499 311.8902 312.0305 312.1708 312.3111 312.4514 312.5917 312.7320 312.8722 313.0124 313.1527 313.2929 313.4331 313.5733 313.7135 313.8537 313.9938 314.1340 314.2741 314.4142 314.5543 314.6944 314.8345 314.9746 315.1147 315.2547 315.3948 315.5348 315.6748 315.8149 315.9549 316.0948 316.2348 316.3748 316.5147 316.6547 316.7946 316.9345 317.0744 317.2143 317.3542 317.4941 317.6339 317.7738 317.9136 318.0534 318.1932 318.3330 318.4728 318.6126 318.7524 318.8921 319.0319 319.1716 319.3113 319.4510 319.5907 319.7304 319.8701 320.0097 320.1494 320.2890 320.4287 320.5683 320.7079 320.8475 320.9870 321.1266 321.2662 321.4057 321.5452 321.6848 321.8243 321.9638 322.1033 322.2427 322.3822 322.5216 322.6611 322.8005 322.9399 323.0793 323.2187 323.3581 323.4975 323.6368 323.7762 323.9155 324.0548 324.1941 324.3334 324.4727 324.6120 324.7512 324.8905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221102T125134.3Z 8341.535814 63 1 49.63 2 83.27 117.13 155.57 2.17 0.00 1 0.00 1 0 25 4.311e-01 2.904e-02 4.268e-01 2.524e-02 7.494206e-01 1.440147e-02 9.095455e-03 -6.000000e+00 2.443574e-01 224.03 -2.00 3.54 -2.00 321.98 0.00e+00 2.391943e-02 7.336168e-03 2.217060e-03 -6.000000e+00 1.194901e-02 280.02 -2.00 20.00 -2.00 321.52 0.00e+00 7.788 0.009 302.00 328.00 3 1.0667e+00 5.2119e-02 9.2429e-02 -6.0000e+00 6.0248e-01 9.6909e-01 6.3876e-02 6.9350e-02 -6.0000e+00 6.5612e-01 -1.2816e+00 5.0571e-02 2.1002e-02 -6.0000e+00 3.9168e-01 5.3302e-01 2.5086e-02 2.3570e-02 -6.0000e+00 1.7185e-01 4.0598e-05 -2.2253e-03 7.2249e-04 2.6564e-04 -6.0000e+00 1.1528e-02 -1.1309e-02 3.1680e-05 12 9 8 11 8 0 27.14 16.28 0.35 -0.01131 -0.02803 23 5 1 5 0 2157.540 22.40 14.99 16.28 17.48 24.2 934.75 900000 900000 -87398 56997 -100803 109999 -102091 16160 -103535 123579 -107823 900000 -46637 900000 -9521 -22570 900000 10238 79114 -729 900000 -5327 88709 -16589 33817 -33459 900000 3682 35343 -71337 -47103 15110 47179 102537 55678 40800 26338 43386 -12637 83839 3203 102634 30474 900000 18811 171733 28416 117820 50553 146394 18692 64581 8802 59861 36920 28148 11281 -179 24555 4422 25293 32597 32276 25237 14184 -4258 38477 3309 35374 1183 13813 19570 11162 -4469 8635 -11566 16582 -26147 13258 -16922 -17503 8757 1330 10267 -2238 5950 1131 1490 -7379 6053 523 7299 -2242 880 -3644 -1559 -7743 313 -824 -3690 37 -3272 -288 -2548 -1654 -8563 -434 -2813 623 -5315 1602 967 2517 -2218 2888 -1611 -995 -1390 -1583 -446 864 1849 -367 3839 2221 2429 -34 1726 -1465 3153 841 1802 421 807 41 -290 -65 439 -965 -64 -577 -222 -1577 900000 900000 -5584 1401 -6193 2703 -4754 397 -4151 3037 -3905 900000 -1146 900000 -299 -963 900000 419 1944 -36 900000 -247 2180 -725 831 -1507 900000 106 869 -4480 -2765 598 1610 2520 1900 1448 1043 1540 -880 2666 236 3116 1872 900000 1387 4220 2017 3747 3106 3809 1761 4232 1094 4740 3831 3190 1494 -26 2648 561 2624 3382 3834 3721 2477 -914 5516 638 5457 274 3180 4506 2801 -1243 2028 -2797 2875 -6426 2516 -4925 -6203 2786 514 3891 -1010 2632 554 759 -4180 2960 257 3106 -992 374 -1772 -873 -5498 242 -742 -3656 34 -2878 -217 -1829 -1226 -7332 -361 -2572 603 -6180 1991 1344 3611 -3323 3959 -2205 -1332 -1939 -2354 -696 1355 2781 -539 5239 2981 3154 -43 2170 -2107 5049 1566 3646 919 1858 102 -772 -179 1219 -2743 -177 -1511 -537 -3624 SS 20221102T130231.3Z 8341.543417 66 1 48.73 2 81.49 119.10 155.36 8.13 0.00 1 0.00 1 0 25 4.743e-01 1.555e-02 2.950e-01 7.600e-03 6.794279e-01 4.096686e-03 7.950588e-03 -6.000000e+00 2.665938e-01 224.03 -2.00 3.54 -2.00 321.57 0.00e+00 