File name: Pandora147s1_SWDetroitMI_20221118_L2Fit_fnvs5c1d20210609p1-8.txt File generation date: 20260322T235515.2Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 147 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora147_OF_v4d20210429.txt Instrument calibration file used: Pandora147s1_CF_v1d20210609.txt Level 1 file used: Pandora147s1_SWDetroitMI_20221118_L1_smca1c1d20210609p1-8.txt.bz2 Full location name: SW Detroit (SWHS) (AQS-26-163-0015) Short location name: SWDetroitMI Country of location: USA Location latitude [deg]: 42.3026 Location longitude [deg]: -83.1068 Location altitude [m]: 178 Local noon date: 20221118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 931 1476 Nominal wavelengths inside fitting window [nm]: 400.1291 400.2612 400.3933 400.5254 400.6575 400.7896 400.9216 401.0537 401.1857 401.3177 401.4497 401.5817 401.7137 401.8456 401.9776 402.1095 402.2414 402.3733 402.5052 402.6371 402.7689 402.9008 403.0326 403.1644 403.2962 403.4280 403.5598 403.6915 403.8233 403.9550 404.0867 404.2184 404.3501 404.4818 404.6134 404.7451 404.8767 405.0083 405.1399 405.2715 405.4031 405.5346 405.6662 405.7977 405.9292 406.0607 406.1922 406.3237 406.4551 406.5866 406.7180 406.8494 406.9808 407.1122 407.2436 407.3749 407.5063 407.6376 407.7689 407.9002 408.0315 408.1627 408.2940 408.4252 408.5565 408.6877 408.8189 408.9501 409.0812 409.2124 409.3435 409.4747 409.6058 409.7369 409.8680 409.9990 410.1301 410.2611 410.3922 410.5232 410.6542 410.7851 410.9161 411.0471 411.1780 411.3089 411.4398 411.5707 411.7016 411.8325 411.9633 412.0942 412.2250 412.3558 412.4866 412.6174 412.7482 412.8789 413.0097 413.1404 413.2711 413.4018 413.5325 413.6631 413.7938 413.9244 414.0550 414.1857 414.3162 414.4468 414.5774 414.7079 414.8385 414.9690 415.0995 415.2300 415.3605 415.4909 415.6214 415.7518 415.8822 416.0126 416.1430 416.2734 416.4038 416.5341 416.6645 416.7948 416.9251 417.0554 417.1856 417.3159 417.4462 417.5764 417.7066 417.8368 417.9670 418.0972 418.2273 418.3575 418.4876 418.6177 418.7478 418.8779 419.0080 419.1380 419.2681 419.3981 419.5281 419.6581 419.7881 419.9181 420.0480 420.1780 420.3079 420.4378 420.5677 420.6976 420.8274 420.9573 421.0871 421.2170 421.3468 421.4766 421.6063 421.7361 421.8659 421.9956 422.1253 422.2550 422.3847 422.5144 422.6441 422.7737 422.9033 423.0330 423.1626 423.2922 423.4217 423.5513 423.6808 423.8104 423.9399 424.0694 424.1989 424.3284 424.4578 424.5873 424.7167 424.8461 424.9755 425.1049 425.2343 425.3636 425.4930 425.6223 425.7516 425.8809 426.0102 426.1394 426.2687 426.3979 426.5272 426.6564 426.7856 426.9147 427.0439 427.1731 427.3022 427.4313 427.5604 427.6895 427.8186 427.9477 428.0767 428.2057 428.3348 428.4638 428.5928 428.7217 428.8507 428.9796 429.1086 429.2375 429.3664 429.4953 429.6241 429.7530 429.8818 430.0107 430.1395 430.2683 430.3971 430.5258 430.6546 430.7833 430.9121 431.0408 431.1695 431.2981 431.4268 431.5555 431.6841 431.8127 431.9413 432.0699 432.1985 432.3270 432.4556 432.5841 432.7126 432.8411 432.9696 433.0981 433.2266 433.3550 433.4834 433.6119 433.7403 433.8686 433.9970 434.1254 434.2537 434.3820 434.5103 434.6386 434.7669 434.8952 435.0234 435.1517 435.2799 435.4081 435.5363 435.6645 435.7926 435.9208 436.0489 436.1770 436.3051 436.4332 436.5613 436.6894 436.8174 436.9454 437.0734 437.2014 437.3294 437.4574 437.5853 437.7133 437.8412 437.9691 438.0970 438.2249 438.3528 438.4806 438.6084 438.7363 438.8641 438.9919 439.1196 439.2474 439.3751 439.5029 439.6306 439.7583 439.8860 440.0137 440.1413 440.2690 440.3966 440.5242 440.6518 440.7794 440.9069 441.0345 441.1620 441.2895 441.4171 441.5445 441.6720 441.7995 441.9269 442.0544 442.1818 442.3092 442.4366 442.5639 442.6913 442.8186 442.9460 443.0733 443.2006 443.3279 443.4551 443.5824 443.7096 443.8368 443.9641 444.0912 444.2184 444.3456 444.4727 444.5999 444.7270 444.8541 444.9812 445.1083 445.2353 445.3624 445.4894 445.6164 445.7434 445.8704 445.9973 446.1243 446.2512 446.3781 446.5051 446.6319 446.7588 446.8857 447.0125 447.1394 447.2662 447.3930 447.5198 447.6465 447.7733 447.9000 448.0268 448.1535 448.2802 448.4068 448.5335 448.6602 448.7868 448.9134 449.0400 449.1666 449.2932 449.4197 449.5463 449.6728 449.7993 449.9258 450.0523 450.1788 450.3052 450.4317 450.5581 450.6845 450.8109 450.9373 451.0636 451.1900 451.3163 451.4426 451.5689 451.6952 451.8215 451.9477 452.0740 452.2002 452.3264 452.4526 452.5788 452.7050 452.8311 452.9572 453.0834 453.2095 453.3356 453.4616 453.5877 453.7137 453.8398 453.9658 454.0918 454.2177 454.3437 454.4697 454.5956 454.7215 454.8474 454.9733 455.0992 455.2250 455.3509 455.4767 455.6025 455.7283 455.8541 455.9799 456.1056 456.2314 456.3571 456.4828 456.6085 456.7342 456.8598 456.9855 457.1111 457.2367 457.3623 457.4879 457.6135 457.7390 457.8645 457.9901 458.1156 458.2411 458.3665 458.4920 458.6174 458.7429 458.8683 458.9937 459.1191 459.2444 459.3698 459.4951 459.6204 459.7457 459.8710 459.9963 460.1216 460.2468 460.3720 460.4972 460.6224 460.7476 460.8728 460.9979 461.1231 461.2482 461.3733 461.4984 461.6235 461.7485 461.8736 461.9986 462.1236 462.2486 462.3736 462.4985 462.6235 462.7484 462.8733 462.9982 463.1231 463.2480 463.3729 463.4977 463.6225 463.7473 463.8721 463.9969 464.1217 464.2464 464.3711 464.4959 464.6206 464.7452 464.8699 464.9946 465.1192 465.2438 465.3684 465.4930 465.6176 465.7421 465.8667 465.9912 466.1157 466.2402 466.3647 466.4892 466.6136 466.7381 466.8625 466.9869 467.1113 467.2356 467.3600 467.4843 467.6086 467.7330 467.8573 467.9815 468.1058 468.2300 468.3543 468.4785 468.6027 468.7269 468.8510 468.9752 469.0993 469.2234 469.3475 469.4716 469.5957 469.7197 469.8438 469.9678 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Temperature at electronics board [°C], 999=no temperature signal Column 159: Spectrometer control temperature [°C], 999=no temperature signal Column 160: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 161: Temperature in head sensor [°C], 999=no temperature signal Column 162: Humidity in head sensor [%], -9=no