4.870534e-03 2.102268e-03 3.103127e-03 -6.000000e+00 1.175460e-02 280.02 -2.00 20.00 -2.00 321.09 0.00e+00 6.367 0.005 302.00 328.00 3 8.8325e-01 1.4501e-02 7.2925e-02 -6.0000e+00 6.5781e-01 2.8574e-01 2.0091e-02 4.0064e-02 -6.0000e+00 7.1483e-01 -4.0613e-01 2.0213e-02 2.2571e-02 -6.0000e+00 4.2612e-01 1.6407e-01 9.5254e-03 7.9589e-03 -6.0000e+00 1.8560e-01 2.2943e-04 -1.0951e-03 2.1218e-04 1.2062e-04 -6.0000e+00 1.2493e-02 -1.0557e-02 -1.8546e-06 12 9 8 11 8 0 -16.99 16.28 0.42 -0.01056 -0.01879 69 16 1 5 0 706.100 22.40 14.99 16.28 18.37 24.3 942.74 900000 -55881 -206068 -14513 -177800 76448 -209543 -53569 -187392 -103738 -172490 -112121 6315 88588 -51964 -106689 -15461 -53472 -5568 -69409 22132 -21298 50767 -71044 -2188 -62459 140998 -55153 59436 -52837 32303 -43585 46097 12425 24351 -14888 -1202 4058 186 6195 10179 36355 20336 26421 7631 28251 8951 24915 -290 29627 7180 23337 6734 18207 9475 14243 10484 10183 6296 11787 12212 3978 14686 6765 12438 -855 12678 -2342 6543 2419 11284 892 6212 455 3102 -2314 1831 -3766 -2796 -5127 -1224 898 -2683 -1406 -2351 1257 -1876 1820 -309 874 -620 918 -4297 -2068 -4209 -1724 -1710 634 -275 -201 -258 -1439 -1523 -2009 -294 -2386 -621 -2056 -654 -1384 600 1016 968 -49 161 -1112 140 -373 944 296 168 940 711 1334 988 992 -257 1231 -241 674 211 681 -443 219 -446 114 -652 292 11 500 -471 -356 -686 900000 -414 -5553 -108 -3354 566 -4941 -397 -4292 -1118 -3835 -1435 47 656 -735 -3234 -241 -1225 -95 -2151 312 -458 527 -2393 -44 -2188 1045 -1821 661 -1673 551 -1762 991 424 740 -572 -45 150 9 330 603 1812 1260 1602 565 1732 681 1662 -26 2076 687 2138 808 2122 1296 1938 1533 1509 946 1620 1670 630 2365 1354 2606 -207 2605 -563 1529 675 3284 309 2071 155 949 -670 460 -972 -765 -1689 -464 387 -1354 -753 -1348 745 -1217 1188 -210 575 -392 531 -2478 -1156 -2608 -1207 -1400 589 -292 -225 -279 -1441 -1360 -1710 -260 -2318 -624 -2233 -760 -1814 871 1478 1458 -74 252 -1666 203 -561 1486 498 288 1552 1127 2040 1463 1419 -357 1677 -366 1167 412 1436 -916 475 -1042 284 -1691 763 29 1296 -1165 -824 -1638 SS 20221102T131734.9Z 8341.553876 71 1 47.79 2 79.09 121.88 154.75 16.10 0.00 1 0.00 1 0 25 2.709e-01 6.406e-03 8.626e-02 2.680e-03 5.673334e-01 1.416790e-03 6.623034e-03 -6.000000e+00 1.522340e-01 224.03 -2.00 3.54 -2.00 320.99 0.00e+00 2.735434e-03 6.200559e-04 1.098282e-03 -6.000000e+00 6.712149e-03 280.02 -2.00 20.00 -2.00 320.45 0.00e+00 5.094 0.002 302.00 328.00 3 6.0089e-01 4.5962e-03 5.7998e-02 -6.0000e+00 3.7563e-01 5.0820e-02 6.1060e-03 3.0875e-02 -6.0000e+00 4.0819e-01 -7.0188e-02 6.1093e-03 1.6994e-02 -6.0000e+00 2.4333e-01 2.0492e-02 2.9934e-03 5.9759e-03 -6.0000e+00 1.0599e-01 1.1376e-03 -8.9224e-04 7.7330e-05 7.0566e-05 -6.0000e+00 7.1336e-03 -1.1152e-02 -1.8258e-05 11 9 0 11 8 0 -18.23 16.29 0.24 -0.01115 -0.01786 177 41 1 5 0 269.950 22.40 15.00 16.29 19.68 24.5 953.77 900000 -107819 -70438 -69253 -103571 -82299 -108258 -66116 -106431 -50940 -98246 -72747 -66823 -53640 -60535 -17493 -23227 8829 -9506 -9462 -14053 -11976 -14136 -7110 -18623 -13159 -14749 -19746 -12990 -24970 -11754 -5585 584 -8314 -3586 -7415 -2017 -5348 1573 -1195 3257 -1675 1030 2241 4790 2308 1198 2373 2943 2824 -858 4069 2354 3886 902 4678 1693 1790 84 -334 42 2250 2423 4194 2326 1183 1213 575 255 1707 1368 773 1731 302 584 -181 -1022 -2480 -2624 -2452 -1184 -1435 -1775 -2153 -1161 -876 41 309 669 1193 937 1055 13 -321 -873 -433 66 785 526 363 -480 -1004 -1217 -1168 -1214 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