humidity signal Column 163: Pressure in head sensor [hPa], -9=no pressure signal Columns 164-709: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 710-1255: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221118T175058.2Z 8357.743729 430 1 49.41 2 62.12 188.89 70.40 261.21 0.00 1 0.00 1 0 33 3.813e-03 3.393e-03 1.807e-03 1.734e-03 -3.915616e+02 3.446187e+02 5.217996e+01 3.423302e+02 7.469134e+02 278.02 -2.00 20.00 -2.00 446.22 0.00e+00 1.055763e-03 1.922601e-04 4.053175e-06 1.423441e-05 4.147159e-04 278.02 -2.00 20.00 -2.00 455.83 0.00e+00 4.605088e-04 1.545406e-05 3.061237e-06 7.850621e-06 3.388496e-05 222.66 -2.00 2.18 -2.00 436.78 0.00e+00 1.276622e+06 2.466568e+05 1.785530e+04 2.120997e+05 5.459447e+05 259.76 -2.00 11.26 -2.00 458.61 0.00e+00 2.499905e-01 4.655768e-02 1.375096e-03 8.329412e-03 1.183733e-01 222.83 -2.00 3.54 -2.00 455.22 0.00e+00 -1.103765e-05 5.955524e-06 2.637431e-07 1.063538e-06 1.446871e-05 278.02 -2.00 20.00 -2.00 456.41 0.00e+00 2.128 0.000 397.00 473.00 4 7.7914e+00 1.8862e-03 5.3065e-03 3.6157e-04 3.8722e-03 4.4714e-02 2.1971e-03 1.1082e-03 2.2064e-04 4.7631e-03 -1.8753e-02 1.3034e-03 1.4560e-04 9.5045e-05 2.7862e-03 -9.2979e-04 4.2730e-04 3.2694e-05 2.3653e-05 9.2403e-04 6.1699e-04 2.2588e-04 2.2476e-05 1.2960e-05 4.6833e-04 5.8699e-04 -2.9365e-03 1.2669e-03 1.8188e-05 4.3147e-05 2.3568e-03 -5.5145e-05 1.8121e-05 1.8669e-07 3.0588e-07 3.8535e-05 1.8550e-05 2.4598e-05 2.1496e-07 3.7332e-07 5.2666e-05 -1.1357e-02 -4.5881e-05 2.0121e-01 1.7385e-01 1.1843e-03 2.0406e-03 3.4376e-01 12 8 8 10 0 0 99.93 16.26 0.94 -0.01136 -0.01414 22 5 1 4 0 2245.490 22.40 15.00 16.26 8.07 23.3 866.32 -149 148 -331 -220 1 -243 -32 197 -68 141 153 -222 -204 -329 -79 -81 235 177 75 -85 405 -118 -221 -63 -110 -392 134 -113 180 25 639 -85 95 -155 -139 98 53 470 43 759 -303 377 -58 147 -339 446 153 426 -261 22 -243 -49 142 267 202 -141 147 -292 147 -251 294 -66 417 -420 254 -19 188 -31 150 -201 229 -189 -131 -178 -177 -283 115 49 16 -37 -11 106 13 193 -151 245 4 -133 -27 62 -154 -81 74 -150 -117 -149 79 -319 121 1 179 -324 56 -256 445 -162 -70 -186 -35 -50 152 -488 -47 -379 -400 64 -67 -159 171 -1 -285 21 -89 53 -320 17 -249 -81 -442 110 -411 349 -214 47 -109 -121 12 124 -262 -308 -354 29 3 -121 375 -244 231 130 119 -103 33 -117 137 -10 326 -65 186 -146 132 -172 132 100 145 310 -127 360 161 356 -86 301 -299 -129 -443 20 -43 282 13 52 94 31 -20 -56 -10 -179 235 -185 47 168 178 -129 529 -186 279 -407 -18 94 76 12 -12 67 -121 133 -8 373 -46 91 14 -72 -457 -89 -319 221 -327 -263 7376 167 -267 -77 -304 -56 -52 481 234 474 -354 119 8 -121 77 -215 67 -324 6 -457 129 -264 177 -630 -404 -154 320 100 98 -25 -14 -7 -15 -248 -392 120 -58 -186 -366 102 -160 57 -325 341 -261 113 -326 102 -254 248 -86 -280 -112 -311 131 8 -100 -568 188 -197 232 -117 99 -242 128 -258 198 -112 -45 -404 -227 -431 -5 -9 -113 76 92 -42 22 104 46 -274 -512 173 -231 290 -164 -2 -170 84 -332 -89 -66 52 -157 172 29 -256 -318 -71 230 -221 347 -150 259 -361 435 -188 -179 -303 130 45 -236 1 254 27 88 0 -221 172 -162 367 -83 116 -251 55 -218 169 -282 226 -158 -139 73 156 -373 70 -50 219 271 12 298 169 172 -281 -12 -364 358 -102 194 -11 -65 -5 -9 -165 -288 -404 -306 60 -139 -240 -127 207 5 6 -72 299 -43 -215 -312 430 54 -208 -26 -121 -42 -28 41 302 156 43 137 -29 134 261 395 128 177 -228 478 -112 191 111 224 10 -9 272 183 -129 117 20 -74 -14 214 212 142 183 49 121 -56 -65 -150 61 -246 145 161 -4 -151 143 -2 31 -35 139 -111 121 143 -392 243 -123 50 -321 -13 49 303 -135 -68 -88 -150 -143 -16 40 234 -142 -22 -188 -99 93 -67 153 -218 201 -1 -15 -99 -16 78 175 23 141 51 99 -441 -69 -44 31 32 52 162 106 42 -79 35 -160 326 -312 147 -27 146 -18 -209 -184 250 18 -39 -5 -82 106 -97 -175 51 -12 -152 257 -239 131 -30 211 -170 15 -278 -231 -395 173 97 -93 16 291 42 93 29 -36 -118 -101 -61 -411 17 103 35 -8 55 -134 124 71 -15 -24 200 -162 51 56 -7 32 267 121 -118 115 -249 -162 1 -181 -25 158 -55 115 124 -179 -165 -268 -65 -67 194 145 62 -71 337 -96 -172 -47 -83 -294 106 -94 154 22 543 -69 75 -117 -103 75 44 392 36 654 -257 309 -47 120 -281 363 121 329 -199 17 -201 -41 119 223 168 -117 121 -237 117 -207 253 -59 371 -373 226 -18 178 -30 143 -189 209 -168 -120 -157 -147 -221 87 37 13 -32 -10 99 12 184 -147 244 4 -130 -27 62 -154 -80 74 -151 -117 -147 78 -310 114 1 163 -301 54 -258 462 -171 -72 -182 -33 -47 145 -484 -47 -380 -396 62 -64 -151 161 -1 -283 22 -93 56 -340 17 -255 -82 -440 106 -389 321 -196 43 -103 -117 12 120 -254 -298 -339 27 3 -115 362 -247 235 131 117 -97 30 -105 122 -9 307 -63 189 -152 137 -172 132 100 149 313 -127 357 164 352 -85 302 -277 -108 -361 17 -39 278 12 50 92 29 -18 -52 -9 -176 223 -180 45 160 165 -121 487 -176 264 -376 -17 88 70 11 -11 63 -112 129 -8 366 -44 81 13 -60 -379 -77 -280 202 -306 -247 6344 153 -244 -70 -271 -48 -46 419 196 404 -311 103 7 -97 57 -151 46 -225 4 -321 87 -175 116 -427 -297 -126 279 96 96 -25 -15 -7 -15 -218 -322 98 -50 -176 -353 101 -159 57 -315 311 -231 90 -249 79 -208 221 -78 -265 -109 -300 122 8 -89 -512 175 -188 222 -114 98 -243 131 -266 202 -113 -45 -396 -220 -413 -5 -8 -105 72 88 -40 20 86 36 -214 -418 150 -209 265 -152 -2 -160 80 -310 -83 -61 48 -141 156 26 -230 -286 -63 215 -216 344 -148 249 -343 409 -183 -181 -295 125 43 -222 1 241 25 84 0 -206 156 -146 334 -78 112 -244 52 -205 158 -268 218 -156 -137 71 151 -354 64 -45 189 233 11 260 150 157 -262 -11 -350 340 -97 186 -11 -65 -5 -10 -171 -293 -401 -295 57 -133 -237 -129 210 5 6 -71 294 -42 -214 -312 430 55 -215 -27 -127 -45 -30 44 329 170 47 148 -31 141 272 408 133 185 -240 501 -117 206 117 228 10 -8 264 180 -128 116 20 -77 -15 233 233 156 200 54 131 -60 -69 -163 67 -268 158 177 -4 -169 163 -2 36 -42 164 -129 139 164 -458 284 -145 59 -378 -15 59 362 -160 -79 -100 -176 -166 -19 47 277 -172 -27 -231 -121 112 -80 182 -261 239 -1 -18 -119 -19 93 212 29 176 65 125 -556 -86 -54 39 40 65 202 133 52 -100 45 -202 410 -394 184 -35 183 -23 -261 -228 306 22 -48 -6 -100 130 -119 -222 64 -14 -188 321 -291 160 -36 256 -208 19 -351 -294 -502 215 118 -116 19 343 50 113 36 -43 -144 -125 -75 -505 20 122 41 -9 66 -165 153 88 -18 -30 243 -197 63 69 -8 39 320 143 SQ 20221118T205741.0Z 8357.873391 538 1 48.94 2 79.81 231.74 103.86 291.81 0.00 1 0.00 1 0 33 3.160e-03 2.510e-03 2.215e-03 1.820e-03 7.122820e+02 3.518657e+02 7.684756e+01 3.423356e+02 6.195278e+02 278.01 -2.00 20.00 -2.00 449.82 0.00e+00 4.766033e-04 2.210207e-04 7.094444e-06 1.604142e-05 3.372516e-04 278.01 -2.00 20.00 -2.00 458.46 0.00e+00 1.454804e-03 1.630391e-05 9.957258e-06 7.856406e-06 2.822820e-05 223.15 -2.00 2.18 -2.00 444.16 0.00e+00 1.331498e+06 2.528322e+05 2.453170e+04 2.119125e+05 4.527501e+05 259.74 -2.00 11.26 -2.00 460.23 0.00e+00 9.157313e-01 4.348118e-02 4.828666e-03 7.965178e-03 9.776463e-02 222.83 -2.00 3.54 -2.00 457.80 0.00e+00 -1.679326e-05 5.743392e-06 4.238408e-07 1.074532e-06 1.198971e-05 278.01 -2.00 20.00 -2.00 458.37 0.00e+00 5.419 0.003 397.00 473.00 4 6.8741e+00 2.1141e-03 1.3534e-02 3.6823e-04 3.2149e-03 -3.1845e-02 2.6766e-03 2.8258e-03 2.5498e-04 4.0761e-03 -5.2913e-03 1.4283e-03 3.7240e-04 1.0274e-04 2.1738e-03 5.3663e-03 5.0648e-04 4.2375e-05 2.4623e-05 7.6562e-04 -2.4180e-03 2.7390e-04 1.3056e-05 1.4722e-05 3.8767e-04 6.7905e-04 -4.4775e-02 1.2710e-03 3.7845e-05 5.1134e-05 1.8069e-03 -3.4126e-05 1.9680e-05 3.9028e-07 2.9492e-07 3.1939e-05 2.0431e-04 2.7298e-05 3.7663e-07 4.0527e-07 4.3678e-05 5.1258e-03 -2.3450e-04 1.8261e-02 1.9871e-01 1.9707e-03 2.2707e-03 2.8275e-01 12 8 8 10 0 0 99.99 16.30 0.88 0.00513 -0.01299 49 11 1 4 0 998.740 22.40 14.99 16.30 6.35 23.1 851.12 858 -296 764 -67 768 21 733 -103 214 -134 749 253 576 -202 -178 439 79 311 -87 313 96 397 -763 314 -512 452 -319 634 -153 567 222 228 -179 -484 -803 -258 216 -428 -1 -236 49 -461 -395 -307 580 -254 339 -594 -8 -205 68 12 -19 -561 -469 -74 -113 -523 -440 316 -332 -275 62 22 -676 -71 -364 61 -340 203 6 160 -488 -73 -409 -624 -672 -143 -434 -666 -166 -167 181 -298 475 -162 66 -211 50 -7 154 -402 275 122 162 3 329 60 -6 -10 -225 68 -472 578 75 403 -258 85 -332 106 9 325 81 73 39 444 -103 376 -178 -103 -40 -278 -10 -137 87 -299 -127 -357 325 152 238 -422 99 -231 375 -311 -170 -228 62 -107 -91 14 102 26 -5 -138 -255 442 -324 280 -170 397 -82 132 -144 322 147 265 182 279 -144 404 178 111 357 -51 78 -58 460 0 297 -109 390 -122 177 0 305 218 -163 -126 -157 -304 92 128 196 330 -1 118 -281 216 -426 158 -334 182 -219 348 -376 365 -397 89 118 40 243 -65 352 207 308 -354 -142 -243 -138 -127 -113 -343 4483 -311 -232 -211 -208 -199 409 -302 197 142 102 51 -118 188 -574 240 144 206 46 556 -286 344 -399 -118 -543 338 70 39 -171 -287 17 97 -17 -228 -201 101 -147 -166 64 -415 67 -579 -68 -447 -150 -416 -3 -414 -72 -200 136 -422 -166 -277 -164 -288 -106 484 121 -61 -439 397 -136 106 146 -115 231 255 139 198 -45 358 48 111 198 248 111 -10 85 -252 232 -321 126 47 341 -242 511 -207 69 -179 -131 -260 128 -252 90 -289 -12 36 -262 59 -94 -229 -295 128 -78 333 -154 329 -218 22 -308 28 -204 45 -279 107 67 -87 21 -138 80 -311 190 -139 238 -164 -91 -225 252 -307 83 -207 -42 -240 172 -19 236 178 194 116 561 167 -6 165 177 -104 -113 -4 138 175 -51 74 -204 -60 -104 28 -290 -185 -132 -37 -148 -77 116 -71 198 186 30 -262 65 -149 58 -170 5 -308 36 -53 -129 76 90 -8 -55 -190 -9 -50 5 -131 -123 -269 -85 -158 -340 119 -153 256 -106 253 83 73 -123 278 -106 158 -68 -132 -58 -190 193 31 73 -285 137 -365 571 119 186 -99 191 -69 -3 36 125 -60 124 201 147 47 97 -25 -88 110 137 -127 -288 245 73 153 396 49 134 161 -4 58 -26 84 -155 -47 108 -149 -128 -236 235 -127 15 -28 78 -10 345 -22 97 -316 139 -129 240 -9 193 -16 103 -38 -139 59 36 -44 -74 142 -310 39 -56 86 4 45 -102 67 -79 216 -153 -76 77 -34 142 -67 17 -151 182 -143 73 -178 140 -221 -77 -268 25 -100 -58 46 162 135 328 132 -45 58 10 -41 -114 -128 4 51 -229 -24 22 -194 -146 -48 -80 113 0 79 -305 91 102 187 59 121 408 -141 348 -30 342 10 348 -51 106 -67 374 126 288 -102 -91 243 44 172 -49 177 54 218 -408 159 -257 232 -174 360 -90 333 130 128 -94 -244 -400 -132 119 -250 -1 -136 27 -254 -215 -169 321 -140 182 -316 -4 -109 39 7 -11 -325 -270 -42 -64 -294 -244 179 -198 -168 38 14 -417 -45 -239 41 -225 132 4 108 -323 -47 -249 -359 -375 -80 -255 -424 -111 -114 125 -209 337 -119 50 -160 37 -5 113 -296 204 91 120 2 241 44 -4 -7 -155 47 -340 432 59 318 -201 63 -241 76 6 246 62 56 30 332 -77 277 -132 -78 -31 -222 -8 -114 72 -246 -103 -287 254 117 178 -311 72 -172 284 -241 -132 -177 48 -83 -70 11 78 20 -4 -113 -211 360 -260 214 -126 291 -61 100 -113 258 122 225 156 240 -126 350 153 93 296 -43 67 -47 398 0 231 -78 269 -88 137 0 244 173 -126 -102 -126 -245 70 99 155 267 -1 94 -219 162 -319 120 -258 143 -176 278 -298 281 -304 69 94 34 210 -56 291 160 224 -249 -98 -174 -105 -102 -93 -282 3489 -251 -186 -169 -164 -152 304 -226 149 110 80 40 -89 131 -375 148 86 124 28 339 -171 199 -231 -70 -352 241 56 34 -151 -263 15 86 -15 -187 -154 77 -120 -146 56 -374 60 -523 -60 -374 -124 -316 -2 -305 -56 -169 114 -367 -147 -244 -139 -240 -87 399 104 -54 -395 360 -126 99 140 -112 221 242 130 183 -42 324 43 98 176 225 104 -10 75 -204 178 -244 99 39 295 -213 450 -185 62 -165 -123 -247 121 -237 82 -258 -11 31 -234 55 -85 -216 -285 122 -73 305 -142 313 -215 22 -305 27 -196 43 -273 105 66 -84 20 -130 75 -295 184 -139 239 -163 -88 -219 247 -307 84 -210 -42 -243 169 -18 219 163 177 107 519 157 -6 163 179 -107 -115 -4 141 171 -51 76 -210 -62 -105 29 -296 -186 -135 -39 -152 -79 118 -76 212 199 32 -286 71 -164 65 -181 6 -334 39 -59 -145 86 102 -9 -65 -226 -11 -58 6 -152 -144 -316 -100 -185 -394 134 -168 273 -112 266 89 78 -133 303 -119 183 -80 -159 -70 -228 229 37 85 -329 167 -448 696 146 231 -125 242 -89 -4 49 169 -80 163 263 193 63 131 -33 -118 147 184 -172 -393 329 96 198 504 62 170 206 -5 77 -36 113 -209 -63 142 -196 -169 -312 309 -168 20 -41 112 -15 506 -31 136 -446 194 -193 359 -14 291 -25 155 -58 -213 90 55 -68 -114 216 -475 59 -86 130 6 68 -153 99 -119 324 -232 -116 116 -51 207 -97 25 -226 276 -220 112 -274 216 -347 -122 -400 41 -157 -89 68 233 191 465 192 -67 89 15 -64 -165 -185 6 77 -349 -35 31 -283 -216 -71 -117 165 0 116 -451 136 151 275 85 172